Phase field modeling of electrochemistry II: Kinetics

The kinetic behavior of a phase field model of electrochemistry is explored for advancing (electrodeposition) and receding (electrodissolution) conditions in one dimension. We described the equilibrium behavior of this model in [J. E. Guyer, W. J. Boettinger, J.A. Warren, and G. B. McFadden, ``Phase field modeling of electrochemistry I: Equilibrium'', cond-mat/0308173]. We examine the relationship between the parameters of the phase field method and the more typical parameters of electrochemistry. We demonstrate ohmic conduction in the electrode and ionic conduction in the electrolyte. We find that, despite making simple, linear dynamic postulates, we obtain the nonlinear relationship between current and overpotential predicted by the classical ``Butler-Volmer'' equation and observed in electrochemical experiments. The charge distribution in the interfacial double layer changes with the passage of current and, at sufficiently high currents, we find that the diffusion limited deposition of a more noble cation leads to alloy deposition with less noble species.Comment: v3: To be published in Phys. Rev. E v2: Attempt to work around turnpage bug. Replaced color Fig. 4a with grayscale 13 pages, 7 figures in 10 files, REVTeX 4, SIunits.sty, follows cond-mat/030817

Non-analytical power law correction to the Einstein-Hilbert action: gravitational wave propagation

We analyze the features of the Minkowskian limit of a particular non-analytical f(R) model, whose Taylor expansion in the weak field limit does not hold, as far as gravitational waves (GWs) are concerned. We solve the corresponding Einstein equations and we find an explicit expression of the modified GWs as the sum of two terms, i.e. the standard one and a modified part. As a result, GWs in this model are not transverse, and their polarization is different from that of General Relativity. The velocity of the GW modified part depends crucially on the parameters characterizing the model, and it mostly results much smaller than the speed of light. Moreover, this investigation allows one to further test the viability of this particular f(R) gravity theory as far as interferometric observations of GWs are concerned.Comment: 18 pages, 3 figure

Partial domain wall partition functions

We consider six-vertex model configurations on an n-by-N lattice, n =< N, that satisfy a variation on domain wall boundary conditions that we define and call "partial domain wall boundary conditions". We obtain two expressions for the corresponding "partial domain wall partition function", as an (N-by-N)-determinant and as an (n-by-n)-determinant. The latter was first obtained by I Kostov. We show that the two determinants are equal, as expected from the fact that they are partition functions of the same object, that each is a discrete KP tau-function, and, recalling that these determinants represent tree-level structure constants in N=4 SYM, we show that introducing 1-loop corrections, as proposed by N Gromov and P Vieira, preserves the determinant structure.Comment: 30 pages, LaTeX. This version, which appeared in JHEP, has an abbreviated abstract and some minor stylistic change

Threshold Resonant Structure of the 232Th Neutron-Induced Fission Cross Section

The structures observed in the sub-threshold neutron-induced fission of ^{232}Th were investigated employing a recent developed model. Theoretical single-particle excitations of a phenomenological two-humped barrier are determined by solving a system of coupled differential equations for the motion along the optimal fission path. A rather good agreement with experimental data was obtained using a small number of independent parameters. It is predicted that the structure at 1.4 and 1.6 MeV is mainly dominated by spin 3/2 partial cross-section with small admixture of spin 1/2, while the structure at 1.7 MeV is given by a large partial cross section of spin 5/2.Comment: 17 pages 11 figure

Disseminated bacillus Calmette-Guérin (BCG): a cause of delirium in an older adult

Intra-vesical Bacillus Calmette-Guérin (BCG) immunotherapy is an effective treatment for high-risk bladder cancer. Less well known is that fewer than 1% of patients receiving BCG treatment can develop disseminated BCG. The reaction can range from a mild flu-like illness to a systemic disorder with a fulminant course which in the most severe cases can lead to death. The diagnostic yield is low and diagnosis is often made after a comprehensive exclusion of more common causes of pyrexia of unknown origin. A high level of suspicion is therefore required in those who may be at risk. We report a case of disseminated BCG in an older patient for whom early involvement of his family was pertinent to determining the precipitant for delirium

Understanding light quanta: First quantization of the free electromagnetic field

The quantization of the electromagnetic field in vacuum is presented without reference to lagrangean quantum field theory. The equal time commutators of the fields are calculated from basic principles. A physical discussion of the commutators suggest that the electromagnetic fields are macroscopic emergent properties of more fundamental physical system: the photons

Consequences of critical interchain couplings and anisotropy on a Haldane chain

Effects of interchain couplings and anisotropy on a Haldane chain have been investigated by single crystal inelastic neutron scattering and density functional theory (DFT) calculations on the model compound SrNi$_2$V$_2$O$_8$. Significant effects on low energy excitation spectra are found where the Haldane gap ($\Delta_0 \approx 0.41J$; where $J$ is the intrachain exchange interaction) is replaced by three energy minima at different antiferromagnetic zone centers due to the complex interchain couplings. Further, the triplet states are split into two branches by single-ion anisotropy. Quantitative information on the intrachain and interchain interactions as well as on the single-ion anisotropy are obtained from the analyses of the neutron scattering spectra by the random phase approximation (RPA) method. The presence of multiple competing interchain interactions is found from the analysis of the experimental spectra and is also confirmed by the DFT calculations. The interchain interactions are two orders of magnitude weaker than the nearest-neighbour intrachain interaction $J$ = 8.7~meV. The DFT calculations reveal that the dominant intrachain nearest-neighbor interaction occurs via nontrivial extended superexchange pathways Ni--O--V--O--Ni involving the empty $d$ orbital of V ions. The present single crystal study also allows us to correctly position SrNi$_2$V$_2$O$_8$ in the theoretical $D$-$J_{\perp}$ phase diagram [T. Sakai and M. Takahashi, Phys. Rev. B 42, 4537 (1990)] showing where it lies within the spin-liquid phase.Comment: 12 pages, 12 figures, 3 tables PRB (accepted). in Phys. Rev. B (2015

The Statistics of the Points Where Nodal Lines Intersect a Reference Curve

We study the intersection points of a fixed planar curve $\Gamma$ with the nodal set of a translationally invariant and isotropic Gaussian random field \Psi(\bi{r}) and the zeros of its normal derivative across the curve. The intersection points form a discrete random process which is the object of this study. The field probability distribution function is completely specified by the correlation G(|\bi{r}-\bi{r}'|) = . Given an arbitrary G(|\bi{r}-\bi{r}'|), we compute the two point correlation function of the point process on the line, and derive other statistical measures (repulsion, rigidity) which characterize the short and long range correlations of the intersection points. We use these statistical measures to quantitatively characterize the complex patterns displayed by various kinds of nodal networks. We apply these statistics in particular to nodal patterns of random waves and of eigenfunctions of chaotic billiards. Of special interest is the observation that for monochromatic random waves, the number variance of the intersections with long straight segments grows like $L \ln L$, as opposed to the linear growth predicted by the percolation model, which was successfully used to predict other long range nodal properties of that field.Comment: 33 pages, 13 figures, 1 tabl

A Liquid Model Analogue for Black Hole Thermodynamics

We are able to characterize a 2--dimensional classical fluid sharing some of the same thermodynamic state functions as the Schwarzschild black hole. This phenomenological correspondence between black holes and fluids is established by means of the model liquid's pair-correlation function and the two-body atomic interaction potential. These latter two functions are calculated exactly in terms of the black hole internal (quasilocal) energy and the isothermal compressibility. We find the existence of a ``screening" like effect for the components of the liquid.Comment: 20 pages and 6 Encapsulated PostScript figure

A radiation-like era before inflation

We show that the semiclassical approximation to the Wheeler-DeWitt equation for the minisuperspace of a minimally coupled scalar field in the spatially flat de Sitter Universe prompts the existence of an initial power-law evolution driven by non-adiabatic terms from the gravitational wavefunction which act like radiation. This simple model hence describes the onset of inflation from a previous radiation-like expansion during which the cosmological constant is already present but subleading.Comment: LaTeX, 8 pages, no figures; final version to be published in JCA