Spectroscopic Temperature Measurements for a Direct Current Arcjet Diamond Chemical Vapor Deposition Reactor

The diamond thin filmcommercial market isprojected to exceed one billion dollars by the year 2000. Potential applications of diamond thin films range from cutting tools to electronics tomedical devices. The explosion ofinterest in this fieldresults from the extreme properties diamond possesses: itis the hardest material known toman and yet, has a coefficient of friction similar to Teflon;its ability to conduct heat is five times that of copper; and diamond is completely inert. However, despite the tremendous economic incentive, there are still several technological barriers preventing diamond filmscale-up to commercial production. Included among these are a fundamental understanding of the gas phase chemistry leading to diamond filmformation and the lack of a reliable insitu, on-line Chemical Vapor Deposition (CVD)monitoring capability. Here we describe the use of optical emission spectroscopy (OES) as a possible direct current CVD plasma jet on-line monitor. Specifically, OES spectra from the C2 radical, an intermediate species in the diamond CVD process, is utilized to obtain plasma gas temperatures insitu. Additionally, the reliability of a plasma gas temperature determined fromOES is examined withLaser-Induced-Fluorescence (LIF)

Spectroscopic Temperature Measurements for a Direct Current Arcjet Diamond Chemical Vapor Deposition Reactor

The diamond thin filmcommercial market isprojected to exceed one billion dollars by the year 2000. Potential applications of diamond thin films range from cutting tools to electronics tomedical devices. The explosion ofinterest in this fieldresults from the extreme properties diamond possesses: itis the hardest material known toman and yet, has a coefficient of friction similar to Teflon;its ability to conduct heat is five times that of copper; and diamond is completely inert. However, despite the tremendous economic incentive, there are still several technological barriers preventing diamond filmscale-up to commercial production. Included among these are a fundamental understanding of the gas phase chemistry leading to diamond filmformation and the lack of a reliable insitu, on-line Chemical Vapor Deposition (CVD)monitoring capability. Here we describe the use of optical emission spectroscopy (OES) as a possible direct current CVD plasma jet on-line monitor. Specifically, OES spectra from the C2 radical, an intermediate species in the diamond CVD process, is utilized to obtain plasma gas temperatures insitu. Additionally, the reliability of a plasma gas temperature determined fromOES is examined withLaser-Induced-Fluorescence (LIF)

Whitetail Deer Carrying Capacity at a Georgia Barrier Island

Whitetail deer (Odocoileus virginianus) populations of several islands along the Georgia coast have appeared to be in declining health for the past 10 years. Several explanations for this phenomenon have been proposed; however, several researchers have alluded to the over-population of the species. We calculated the carrying capacity of the Skidaway Island State Park (SISP), a portion of Skidaway Island located near the coastal City of Savannah. By determining the amount of biomass produced by several habitats located within the park, and knowing the hectares of these habitats, the total amount of biomass was calculated. Using the caloric requirements of the whitetail deer found at various regions of the continental United States, we determined the sustainable carrying capacity of a healthy deer population within the park. We calculated that approximately 11.5 deer can be annually sustained on the vegetative biomass produced by the Skidaway Island State Park (SISP)

Comment on “Nonlinear response of the polar ionosphere to large values of the interplanetary electric field” by C. T. Russell et al.

Peer Reviewedhttp://deepblue.lib.umich.edu/bitstream/2027.42/95504/1/jgra16638.pd

Effective thermodynamics of strongly coupled qubits

Interactions between a quantum system and its environment at low temperatures can lead to violations of thermal laws for the system. The source of these violations is the entanglement between system and environment, which prevents the system from entering into a thermal state. On the other hand, for two-state systems, we show that one can define an effective temperature, placing the system into a `pseudo-thermal' state where effective thermal laws are upheld. We then numerically explore these assertions for an n-state system inspired by the spin-boson environment.Comment: 9 pages, 3 figure

The two‐way relationship between ionospheric outflow and the ring current

It is now well established that the ionosphere, because it acts as a significant source of plasma, plays a critical role in ring current dynamics. However, because the ring current deposits energy into the ionosphere, the inverse may also be true: the ring current can play a critical role in the dynamics of ionospheric outflow. This study uses a set of coupled, first‐principles‐based numerical models to test the dependence of ionospheric outflow on ring current‐driven region 2 field‐aligned currents (FACs). A moderate magnetospheric storm event is modeled with the Space Weather Modeling Framework using a global MHD code (Block Adaptive Tree Solar wind Roe‐type Upwind Scheme, BATS‐R‐US), a polar wind model (Polar Wind Outflow Model), and a bounce‐averaged kinetic ring current model (ring current atmosphere interaction model with self‐consistent magnetic field, RAM‐SCB). Initially, each code is two‐way coupled to all others except for RAM‐SCB, which receives inputs from the other models but is not allowed to feed back pressure into the MHD model. The simulation is repeated with pressure coupling activated, which drives strong pressure gradients and region 2 FACs in BATS‐R‐US. It is found that the region 2 FACs increase heavy ion outflow by up to 6 times over the noncoupled results. The additional outflow further energizes the ring current, establishing an ionosphere‐magnetosphere mass feedback loop. This study further demonstrates that ionospheric outflow is not merely a plasma source for the magnetosphere but an integral part in the nonlinear ionosphere‐magnetosphere‐ring current system.Key PointsRegion 2 field‐aligned currents drive additional ionospheric O+ outflowThis additional outflow feeds the ring current, creating a feedback systemIonospheric outflow is a tightly coupled piece of the M‐I systemPeer Reviewedhttp://deepblue.lib.umich.edu/bitstream/2027.42/112284/1/jgra51836.pd

Biogeochemical distribution of rare earths and other trace elements in plants and soils

The rare earth concentrations in vegetables (corn, potatoes, peas, and butternut squash) were found to be extremely low: 10/sup -8/ g/g to 10/sup -10/ g/g. The chondritic normalized vegetable REE patterns are fractionated, including a negative Eu anomaly, and behave as a smooth function of the REE ionic radii. These patterns may be governed by the geochemistry of accessory minerals in the host soils. The depletion factors for various elements by vegetables relative to bulk soils are approx. 10/sup -4/ for REE, Hf, Ta, Th, and U; approx. 10/sup -3/ for Al, As, Ba, Cr, Fe, Mn, Sc, Se, And Sr; approx. 10/sup -2/ for Co, Cs, Na, Ni, and Sb; approx. 10/sup -1/ for Rb; and approx. 1 for K, Zn, and Br

Indirect Pathogenicity of Haemophilus influenzae and Moraxella catarrhalis in Polymicrobial Otitis Media Occurs via Interspecies Quorum Signaling

Otitis media (OM) is among the leading diseases of childhood and is caused by opportunists that reside within the nasopharynx, such as Haemophilus influenzae and Moraxella catarrhalis. As with most airway infections, it is now clear that OM infections involve multiple organisms. This study addresses the hypothesis that polymicrobial infection alters the course, severity, and/or treatability of OM disease. The results clearly show that coinfection with H. influenzae and M. catarrhalis promotes the increased resistance of biofilms to antibiotics and host clearance. Using H. influenzae mutants with known biofilm defects, these phenotypes were shown to relate to biofilm maturation and autoinducer-2 (AI-2) quorum signaling. In support of the latter mechanism, chemically synthesized AI-2 (dihydroxypentanedione [DPD]) promoted increased M. catarrhalis biofilm formation and resistance to antibiotics. In the chinchilla infection model of OM, polymicrobial infection promoted M. catarrhalis persistence beyond the levels seen in animals infected with M. catarrhalis alone. Notably, no such enhancement of M. catarrhalis persistence was observed in animals infected with M. catarrhalis and a quorum signaling-deficient H. influenzae luxS mutant strain. We thus conclude that H. influenzae promotes M. catarrhalis persistence within polymicrobial biofilms via interspecies quorum signaling. AI-2 may therefore represent an ideal target for disruption of chronic polymicrobial infections. Moreover, these results strongly imply that successful vaccination against the unencapsulated H. influenzae strains that cause airway infections may also significantly impact chronic M. catarrhalis disease by removing a reservoir of the AI-2 signal that promotes M. catarrhalis persistence within biofilm

Influence of dispersion state of initial AlN powder on the hydrolysis process in air environment

The research results of the hydrolysis processes of aluminum nitride powders received by the SVS method in dependence on humidity of the storage environment, and grain size distribution are presented in this work. Oxidation kinetics was estimated by means of X- ray Diffraction (XRD) and scanning electron microscopy (SEM). The induction period of the hydrolysis process for various powders, its dependence on powder dispersion and thickness of the oxide layer on surface of particles have been defined