196 research outputs found

    Diffractive imaging of dissociation and ground state dynamics in a complex molecule

    Get PDF
    We have investigated the structural dynamics in photoexcited 1,2-diiodotetrafluoroethane molecules (C2F4I2) in the gas phase experimentally using ultrafast electron diffraction and theoretically using FOMO-CASCI excited state dynamics simulations. The molecules are excited by an ultra-violet femtosecond laser pulse to a state characterized by a transition from the iodine 5p orbital to a mixed 5p|| hole and CF2 antibonding orbital, which results in the cleavage of one of the carbon-iodine bonds. We have observed, with sub-Angstrom resolution, the motion of the nuclear wavepacket of the dissociating iodine atom followed by coherent vibrations in the electronic ground state of the C2F4I radical. The radical reaches a stable classical (non-bridged) structure in less than 200 fs.Comment: 13 pages, 11 figure

    Mark ratio modulation over pulse position modulation

    Get PDF
    Orthogonal modulation superimposes non-amplitude-modulated signals on Manchester coded or pulse position modulated amplitude shift keying (ASK) signals, allowing two traffic flows with different bit rates to be modulated on the same wavelength channel, and hence improving spectrum efficiency. Inspired by the orthogonal modulation, this paper proposes a novel modulation format, i.e., mark ratio modulation over pulse position modulation (PPM), which utilizes the mark ratio difference between the PPM symbols and the inverse PPM symbols to deliver an overlaid signal. Better than traditional orthogonal modulation, in the mark ratio modulation over PPM, both low-speed and high-speed traffic flows are modulated by ASK with no need to sacrifice the extinction ratio, while keeping the reception simple and easy. According to theoretical analysis and test, we found 4PPM is a good option, which can balance the trade-off between the PPM signal\u27s effective bit rate and the mark ratio modulated signal\u27s quality

    Ultrafast manipulation of mirror domain walls in a charge density wave

    Get PDF
    Domain walls (DWs) are singularities in an ordered medium that often host exotic phenomena such as charge ordering, insulator-metal transition, or superconductivity. The ability to locally write and erase DWs is highly desirable, as it allows one to design material functionality by patterning DWs in specific configurations. We demonstrate such capability at room temperature in a charge density wave (CDW), a macroscopic condensate of electrons and phonons, in ultrathin 1T-TaS2_2. A single femtosecond light pulse is shown to locally inject or remove mirror DWs in the CDW condensate, with probabilities tunable by pulse energy and temperature. Using time-resolved electron diffraction, we are able to simultaneously track anti-synchronized CDW amplitude oscillations from both the lattice and the condensate, where photo-injected DWs lead to a red-shifted frequency. Our demonstration of reversible DW manipulation may pave new ways for engineering correlated material systems with light
    corecore