Synthesis, CP-MAS NMR Characterization, and Antibacterial Activities of Glycine and Histidine Complexes of Cd(SeCN) 2

The synthesis and characterization of cadmium and mercury complexes of selenocyanate of the type [(L)M(SeCN)2] are described, where L is L-Histidine (His) or L-Glycine (Gly) and M is Cd2+ or Hg2+. These complexes are obtained by the reaction of 1 equivalent of respective amino acids with metal diselenocyanate precursor in a mixture of solvents (methanol : water = 1 : 1). These synthesized compounds are characterized by analytical and various spectroscopic techniques such as elemental analysis (EA), IR, H,1 and C13 NMR in solution and in the solid state for C13 and N15. The in vitro antibacterial activities of these complexes have been investigated with standard type cultures of Escherichia coli (MTCC 443), Klebsiella pneumoniae (MTCC 109), Pseudomonas aeruginosa (MTCC 1688), Salmonella typhi (MTCC 733), and Staphylococcus aureus (MTCC 737)

Long-term desalinated water demand and investment requirements: a case study of Riyadh

The Kingdom of Saudi Arabia (KSA) is situated in an arid region and faces a chronic challenge to meet its increasing water demand. Riyadh is the capital of KSA and home to about six million people. The water demand is mostly met by groundwater resources (up to 48%), while the desalination plants cover the rest of the water supply requirements. There is a potential risk of a significant gap in water demand–supply due to the retirement of old desalination plants. This study, therefore, developed a probabilistic model to forecast desalinated water demand in Riyadh for domestic purposes up to the year 2040 based on three scenarios: low growth, the most likely (mean), and high growth scenario. The results showed that an investment of about US$6.24, 11.59, and 16.04 billion is required to meet the future domestic water demand of the city for the next 25 years based on low, mean, and high growth scenarios, respectively. Moreover, a strong commitment to public–private partnership is required to remove the fiscal budget burden related to the desalination along with public awareness campaigns to reduce per capita water consumption, upgrading the water tariff system and using renewable energy to run desalination plants.Peer Reviewe

Long-term desalinated water demand and investment requirements: a case study of Riyadh

The Kingdom of Saudi Arabia (KSA) is situated in an arid region and faces a chronic challenge to meet its increasing water demand. Riyadh is the capital of KSA and home to about six million people. The water demand is mostly met by groundwater resources (up to 48%), while the desalination plants cover the rest of the water supply requirements. There is a potential risk of a significant gap in water demand–supply due to the retirement of old desalination plants. This study, therefore, developed a probabilistic model to forecast desalinated water demand in Riyadh for domestic purposes up to the year 2040 based on three scenarios: low growth, the most likely (mean), and high growth scenario. The results showed that an investment of about US$6.24, 11.59, and 16.04 billion is required to meet the future domestic water demand of the city for the next 25 years based on low, mean, and high growth scenarios, respectively. Moreover, a strong commitment to public–private partnership is required to remove the fiscal budget burden related to the desalination along with public awareness campaigns to reduce per capita water consumption, upgrading the water tariff system and using renewable energy to run desalination plants.Peer Reviewe