8 research outputs found
Correlation analysis between CSE and organizational commitment (r).
<p>Note: **p<0.01; ***p<0.001.</p
Correlation analysis between organizational commitment and job burnout (r).
<p>Correlation analysis between organizational commitment and job burnout (r).</p
Correlation analysis between CSE and job burnout (r).
<p>Correlation analysis between CSE and job burnout (r).</p
Photoinduced Reactions between Pb<sub>3</sub>O<sub>4</sub> and Organic Dyes in Aqueous Solution under Visible Light
Pb<sub>3</sub>O<sub>4</sub> could react with organic
dyes in aqueous
solution under visible light irradiation, in which Pb<sub>3</sub>O<sub>4</sub> was transformed into Pb<sub>3</sub>(CO<sub>3</sub>)<sub>2</sub>(OH)<sub>2</sub> along with oxidation of the organic dyes. Cu<sup>2+</sup> has considerable effect on the reaction. In the presence
of Cu<sup>2+</sup>, MO (20 ppm) and RhB (10<sup>–5</sup> mol
L<sup>–1</sup>) were completely degraded under visible light
within 6 and 20 min, respectively, while both Pb<sub>3</sub>O<sub>4</sub> and Cu<sup>2+</sup> keep almost stable during photodegradation.
The mechanisms of the reactions with and without Cu<sup>2+</sup> ions
were studied. The photochemical system of Pb<sub>3</sub>O<sub>4</sub> cooperating with Cu<sup>2+</sup> ions is probably used for the treatment
of organic pollutants in water under visible light
Influence of Surface States on the Evaluation of the Flat Band Potential of TiO<sub>2</sub>
Flat band potential (<i>V</i><sub>fb</sub>) is one of the most important physical parameters to study and understand semiconductor materials. However, the influence of surface states on the evaluating <i>V</i><sub>fb</sub> of titanium oxide (TiO<sub>2</sub>) and other semiconductor materials through a Mott–Schottky plot is ignored. Our study indicated that the influence of surface states should be introduced into the corresponding equivalent circuit even when the kinetic process did not occur. Ignoring the influence of surface states would lead to an underestimation of the space charge capacitance. Our paper would be beneficial for accurate determination of <i>V</i><sub>fb</sub> of semiconductor materials. We anticipate that this preliminary study will open new perspectives in understanding the semiconductor–electrolyte interface
Highly Efficient Photoelectrochemical Water Splitting from Hierarchical WO<sub>3</sub>/BiVO<sub>4</sub> Nanoporous Sphere Arrays
Nanoarchitecture
of bismuth vanadate (BiVO<sub>4</sub>) photoanodes
for effectively increasing light harvesting efficiency and simultaneously
achieving high charge separation efficiency is the key to approaching
their theoretic performance of solar-driven water splitting. Here,
we developed hierarchical BiVO<sub>4</sub> nanoporous sphere arrays,
which are composed of small nanoparticles and sufficient voids for
offering high capability of charge separation. Significantly, multiple
light scattering in the sphere arrays and voids along with the large
effective thickness of the BiVO<sub>4</sub> photoanode induce efficient
light harvesting. In addition, attributed to ultrathin two-dimensional
Bi<sub>2</sub>WO<sub>6</sub> nanosheets as the precursor, the synergy
of various enhancement strategies including WO<sub>3</sub>/BiVO<sub>4</sub> nanojunction formation, W-doping, and oxygen vacancy creation
can be directly incorporated into such a unique hierarchical architecture
during the one-step synthesis of BiVO<sub>4</sub> without complex
pre- or post-treatment. The as-obtained photoanode exhibits a water
splitting photocurrent of 5.5 mA cm<sup>–2</sup> at 1.23 V
versus RHE under 1-sun illumination, among the best values reported up-to-date
in the field