Thermodynamics of gas–liquid colloidal equilibrium states: hetero-phase fluctuations

Following on from two previous JETC (Joint European Thermodynamics Conference) presentations, we present a preliminary report of further advances towards the thermodynamic description of critical behavior and a supercritical gas-liquid coexistence with a supercritical fluid mesophase defined by percolation loci. The experimental data along supercritical constant temperature isotherms (T >= T-c) are consistent with the existence of a two-state mesophase, with constant change in pressure with density, rigidity, (dp/d rho) (T), and linear thermodynamic state-functions of density. The supercritical mesophase is bounded by 3rd-order phase transitions at percolation thresholds. Here we present the evidence that these percolation transitions of both gaseous and liquid states along any isotherm are preceded by pre-percolation hetero-phase fluctuations that can explain the thermodynamic properties in the mesophase and its vicinity. Hetero-phase fluctuations give rise to one-component colloidal-dispersion states; a single Gibbs phase retaining 2 degrees of freedom in which both gas and liquid states with different densities percolate the phase volume. In order to describe the thermodynamic properties of two-state critical and supercritical coexistence, we introduce the concept of a hypothetical homo-phase of both gas and liquid, defined as extrapolated equilibrium states in the pre-percolation vicinity, with the hetero-phase fractions subtracted. We observe that there can be no difference in chemical potential between homo-phase liquid and gaseous states along the critical isotherm in mid-critical isochoric experiments when the meniscus disappears at T = T-c. For T > T-c, thermodynamic states comprise equal mole fractions of the homo-phase gas and liquid, both percolating the total phase volume, at the same temperature, pressure, and with a uniform chemical potential, stabilised by a positive finite interfacial surface tension.info:eu-repo/semantics/publishedVersio

Medicare Advantage Special Needs Plans for Dual Eligibles: A Primer

Identifies the key issues behind the goal of a new plan for people eligible for both Medicare and Medicaid -- to offer the full array of Medicare, Medicaid, and supplemental benefits through a single plan -- and outlines progress thus far

Mars transfer vehicle studies

Earth-to-Mars distances vary from 60 to 400 million kilometers over a 14-year cycle. This complicates Mars mission design as a function of calendar time. Stay times at Mars are also strongly driven by opportunities for a return flight path which are within the limits of delta-V associated with practical space vehicles. The biggest difference between Mars and lunar transfer missions is mission time, which grows from a few days for the moon, to as much as a few hundred days for Mars missions. As a result, modules for similarly sized crews must be much larger for Mars missions that for transfer to lunar orbit. Technology challenges for one Mars mission scenario analyzed by Boeing include aerobrakes, propulsion, and life support systems. Mission performance is very sensitive to aerobrake weight fraction and, as a result, there is an incentive to use high performance materials such as advanced composites and thermal protection systems. Lander aerobrake would be used twice (for both planetary capture and descent to the Mars surface), and it would need to survive temperatures up to 3500 degrees

Match Effects

We present an empirical model of earnings that controls for observable and unobservable characteristics of workers (person effects), unmeasured characteristics of their employers (firm effects), and unmeasured characteristics of worker-firm matches (match effects). We interpret these as the returns to general human capital, firm-specific human capital, and match-specific human capital, respectively. We stress the importance of match effects because the returns to match-specific human capital will be incorrectly attributed to general and/or firm-specific human capital when match effects are omitted, and because general and specific human capital have very different implications for the economic cost of job destruction. We find that slightly more than half of observed variation in log earnings is attributable to general human capital, 22 percent is attributable to firm-specific human capital, and 16 percent to match-specific human capital. Specifications that omit match effects over-estimate the returns to experience by as much as 50 percent, over-estimate the returns to a college education by as much as 8 percent, attribute too much variation to person effects, and too little to firm effects. Our results suggest that considerable earnings variation previously attributed to general human capital -- both observed and unobserved -- is in fact attributable to workers sorting into higher-paying firms and better worker-firm matches.human capital; fixed effects; mixed effects; person and firm effects; linked employer-employee data

Wage Differentials in the Presence of Unobserved Worker, Firm, and Match Heterogeneity

We consider the problem of estimating and decomposing wage differentials in the presence of unobserved worker, firm, and match heterogeneity. Controlling for these unobservables corrects omitted variable bias in previous studies. It also allows us to measure the contribution of unmeasured characteristics of workers, firms, and worker-firm matches to observed wage differentials. An application to linked employer-employee data shows that decompositions of inter-industry earnings differentials and the male-female differential are misleading when unobserved heterogeneity is ignored.wage differentials; unobserved heterogeneity; employer-employee data

Electrical power integration for lunar operations

Electrical power for future lunar operations is expected to range from a few kilowatts for an early human outpost to many megawatts for industrial operations in the 21st century. All electrical power must be imported as chemical, solar, nuclear, or directed energy. The slow rotation of the Moon and consequent long lunar night impose severe mass penalties on solar systems needing night delivery from storage. The cost of power depends on the cost of the power systems the cost of its transportation to the Moon, operating cost, and, of course, the life of the power system. The economic feasibility of some proposed lunar ventures depends in part on the cost of power. This paper explores power integration issues, costs, and affordability in the context of the following representative lunar ventures: (1) early human outpost (10 kWe); (2) early permanent lunar base, including experimental ISMU activities (100 kWe); (3) lunar oxygen production serving an evolved lunar base (500 kWe); (4) lunar base production of specialized high-value products for use on Earth (5 kWe); and (5) lunar mining and production of helium-3 (500 kWe). The schema of the paper is to project likely costs of power alternatives (including integration factors) in these power ranges, to select the most economic, to determine power cost contribution to the product or activities, to estimate whether the power cost is economically acceptable, and, finally, to offer suggestions for reaching acceptability where cost problems exist

iPod therefore I am: Using PC Videos to Aid the Teaching of the History of Political Philosophy

This article outlines our experiences at the University of Huddersfield of (a) producing and using mini-lectures on the history of political philosophy that were available to students as MP4 and progressive download PC video files (and MP3 audio files), and (b) the student feedback on these files which will help future development. This article largely avoids pedagogical issues regarding the use of technology in teaching and focuses more on student feedback and use of these technologies, along with practical issues regarding the production and hosting of these teaching tools

Non-linear Group Actions with Polynomial Invariant Rings and a Structure Theorem for Modular Galois Extensions

Let $G$ be a finite $p$-group and $k$ a field of characteristic $p>0$. We show that $G$ has a \emph{non-linear} faithful action on a polynomial ring $U$ of dimension $n=\mathrm{log}_p(|G|)$ such that the invariant ring $U^G$ is also polynomial. This contrasts with the case of \emph{linear and graded} group actions with polynomial rings of invariants, where the classical theorem of Chevalley-Shephard-Todd and Serre requires $G$ to be generated by pseudo-reflections. Our result is part of a general theory of "trace surjective $G$-algebras", which, in the case of $p$-groups, coincide with the Galois ring-extensions in the sense of \cite{chr}. We consider the \emph{dehomogenized symmetric algebra} $D_k$, a polynomial ring with non-linear $G$-action, containing $U$ as a retract and we show that $D_k^G$ is a polynomial ring. Thus $U$ turns out to be \emph{universal} in the sense that every trace surjective $G$-algebra can be constructed from $U$ by "forming quotients and extending invariants". As a consequence we obtain a general structure theorem for Galois-extensions with given $p$-group as Galois group and any prescribed commutative $k$-algebra $R$ as invariant ring. This is a generalization of the Artin-Schreier-Witt theory of modular Galois field extensions of degree $p^s$.Comment: 20 page