Variations in radiocarbon ages of various organic fractions in core sediments from Erhai Lake, SW China

Radiocarbon dating was performed for the extracted organic fractions (cellulose-rich and humic acid fractions of plant fragment; fulvic acid, humic acid and humin fractions of humus substance) and shell from core sediments of the Erhai Lake, SW China. The C-14 dating results reveal that there are considerable differences, but there apparently is a humic acid less than or equal to humin < fulvic acid fraction sequence of C-14 age increase. The variability in radiocarbon ages of organic fraction of lake sediment suggests that special caution is necessary when radiocarbon ages of bulk sediments are used. The linear correlation between C-14 age of allochthonous terrestrial macrofossil (plant fragment and shell) and depth indicates roughly a constant sedimentation rate of ca. 0.7 rum yr(-1) in central Erhai Lake since 4500 yr BP. The C-14 ages of the autochthonous humic acid fraction are 210similar to4800 yr shift from "the true C-14 age" obtained by interpolating the corresponding horizontal level to the above C-14 age-depth correlation. Such age difference may be alternatively attributed to a uniform reservoir effect (most likely ca. 300 yr). The period with large C-14 age shift synchronizes with the period of changes in (delta(13)C and ARM intensity and ARM/susceptibility values

The polymeric conformational effect on capacitive deionization performance of graphene oxide/polypyrrole composite electrode

Exploitation of novel faradic materials is an alternative implementation for solving the problem of poor specific electrosorption capacity that conventional carbon materials are encountered in capacitive deionization. Particularly, composite electrode is just a suitable choice because of its potentially high ion-storage ability. Herein, a cyclic voltammetric treatment method with different low limit of potential window was used to manipulate the polymeric conformation and doping level of graphene oxide/polypyrrole (GO/PPy) composite electrode. Based on it, the effect of polymeric structure on the electrosorption performance was systematically studied. When the low limit of potential window is shifted negatively enough, the irreversible polymeric conformational shrinks of GO/PPy are promoted, which not only hinders the insertion process of ions, but also decreases the doping level of polymer due to the intensive interchain-action produced by more entangled polymeric chain. Thus, the number of intercalated ions should decrease, which is expressed by electrochemical impedance spectroscopy (EIS) results and is proportional to the electrosorption capacity of GO/PPy composite electrode in membrane capacitive deionization (MCDI) process. Our work suggests that the less packing density, higher doping level and more charge delocalization on PPy backbone in electrode are beneficial to enhance its capacitive deionization performance

News on PHOTOS Monte Carlo: gamma^* -> pi^+ pi^-(gamma) and K^\pm -> pi^+ pi^- e^\pm nu (gamma)

PHOTOS Monte Carlo is widely used for simulating QED effects in decay of intermediate particles and resonances. It can be easily connected to other main process generators. In this paper we consider decaying processes gamma^* -> pi^+ pi^-(gamma) and K^\pm -> pi^+ pi^- e^\pm nu (gamma) in the framework of Scalar QED. These two processes are interesting not only for the technical aspect of PHOTOS Monte Carlo, but also for precision measurement of alpha_{QED}(M_Z), g-2, as well as pi pi scattering lengths.Comment: 6 pages, 11 figures, proceedings of the PhiPsi09, Oct. 13-16, 2009, Beijing, Chin