6,570 research outputs found

    A structure for maturing intelligent tutoring system student models

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    A special structure is examined for evolving a detached model of the user of an intelligent tutoring system. Tutoring is used in the context of education and training devices. A detached approach to populating the student model data structure is examined in the context of the need for time dependent reasoning about what the student knows about a particular concept in the domain of interest. This approach, to generating a data structure for the student model, allows an inference engine separate from the tutoring strategy determination to be used. This methodology has advantages in environments requiring real-time operation

    Josiah Parsons Cooke Jr.: Epistemology in the Service of Science, Pedagogy, and Natural Theology

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    Josiah Parsons Cooke established chemistry education at Harvard University, initiated an atomic weight research program, and broadly impacted American chemical education through his students, the introduction of laboratory instruction, textbooks, and influence on Harvard's admissions requirements. The devoutly Unitarian Cooke also articulated and defended a biogeochemical natural theology, which he defended by arguing for commonalities between the epistemologies of science and religion. Cooke's pre-Mendeleev classification scheme for the elements and atomic weight research were motivated by his interest in numerical order in nature, which reflected his belief in a divine lawgive

    Tools for Verifying Classical and Quantum Superintegrability

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    Recently many new classes of integrable systems in n dimensions occurring in classical and quantum mechanics have been shown to admit a functionally independent set of 2n-1 symmetries polynomial in the canonical momenta, so that they are in fact superintegrable. These newly discovered systems are all separable in some coordinate system and, typically, they depend on one or more parameters in such a way that the system is superintegrable exactly when some of the parameters are rational numbers. Most of the constructions to date are for n=2 but cases where n>2 are multiplying rapidly. In this article we organize a large class of such systems, many new, and emphasize the underlying mechanisms which enable this phenomena to occur and to prove superintegrability. In addition to proofs of classical superintegrability we show that the 2D caged anisotropic oscillator and a Stackel transformed version on the 2-sheet hyperboloid are quantum superintegrable for all rational relative frequencies, and that a deformed 2D Kepler-Coulomb system is quantum superintegrable for all rational values of a parameter k in the potential

    Three-body problem in 3D space: ground state, (quasi)-exact-solvability

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    We study aspects of the quantum and classical dynamics of a 33-body system in 3D space with interaction depending only on mutual distances. The study is restricted to solutions in the space of relative motion which are functions of mutual distances only. It is shown that the ground state (and some other states) in the quantum case and the planar trajectories in the classical case are of this type. The quantum (and classical) system for which these states are eigenstates is found and its Hamiltonian is constructed. It corresponds to a three-dimensional quantum particle moving in a curved space with special metric. The kinetic energy of the system has a hidden sl(4,R)sl(4,R) Lie (Poisson) algebra structure, alternatively, the hidden algebra h(3)h^{(3)} typical for the H3H_3 Calogero model. We find an exactly solvable three-body generalized harmonic oscillator-type potential as well as a quasi-exactly-solvable three-body sextic polynomial type potential; both models have an extra integral.Comment: 24 pages, Appendix about non-equal masses adde

    Can disorder enhance incoherent exciton diffusion?

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    Recent experiments aimed at probing the dynamics of excitons have revealed that semiconducting films composed of disordered molecular subunits, unlike expectations for their perfectly ordered counterparts, can exhibit a time-dependent diffusivity in which the effective early time diffusion constant is larger than that of the steady state. This observation has led to speculation about what role, if any, microscopic disorder may play in enhancing exciton transport properties. In this article, we present the results of a model study aimed at addressing this point. Specifically, we present a general model, based upon F\"orster theory, for incoherent exciton diffusion in a material composed of independent molecular subunits with static energetic disorder. Energetic disorder leads to heterogeneity in molecule-to-molecule transition rates which we demonstrate has two important consequences related to exciton transport. First, the distribution of local site-specific diffusivity is broadened in a manner that results in a decrease in average exciton diffusivity relative to that in a perfectly ordered film. Second, since excitons prefer to make transitions that are downhill in energy, the steady state distribution of exciton energies is biased towards low energy molecular subunits, those that exhibit reduced diffusivity relative to a perfectly ordered film. These effects combine to reduce the net diffusivity in a manner that is time dependent and grows more pronounced as disorder is increased. Notably, however, we demonstrate that the presence of energetic disorder can give rise to a population of molecular subunits with exciton transfer rates exceeding that of subunits in an energetically uniform material. Such enhancements may play an important role in processes that are sensitive to molecular-scale fluctuations in exciton density field.Comment: 15 pages, 3 figure
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