Multi-layer configuration for the cathode electrode of polymer electrolyte fuel cell

This paper conducts a one-dimensional theoretical study on the electrochemical phenomenon in the dual-layer cathode electrode of polymer electrolyte fuel cells (PEFCs) with varying sub-layer thicknesses, and further extends the analysis to a triple-layer configuration. We obtain the explicit solution for a general dual-layer configuration with different layer thicknesses. Distributions of the key quantities such as the local reaction current and electrolyte overpotential are exhibited at different ratios of the ionic conductivities, electrochemical kinetics, and layer thicknesses. Based on the dual-layer approach, we further derive the explicit solutions for a triple-layer electrode. Sub-layer performances are plotted and compared. The results indicate that the layer adjacent to the electrolyte membrane may contribute a major part of the electrode faradic current production. The theoretical analysis presented in this paper can be applied to assist electrode development through complicated multi-layer configuration for cost-effective high performance electrodes. © 2010 Elsevier Ltd

The structure and magnetism of graphone

Graphone is a half-hydrogenated graphene. The structure of graphone is illustrated as trigonal adsorption of hydrogen atoms on graphene at first. However, we found the trigonal adsorption is unstable. We present an illustration in detail to explain how a trigonal adsorption geometry evolves into a rectangular adsorption geometry. We check the change of magnetism during the evolution of geometry by evaluating the spin polarization of the intermediate geometries. We prove and clarify that the rectangular adsorption of hydrogen atoms on graphene is the most stable geometry of graphone and graphone is actually antiferromagnetic.Comment: 11 pages, 4 figure

Experimentally realizable control fields in quantum Lyapunov control

As a hybrid of techniques from open-loop and feedback control, Lyapunov control has the advantage that it is free from the measurement-induced decoherence but it includes the system's instantaneous message in the control loop. Often, the Lyapunov control is confronted with time delay in the control fields and difficulty in practical implementations of the control. In this paper, we study the effect of time-delay on the Lyapunov control, and explore the possibility of replacing the control field with a pulse train or a bang-bang signal. The efficiency of the Lyapunov control is also presented through examining the convergence time of the controlled system. These results suggest that the Lyapunov control is robust gainst time delay, easy to realize and effective for high-dimensional quantum systems

Measuring dynamic oil film coefficients of sliding bearing

A method is presented for determining the dynamic coefficients of bearing oil film. By varying the support stiffness and damping, eight dynamic coefficients of the bearing were determined. Simple and easy to apply, the method can be used in solving practical machine problems

Spin-current diode with a ferromagnetic semiconductor

Diode is a key device in electronics: the charge current can flow through the device under a forward bias, while almost no current flows under a reverse bias. Here we propose a corresponding device in spintronics: the spin-current diode, in which the forward spin current is large but the reversed one is negligible. We show that the lead/ferromagnetic quantum dot/lead system and the lead/ferromagnetic semiconductor/lead junction can work as spin-current diodes. The spin-current diode, a low dissipation device, may have important applications in spintronics, as the conventional charge-current diode does in electronics.Comment: 5 pages, 3 figure

The spin-polarized ν=0\nu=0 state of graphene: a spin superconductor

We study the spin-polarized $\nu=0$ Landau-level state of graphene. Due to the electron-hole attractive interaction, electrons and holes can bound into pairs. These pairs can then condense into a spin-triplet superfluid ground state: a spin superconductor state. In this state, a gap opens up in the edge bands as well as in the bulk bands, thus it is a charge insulator, but it can carry the spin current without dissipation. These results can well explain the insulating behavior of the spin-polarized $\nu=0$ state in the recent experiments.Comment: 6 pages, 4 figure

Effect factors of part-load performance for various Organic Rankine cycles using in engine waste heat recovery

The Organic Rankine Cycle (ORC) is regarded as one of the most promising waste heat recovery technologies for electricity generation engines. Since the engine usually operates under different working conditions, it is important to research the part-load performance of the ORC. In order to reveal the effect factors of part-load performance, four different forms of ORCs are compared in the study with dynamic math models established in SIMULINK. They are the ORC applying low temperature working fluid R245fa with a medium heat transfer cycle, the ORCs with high temperature working fluid toluene heated directly by exhaust condensing at low pressure and high pressure, and the double-stage ORC. It is regarded that the more slowly the system output power decreases, the better part-load performance it has. Based on a comparison among the four systems, the effects of evaporating pressure, condensing condition, working fluid, and system structure on part-load performance are revealed in the work. Further, it is found that the system which best matches with the heat source not only performs well under the design conditions, but also has excellent part-load performance