Dopant site selectivity in BaCe0.85M0.15O3-δ by extended x-ray absorption fine structure

Rare earth doped BaCeO3 has been widely investigated as a proton conducting material. Trivalent dopants are generally assumed to fully occupy the Ce4+-site, and thereby introduce oxygen vacancies into the perovskite structure. Recent studies indicate the possibility of partial dopant incorporation onto the Ba2+-site concomitant with BaO evaporation, reducing the oxygen vacancy content. Because proton incorporation requires, as a first step, the generation of oxygen vacancies such dopant partitioning is detrimental to protonic conductivity. A quantitative Extended X-ray Absorption Fine Structure (EXAFS) study of BaCe0.85M0.15O3-δ (M=Yb,Gd) is presented here along with complementary x-ray powder diffraction and electron probe chemical analyses. The EXAFS results demonstrate that as much as 4.6% of the ytterbium and 7.2% of the gadolinium intended for incorporation onto the Ce site, in fact, resides on the Ba site. The results are in qualitative agreement with the diffraction and chemical analyses, which additionally show an even greater extent of Nd incorporation on the Ba site

Precise near-earth navigation with GPS: A survey of techniques

The tracking accuracy of the low earth orbiters (below about 3000 km altitude) can be brought below 10 cm with a variety of differential techniques that exploit the Global Positioning System (GPS). All of these techniques require a precisely known global network of GPS ground receivers and a receiver aboard the user satellite, and all simultaneously estimate the user and GPS satellite orbits. Three basic approaches are the geometric, dynamic, and nondynamic strategies. The last combines dynamic GPS solutions with a geometric user solution. Two powerful extensions of the nondynamic strategy show considerable promise. The first uses an optimized synthesis of dynamics and geometry in the user solution, while the second uses a novel gravity-adjustment method to exploit data from repeat ground tracks. These techniques will offer sub-decimeter accuracy for dynamically unpredictable satellites down to the lowesst possible altitudes

Charge pumping in monolayer graphene driven by a series of time-periodic potentials

We applied the Floquet scattering-matrix formalism to studying the electronic transport properties in a mesoscopic Dirac system. Using the method, we investigate theoretically quantum pumping driven by a series of time-periodic potentials in graphene monolayer both in the adiabatic and non-adiabatic regimes. Our numerical results demonstrate that adding harmonic modulated potentials can break the time reversal symmetry when no voltage bias is applied to the graphene monolayer. Thus, when the system is pumped with proper dynamic parameters, these scatterers can produce a nonzero dc pumped current. We also find that the transmission is anisotropic as the incident angle is changed.Comment: 8 pages, 6 figure

Dual Fabry-Perot filter for measurement of CO rotational spectra: design and application to the CO spectrum of Venus

We present the design of a harmonic resonant filter that can be used with a Fourier transform spectrometer (FTS) for simultaneous measurement of a series of lines in the CO rotational ladder. To enable studies of both broad CO absorptions in Venus and modestly red-shifted CO emission from external galaxies, relatively broad (approximately 10-30-GHz FWHM) transmission passbands are desirable. Because a single low-finesse Fabry Perot (FP) etalon has insufficient interline rejection, a dual-FP etalon was considered. Such a design provides significantly better interband rejection and somewhat more flattopped transmission spikes. A prototype filter of this type, made of two thin silicon disks spaced by an air gap, has been constructed and used with our FTS at the Caltech Submillimeter Observatory for simultaneous measurement of the four submillimeter CO transitions in the atmosphere of Venus that are accessible from the ground