Dialkylaluminium 2-imidazolylphenolates: Synthesis, characterization and ring-opening polymerization behavior towards lactides

The stoichiometric reaction of the 2-imidazolylphenols (L1–L9) with the trialkylaluminium reagents AlR₃ (R = Me, Et and iBu), afforded the corresponding dialkylaluminium 2-imidazolylphenolate complexes [R₂Al(L1–L9)] (C1–C11), which were characterized by ¹H/¹³C NMR spectroscopy and by elemental analysis. The molecular structures of the representative complexes C1, C2, C4, C6 and C11 were determined by single-crystal X-Ray diffraction, and revealed a distorted tetrahedral geometry at aluminum. These dialkylaluminium 2-imidazolylphenolates (C1–C11) could efficiently catalyze the ring-opening polymerization of lactides to afford high molecular weight polylactide, both in the presence and absence of BnOH, and as such represent rare examples of the use of bi-dentate ligation at aluminum in such lactide polymerization systems. On the basis of the polymerization results for l-lactide, d-lactide and rac-lactide, the nature of the ligands and the aluminum bound alkyls were found to significantly affect the catalytic activity as well as the properties of the resultant polylactides

Relationship between CYP1A1 polymorphisms and invasion and metastasis of breast cancer

AbstractObjectiveTo investigate the relationship between CYP1A1 genetic polymorphisms and the invasion and metastasis of breast cancer.MethodsThe CYP1A1 gene polymorphism (an T-C transversion at nucleotide position 3801) was detected by the polymerase chain reaction and restriction fragment length polymorphism in 80 cases with breast cancer and 60 samples of normal breast tissue. The difference in genotypic distribution frequency between the groups, the correlation between the genotypes and the factors related to prognosis were analyzed.ResultsThe incidence of homozygous and variant genotypes had no difference between the breast cancer group and controls group (P=0.746). The proportion of variant genotype increased as clinical stage (P=0.006) advanced, as well as with increased numbers of lymph node metastases (P=0.010).ConclusionsIn patients with breast cancer there is a correlation between the CYP1A1 CC allele and some factors indicating poor prognosis, including more lymph node metastases as well as a more advanced clinical stage

Recent progress on nickel-based systems for ethylene oligo-/polymerization catalysis

Recent progress on nickel-based complex pre-catalysts is reviewed herein. The ethylene oligo-/polymerization behaviour is discussed in terms of the variation of the complex models bearing different kinds of ligand sets. These discussions focus mainly on the influence that the different substituents present have on the observed catalytic activity, the results of which can guide the design of new target structures possessing high ethylene activity

Observation of recoil-induced resonances and electromagnetically induced absorption of cold atoms in diffuse light

In this paper we report an experiment on the observation of the recoil-induced resonances (RIR) and electromagnetically induced absorption (EIA) of cold Rb87 atoms in diffuse light. The pump light of the RIR and the EIA comes from the diffuse light in an integrating sphere, which also serves the cooling light. The probe light beam is a weak laser split from the cooling laser in order to keep the cooling and probe lasers correlated. We measured the RIR and the EIA signal varying with the detuning of the diffuse laser light, and also measured the temperature of the cold atoms at the different detunings. The mechanism of RIR and EIA in the configuration with diffuse-light pumping and laser probing is discussed, and the difference of nonlinear spectra of cold atoms between in diffuse-light cooling system and in optical molasses as well as in a magneto-optical trap (MOT) are studied.Comment: 9 pages, 6 figure

The edge engineering of topological Bi(111) bilayer

A topological insulator is a novel quantum state, characterized by symmetry-protected non-trivial edge/surface states. Our first-principle simulations show the significant effects of the chemical decoration on edge states of topological Bi(111) bilayer nanoribbon, which remove the trivial edge state and recover the Dirac linear dispersion of topological edge state. By comparing the edge states with and without chemical decoration, the Bi(111) bilayer nanoribbon offers a simple system for assessing conductance fluctuation of edge states. The chemical decoration can also modify the penetration depth and the spin texture of edge states. A low-energy effective model is proposed to explain the distinctive spin texture of Bi(111) bilayer nanoribbon, which breaks the spin-momentum orthogonality along the armchair edge.Comment: 5 pages, 5 figure

The Bc→ψ(2S)πB_c\rightarrow \psi(2S)\pi, ηc(2S)π\eta_c(2S)\pi decays in the perturbative QCD approach

Nonleptonic two body $B_c$ decays including radially excited $\psi(2S)$ or $\eta_c(2S)$ mesons in the final state are studied using the perturbative QCD approach based on $k_T$ factorization. The charmonium distribution amplitudes are extracted from the $n = 2, l = 0$ Schr$\ddot{o}$dinger states for the harmonic oscillator potential. Utilizing these distribution amplitudes, we calculate the numerical results of the $B_c\rightarrow \psi(2S),\eta_c(2S)$ transition form factors and branching fractions of $B_c\rightarrow \psi(2S)\pi, \eta_c(2S)\pi$ decays. The ratio between two decay modes $B_c\rightarrow \psi(2S)\pi$ and $B_c\rightarrow J/\psi\pi$ is compatible with the experimental data within uncertainties, which indicate that the harmonic oscillator wave functions for $\psi(2S)$ and $\eta_c(2S)$ work well. It is found that the branching fraction of $B_c\rightarrow \eta_c(2S)\pi$, which is dominated by the twist-3 charmonium distribution amplitude, can reach the order of $10^{-3}$. We hope it can be measured soon in the LHCb experiment.Comment: 9 pages, 3 figures,3 Table