Current rectification by asymmetric molecules: An ab initio study

We study current rectification effect in an asymmetric molecule HOOC-C$_6$H$_4$-(CH$_2$)$_n$ sandwiched between two Aluminum electrodes using an {\sl ab initio} nonequilibrium Green function method. The conductance of the system decreases exponentially with the increasing number $n$ of CH$_2$. The phenomenon of current rectification is observed such that a very small current appears at negative bias and a sharp negative differential resistance at a critical positive bias when $n\ge 2$. The rectification effect arises from the asymmetric structure of the molecule and the molecule-electrode couplings. A significant rectification ratio of $\sim$38 can be achieved when $n=5$.Comment: to appear in J. Chem. Phy

Multiparty quantum secret splitting and quantum state sharing

A protocol for multiparty quantum secret splitting is proposed with an ordered $N$ EPR pairs and Bell state measurements. It is secure and has the high intrinsic efficiency and source capacity as almost all the instances are useful and each EPR pair carries two bits of message securely. Moreover, we modify it for multiparty quantum state sharing of an arbitrary $m$-particle entangled state based on quantum teleportation with only Bell state measurements and local unitary operations which make this protocol more convenient in a practical application than others.Comment: 7 pages, 1 figure. The revision of the manuscript appeared in PLA. Some procedures for detecting cheat have been added. Then the security loophole in the original manuscript has been eliminate