454 research outputs found
Distinct Fermi Surface Topology and Nodeless Superconducting Gap in (Tl0.58Rb0.42)Fe1.72Se2 Superconductor
High resolution angle-resolved photoemission measurements have been carried
out to study the electronic structure and superconducting gap of the
(TlRb)FeSe superconductor with a T=32 K. The
Fermi surface topology consists of two electron-like Fermi surface sheets
around point which is distinct from that in all other iron-based
compounds reported so far. The Fermi surface around the M point shows a nearly
isotropic superconducting gap of 12 meV. The large Fermi surface near the
point also shows a nearly isotropic superconducting gap of 15
meV while no superconducting gap opening is clearly observed for the inner tiny
Fermi surface. Our observed new Fermi surface topology and its associated
superconducting gap will provide key insights and constraints in understanding
superconductivity mechanism in the iron-based superconductors.Comment: 4 pages, 4 figure
Printable Metal-Polymer Conductors for Highly Stretchable Bio-Devices
Stretchable, biocompatible devices can bridge electronics and biology. However, most stretchable conductors for such devices are toxic, costly, and regularly break/degrade after several large deformations. Here we show printable, highly stretchable, and biocompatible metal-polymer conductors by casting and peeling off polymers from patterned liquid metal particles, forming surface-embedded metal in polymeric hosts. Our printable conductors present good stretchability (2,316 S/cm at a strain of 500%) and repeatability (ΔR/R <3% after 10,000 cycles), which can satisfy most electrical applications in extreme deformations. This strategy not only overcomes large surface tension of liquid metal but also avoids the undesirable sintering of its particles by stress in deformations, such that stretchable conductors can form on various substrates with high resolution (15 μm), high throughput (∼2,000 samples/hour), and low cost (one-quarter price of silver). We use these conductors for stretchable circuits, motion sensors, wearable glove keyboards, and electroporation of live cells
Tunable Dirac Fermion Dynamics in Topological Insulators
Three-dimensional topological insulators are characterized by insulating bulk
state and metallic surface state involving Dirac fermions that behave as
massless relativistic particles. These Dirac fermions are responsible for
achieving a number of novel and exotic quantum phenomena in the topological
insulators and for their potential applications in spintronics and quantum
computations. It is thus essential to understand the electron dynamics of the
Dirac fermions, i.e., how they interact with other electrons, phonons and
disorders. Here we report super-high resolution angle-resolved photoemission
studies on the Dirac fermion dynamics in the prototypical Bi2(Te,Se)3
topological insulators. We have directly revealed signatures of the
electron-phonon coupling in these topological insulators and found that the
electron-disorder interaction is the dominant factor in the scattering process.
The Dirac fermion dynamics in Bi2(Te3-xSex) topological insulators can be tuned
by varying the composition, x, or by controlling the charge carriers. Our
findings provide crucial information in understanding the electron dynamics of
the Dirac fermions in topological insulators and in engineering their surface
state for fundamental studies and potential applications.Comment: 14 Pages, 4 Figure
Extraction of Electron Self-Energy and Gap Function in the Superconducting State of Bi_2Sr_2CaCu_2O_8 Superconductor via Laser-Based Angle-Resolved Photoemission
Super-high resolution laser-based angle-resolved photoemission measurements
have been performed on a high temperature superconductor Bi_2Sr_2CaCu_2O_8. The
band back-bending characteristic of the Bogoliubov-like quasiparticle
dispersion is clearly revealed at low temperature in the superconducting state.
This makes it possible for the first time to experimentally extract the complex
electron self-energy and the complex gap function in the superconducting state.
The resultant electron self-energy and gap function exhibit features at ~54 meV
and ~40 meV, in addition to the superconducting gap-induced structure at lower
binding energy and a broad featureless structure at higher binding energy.
These information will provide key insight and constraints on the origin of
electron pairing in high temperature superconductors.Comment: 4 pages, 4 figure
Covalent Organic Framework (COF) derived Ni-N-C Catalysts for Electrochemical CO<sub>2</sub> Reduction: Unraveling Fundamental Kinetic and Structural Parameters of the Active Sites
Electrochemical CO2 reduction is a potential approach to convert CO2 into valuable chemicals using electricity as feedstock. Abundant and affordable catalyst materials are needed to upscale this process in a sustainable manner. Nickel-nitrogen-doped carbon (Ni-N-C) is an efficient catalyst for CO2 electro-reduction to CO, and the single-site Ni-Nx motif is believed as the active site. However, critical metrics for its catalytic activity, such as active site density and intrinsic turnover frequency, so far lack systematic discussion. In this work, we prepared a set of covalent organic framework (COF)-derived Ni-N-C catalysts, for which the Ni-Nx content could be adjusted by the pyrolysis temperature. The combination of high-angle annular dark-field scanning transmission electron microscopy and extended X-ray absorption fine structure evidenced the presence of Ni single-sites, and quantitative X-ray photoemission addressed the relation between active site density and turnover frequency
Covalent Organic Framework (COF) derived Ni-N-C Catalysts for Electrochemical CO<sub>2</sub> Reduction: Unraveling Fundamental Kinetic and Structural Parameters of the Active Sites
Electrochemical CO2 reduction is a potential approach to convert CO2 into valuable chemicals using electricity as feedstock. Abundant and affordable catalyst materials are needed to upscale this process in a sustainable manner. Nickel-nitrogen-doped carbon (Ni-N-C) is an efficient catalyst for CO2 electro-reduction to CO, and the single-site Ni-Nx motif is believed as the active site. However, critical metrics for its catalytic activity, such as active site density and intrinsic turnover frequency, so far lack systematic discussion. In this work, we prepared a set of covalent organic framework (COF)-derived Ni-N-C catalysts, for which the Ni-Nx content could be adjusted by the pyrolysis temperature. The combination of high-angle annular dark-field scanning transmission electron microscopy and extended X-ray absorption fine structure evidenced the presence of Ni single-sites, and quantitative X-ray photoemission addressed the relation between active site density and turnover frequency
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