6,570 research outputs found
A structure for maturing intelligent tutoring system student models
A special structure is examined for evolving a detached model of the user of an intelligent tutoring system. Tutoring is used in the context of education and training devices. A detached approach to populating the student model data structure is examined in the context of the need for time dependent reasoning about what the student knows about a particular concept in the domain of interest. This approach, to generating a data structure for the student model, allows an inference engine separate from the tutoring strategy determination to be used. This methodology has advantages in environments requiring real-time operation
Josiah Parsons Cooke Jr.: Epistemology in the Service of Science, Pedagogy, and Natural Theology
Josiah Parsons Cooke established chemistry education at Harvard University, initiated an atomic weight research program, and broadly impacted American chemical education through his students, the introduction of laboratory instruction, textbooks, and influence on Harvard's admissions requirements. The devoutly Unitarian Cooke also articulated and defended a biogeochemical natural theology, which he defended by arguing for commonalities between the epistemologies of science and religion. Cooke's pre-Mendeleev classification scheme for the elements and atomic weight research were motivated by his interest in numerical order in nature, which reflected his belief in a divine lawgive
Tools for Verifying Classical and Quantum Superintegrability
Recently many new classes of integrable systems in n dimensions occurring in
classical and quantum mechanics have been shown to admit a functionally
independent set of 2n-1 symmetries polynomial in the canonical momenta, so that
they are in fact superintegrable. These newly discovered systems are all
separable in some coordinate system and, typically, they depend on one or more
parameters in such a way that the system is superintegrable exactly when some
of the parameters are rational numbers. Most of the constructions to date are
for n=2 but cases where n>2 are multiplying rapidly. In this article we
organize a large class of such systems, many new, and emphasize the underlying
mechanisms which enable this phenomena to occur and to prove
superintegrability. In addition to proofs of classical superintegrability we
show that the 2D caged anisotropic oscillator and a Stackel transformed version
on the 2-sheet hyperboloid are quantum superintegrable for all rational
relative frequencies, and that a deformed 2D Kepler-Coulomb system is quantum
superintegrable for all rational values of a parameter k in the potential
Three-body problem in 3D space: ground state, (quasi)-exact-solvability
We study aspects of the quantum and classical dynamics of a -body system
in 3D space with interaction depending only on mutual distances. The study is
restricted to solutions in the space of relative motion which are functions of
mutual distances only. It is shown that the ground state (and some other
states) in the quantum case and the planar trajectories in the classical case
are of this type. The quantum (and classical) system for which these states are
eigenstates is found and its Hamiltonian is constructed. It corresponds to a
three-dimensional quantum particle moving in a curved space with special
metric. The kinetic energy of the system has a hidden Lie (Poisson)
algebra structure, alternatively, the hidden algebra typical for the
Calogero model. We find an exactly solvable three-body generalized
harmonic oscillator-type potential as well as a quasi-exactly-solvable
three-body sextic polynomial type potential; both models have an extra
integral.Comment: 24 pages, Appendix about non-equal masses adde
Can disorder enhance incoherent exciton diffusion?
Recent experiments aimed at probing the dynamics of excitons have revealed
that semiconducting films composed of disordered molecular subunits, unlike
expectations for their perfectly ordered counterparts, can exhibit a
time-dependent diffusivity in which the effective early time diffusion constant
is larger than that of the steady state. This observation has led to
speculation about what role, if any, microscopic disorder may play in enhancing
exciton transport properties. In this article, we present the results of a
model study aimed at addressing this point. Specifically, we present a general
model, based upon F\"orster theory, for incoherent exciton diffusion in a
material composed of independent molecular subunits with static energetic
disorder. Energetic disorder leads to heterogeneity in molecule-to-molecule
transition rates which we demonstrate has two important consequences related to
exciton transport. First, the distribution of local site-specific diffusivity
is broadened in a manner that results in a decrease in average exciton
diffusivity relative to that in a perfectly ordered film. Second, since
excitons prefer to make transitions that are downhill in energy, the steady
state distribution of exciton energies is biased towards low energy molecular
subunits, those that exhibit reduced diffusivity relative to a perfectly
ordered film. These effects combine to reduce the net diffusivity in a manner
that is time dependent and grows more pronounced as disorder is increased.
Notably, however, we demonstrate that the presence of energetic disorder can
give rise to a population of molecular subunits with exciton transfer rates
exceeding that of subunits in an energetically uniform material. Such
enhancements may play an important role in processes that are sensitive to
molecular-scale fluctuations in exciton density field.Comment: 15 pages, 3 figure
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