40,245 research outputs found
Ion specificity and the theory of stability of colloidal suspensions
A theory is presented which allow us to accurately calculate the critical
coagulation concentration (CCC) of hydrophobic colloidal suspensions. For
positively charged particles the CCC's follow the Hofmeister (lyotropic)
series. For negatively charged particles the series is reversed. We find that
strongly polarizable chaotropic anions are driven towards the colloidal surface
by electrostatic and hydrophobic forces. Within approximately one ionic radius
from the surface, the chaotropic anions loose part of their hydration sheath
and become strongly adsorbed. The kosmotropic anions, on the other hand, are
repelled from the hydrophobic surface. The theory is quantitatively accurate
without any adjustable parameters. We speculate that the same mechanism is
responsible for the Hofmeister series that governs stability of protein
solutions.Comment: Phys. Rev. Lett. (in press
A More Precise Extraction of |V_{cb}| in HQEFT of QCD
The more precise extraction for the CKM matrix element |V_{cb}| in the heavy
quark effective field theory (HQEFT) of QCD is studied from both exclusive and
inclusive semileptonic B decays. The values of relevant nonperturbative
parameters up to order 1/m^2_Q are estimated consistently in HQEFT of QCD.
Using the most recent experimental data for B decay rates, |V_{cb}| is updated
to be |V_{cb}| = 0.0395 \pm 0.0011_{exp} \pm 0.0019_{th} from B\to D^{\ast} l
\nu decay and |V_{cb}| = 0.0434 \pm 0.0041_{exp} \pm 0.0020_{th} from B\to D l
\nu decay as well as |V_{cb}| = 0.0394 \pm 0.0010_{exp} \pm 0.0014_{th} from
inclusive B\to X_c l \nu decay.Comment: 7 pages, revtex, 4 figure
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Numerical simulation of viscous fingering phenomenon in immiscible displacement of two fluids in porous media using Lattice Boltzmann method
This paper was presented at the 2nd Micro and Nano Flows Conference (MNF2009), which was held at Brunel University, West London, UK. The conference was organised by Brunel University and supported by the Institution of Mechanical Engineers, IPEM, the Italian Union of Thermofluid dynamics, the Process Intensification Network, HEXAG - the Heat Exchange Action Group and the Institute of Mathematics and its Applications.In the present study, viscous fingering phenomenon, which occurs when a less viscous fluid (e.g. supercritical carbon dioxide) is injected into simplified porous media to displace a more viscous fluid (e.g. crude oil), is investigated by a mesoscopic approach-the lattice Boltzmann method (LBM). Due to its convenience in dealing with complex fluids of different viscosities, the pseudo-potential model is employed to study the effects of the capillary number, Bond number and viscosity ratio between the displaced fluids and displacing fluid; as such effects reflect the competition of viscous force and surface tension and gravity
forces during viscous fingering. The numerical procedure is validated against a series of droplet tests, in which surface tension can be determined. By changing the injecting velocity of the displacing fluid and gravitational acceleration, the displacement processes under conditions of different capillary number and Bond number are investigated. The finger pattern is presented in this paper. The effects of capillary number, Bond number and viscosity ratio are discussed in detail. The ability and suitability of the lattice Boltzmann
method for simulating multi-component fluids displacement in porous media are proved in our work.This work is supported by China Scholarship Council (CSC)
Density matrix renormalization group study of conjugated polymers with transverse pi-conjugation
We report accurate numerical studies of excited state orderings in long
hypothetical pi-conjugated oligomers in which the hydrogen atoms of
trans-polyacetylene are replaced with conjugated sidegroups, within modified
Hubbard models. There exists a range of the bare Coulomb repulsion for which
the excited state ordering is conducive to photoluminescence in the substituted
systems, even as this ordering is opposite in the unsubstituted polyenes of the
same lengths. Our work provides motivation to study real pi-conjugated polymers
with transverse conjugation and small optical gaps.Comment: 5 pages, 4 fig
Developing and applying an integrated modular design methodology within a SME
Modularity within a product can bring advantages to the design process by facilitating enhanced design reuse, reduced lead times, decreased cost and higher levels of quality. While the benefits of modularity are becoming increasingly better known, at present it is usually left to the designers themselves to introduce modularity into products. Studies into modularity have shown that byimplementing 'formal' methods, further benefits can be made in terms of time, cost, quality and performance. Current approaches that have been proposed for the formal development of modular design methodologies fail to accurately represent knowledge that is inherently produced during design projects and fail to consider design from the different viewpoints of the development process. This work, built on previous work on modularity and design for reuse, aims to develop an integrated design methodology that will optimise the modules created through the design process and allow for modularity to be 'built-in' to product development from the initial stages. The methodology andassociated tools have been developed to provide an easy-to-use approach to modularity that has support for design rationales and company knowledge that aid in effective design decision making. The methodology, named GeMoCURE, provides an integrated total solution to modular design based on reuse of proven physical and knowledge modules. Its incremental nature allows for the optimalstructure to be maintained as the design progresses. A special focus has been on the application of this approach for Small to Medium Enterprises (SMEs), which are typically challenged by a lack of design human resources and expertise
Boiling a Unitary Fermi Liquid
We study the thermal evolution of a highly spin-imbalanced, homogeneous Fermi
gas with unitarity limited interactions, from a Fermi liquid of polarons at low
temperatures to a classical Boltzmann gas at high temperatures. Radio-frequency
spectroscopy gives access to the energy, lifetime, and short-range correlations
of Fermi polarons at low temperatures . In this regime, we observe a
characteristic dependence of the spectral width, corresponding to the
quasiparticle decay rate expected for a Fermi liquid. At high , the spectral
width decreases again towards the scattering rate of the classical, unitary
Boltzmann gas, . In the transition region between the quantum
degenerate and classical regime, the spectral width attains its maximum, on the
scale of the Fermi energy, indicating the breakdown of a quasiparticle
description. Density measurements in a harmonic trap directly reveal the
majority dressing cloud surrounding the minority spins and yield the
compressibility along with the effective mass of Fermi polarons.Comment: Accepted version at PR
Spin Polarisability of the Nucleon in the Heavy Baryon Effective Field Theory
We have constructed a heavy baryon effective field theory with photon as an
external field in accordance with the symmetry requirements similar to the
heavy quark effective field theory. By treating the heavy baryon and
anti-baryon equally on the same footing in the effective field theory, we have
calculated the spin polarisabilities of the nucleon at
third order and at fourth-order of the spin-dependent Compton scattering. At
leading order (LO), our results agree with the corresponding results of the
heavy baryon chiral perturbation theory, at the next-to-leading order(NLO) the
results show a large correction to the ones in the heavy baryon chiral
perturbation theory due to baryon-antibaryon coupling terms. The low energy
theorem is satisfied both at LO and at NLO. The contributions arising from the
heavy baryon-antibaryon vertex were found to be significant and the results of
the polarisabilities obtained from our theory is much closer to the
experimental data.Comment: 21pages, title changed, minimal correction
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