Origin of second-harmonic generation in the incommensurate phase of K2SeO4

We show that a ferroelectric phase transition takes place in the incommensurate phase of the K2SeO4 crystal. The ferroelectric character of the IC phase explains the second-harmonic generation observed in the corresponding temperature range.Comment: 5 pages, 1 figur

Comment on "On the TST_S-Anomaly in Betaine Calcium Chloride Dihydrate"

Recently, Hlinka and Ishibashi [J. Phys. Soc. Jpn. 67, 495 (1998)] discussed the $T_S$-anomaly in betaine calcium chloride dihydrate (BCCD) in a Landau-type approach. We comment on the shortcomings of this approach and discuss the $T_S$-anomaly in the framework of a microscopical pseudo spin model based on a realistic description of BCCD in terms of symmetry-adapted local modes.Comment: 2 pages, RevTex, submitted to J. Phys. Soc. Jp

Landau Model for Commensurate-Commensurate Phase Transitions in Uniaxial Improper Ferroelectric Crystals

We propose the Landau model for lock-in phase transitions in uniaxially modulated improper ferroelectric incommensurate-commensurate systems of class I. It includes Umklapp terms of third and fourth order and secondary order parameter representing the local polarization. The corresponding phase diagram has the structure of harmless staircase, with the allowed wave numbers obeying the Farey tree algorithm. Among the stable commensurate phases only those with periods equal to odd number of lattice constants have finite macroscopic polarizations. These results are in excellent agreement with experimental findings in some A2BX4 compounds.Comment: 9 pages, 5 figures, revtex, to be published in Journal of Physics: Cond. Matter as a Letter to the Edito

Collective modes in uniaxial incommensurate-commensurate systems with the real order parameter

The basic Landau model for uniaxial systems of the II class is nonintegrable, and allows for various stable and metastable periodic configurations, beside that representing the uniform (or dimerized) ordering. In the present paper we complete the analysis of this model by performing the second order variational procedure, and formulating the combined Floquet-Bloch approach to the ensuing nonstandard linear eigenvalue problem. This approach enables an analytic derivation of some general conclusions on the stability of particular states, and on the nature of accompanied collective excitations. Furthermore, we calculate numerically the spectra of collective modes for all states participating in the phase diagram, and analyze critical properties of Goldstone modes at all second order and first order transitions between disordered, uniform and periodic states. In particular it is shown that the Goldstone mode softens as the underlying soliton lattice becomes more and more dilute.Comment: 19 pages, 16 figures, REVTeX, to be published in Journal of Physics A: Mathematical and Genera

Landau model for uniaxial systems with complex order parameter

We study the Landau model for uniaxial incommensurate-commensurate systems of the I class by keeping Umklapp terms of third and fourth order in the expansion of the free energy. It applies to systems in which the soft mode minimum lies between the corresponding commensurate wave numbers. The minimization of the Landau functional leads to the sine-Gordon equation with two nonlinear terms, equivalent to the equation of motion for the well-known classical mechanical problem of two mixing resonances. We calculate the average free energies for periodic, quasiperiodic and chaotic solutions of this equation, and show that in the regime of finite strengths of Umklapp terms only periodic solutions are absolute minima of the free energy, so that the phase diagram contains only commensurate configurations. The phase transitions between neighboring configurations are of the first order, and the wave number of ordering goes through harmless staircase with a finite number of steps. These results are the basis for the interpretation of phase diagrams for some materials from the I class of incommensurate-commensurate systems, in particular of those for A$_2$BX$_4$ and BCCD compounds. Also, we argue that chaotic barriers which separate metastable periodic solutions represent an intrinsic mechanism for observed memory effects and thermal hystereses.Comment: 12 pages, 14 figures, LaTeX, to be published in Phys. Rev.

Universal mechanism of discontinuity of commensurate-incommensurate transitions in three-dimensional solids: Strain dependence of soliton self-energy

We show that there exists a universal mechanism of long-range soliton attraction in three-dimensional solids and, therefore, of discontinuity of any commensurate-incommensurate (C-IC) phase transition. This mechanism is due to the strain dependence of the soliton self-energy and specific features of the solid-state elasticity. The role of this mechanism is studied in detail for a class of C-IC transitions where the IC modulation is one-dimensional, the anisotropy in the order parameter space is small, and the symmetry of the systems allows the existence of the Lifshitz invariant. Two other mechanisms of soliton attraction are operative here but the universal mechanism considered in this paper is found to be the most important one in some cases. Comparison with the most extensively studied C-IC transition in $\rm K_2SeO_4$ shows that the experimentally observed thermal anomalies can be understood as a result of the smearing of the theoretically predicted discontinuous transition.Comment: 8 pages (extended version, title changed

Diversity-Oriented Synthesis of Novel Trihalomethyl-Containing Spirochromeno[3,4- a ](thia)pyrrolizidines and Spirochromeno-[3,4- a ]indolizidines by One-Pot, Three-Component [3+2]-Cyclo addition Reaction

Regio- and stereoselective methods for the synthesis of 6′-trifluoro(trichloro)methyl substituted spiro[acenaphthylene-1,11′-chromeno[3,4- a ](thia)pyrrolizidin]-2-ones and spiro[acenaphthylene-1,12′-chromeno[3,4- a ]indolizidin]-2-ones have been developed based on the three-component reaction of 3-nitro-2-trifluoro(trichloro)methyl-2 H -chromenes with azomethine ylides generated in situ from acenaphthenequinone and cyclic α-amino acids. The cycloaddition proceeds under mild conditions in ethanol or DMSO, and only endo -isomers of the products with cis -arrangement of nitro and trifluoromethyl groups are formed. The relative configuration of cycloadducts is reliably confirmed by X-ray diffraction analysis and by 2D NOESY spectroscopy. © 2021 Georg Thieme Verlag. All rights reserved.The work was financially supported by the Russian Foundation for Basic Research (grant 20-03-00716) and by the Ministry of Science and Higher Education of the Russian Federation (project FEUZ-2020-0052)

DOPING NANOSTRUCTURED ALUMINA BY MANGANESE AND INVESTIGATION OF ITS LUMINESCENT PROPERTIES

The nanostructured aluminium oxide doped manganese are synthesized at different annealing temperature and concentration of impurity. Pulse cathodoluminescence of obtained samples are measured. An increase in the concentration of dopant causes quenching of the luminescence of chromium ions