Demonstration of Best Management Practices for the Protection and Improvement of the Soil and Water Resources in the Arkansas Delta

This report is the compilation of a multi~year project that was directed at identifying the impact and possible mitigation solutions of non-point pollution from row crop agriculture in a watershed in the Arkansas Delta. The first part of the project involved an inventory of the condition of the major streams that make up the study watershed. The remainder of the project was focused at demonstrating and reporting best management nutrient and sediment runoff control practices (BMP) that could be implemented. The final assessment of the demonstration work is a GIS analysis that provides an overview of the effectiveness of these BMP control measures based on the conditions of the study watershed

Current status of haploidentical stem cell transplantation for leukemia

Haploidentical hematopoietic stem cell transplantation has made tremendous progress over the past 20 years and has become a feasible option for leukemia patients without a HLA identical sibling donor. The early complications of severe graft-versus-host disease (GVHD), graft failure and delayed engraftment, as well as disease recurrence have limited the use of this approach. Newer strategies have been applied and overcome some of the problems, including the use of T-cell depleted graft, "mega" dose of stem cells, intensive post-transplant immunosuppression and manipulation of the graft. These have decreased the transplant related mortality and GVHD associated with haploidentical transplantation, however, the major problems of disease relapse and infection, which related to late immune reconstitution, limit the development of haploidentical HSCT. Future challenges remain in improving post-transplant immune reconstitution and finding the best approach to reduce the incidence and severity of GVHD, while preserving graft-versus-leukemia effect to prevent the recurrence of underlying malignancy

Survey of gas-side fouling measuring devices

A survey of measuring devices or probes, which have been used to investigate gas-side fouling, has been carried out. Five different types of measuring devices are identified and discussed including: heat flux meters, mass accumulation probes, optical devices, deposition probes, and acid condensation probes. A total of 32 different probes are described in detail and summarized in matrix or tabular form. The important considerations of combustion gas characterization and deposit analysis are also given a significant amount of attention. The results of this study show that considerable work has been done in the development of gas-side fouling probes. However, it is clear that the design, construction, and testing of a durable versatile probe - capable of monitoring on-line fouling resistances - remains a formidable task

Optical measurements of vocal fold tensile properties: Implications for phonatory mechanics

In voice research, in vitro tensile stretch experiments of vocal fold tissues are commonly employed to determine the tissue biomechanical properties. In the standard stretch-release protocol, tissue deformation is computed from displacements applied to sutures inserted through the thyroid and arytenoid cartilages, with the cartilages assumed to be rigid. Here, a non-contact optical method was employed to determine the actual tissue deformation of vocal fold lamina propria specimens from three excised human larynges in uniaxial tensile tests. Specimen deformation was found to consist not only of deformation of the tissue itself, but also deformation of the cartilages, as well as suture alignment and tightening. Stress–stretch curves of a representative load cycle were characterized by an incompressible Ogden model. The initial longitudinal elastic modulus was found to be considerably higher if determined based on optical displacement measurements than typical values reported in the literature. The present findings could change the understanding of the mechanics underlying vocal fold vibration. Given the high longitudinal elastic modulus the lamina propria appeared to demonstrate a substantial level of anisotropy. Consequently, transverse shear could play a significant role in vocal fold vibration, and fundamental frequencies of phonation should be predicted by beam theories accounting for such effects

Optical measurements of vocal fold tensile properties: Implications for phonatory mechanics

[[abstract]]n voice research, in vitro tensile stretch experiments of vocal fold tissues are commonly employed to determine the tissue biomechanical properties. In the standard stretch-release protocol, tissue deformation is computed from displacements applied to sutures inserted through the thyroid and arytenoid cartilages, with the cartilages assumed to be rigid. Here, a non-contact optical method was employed to determine the actual tissue deformation of vocal fold lamina propria specimens from three excised human larynges in uniaxial tensile tests. Specimen deformation was found to consist not only of deformation of the tissue itself, but also deformation of the cartilages, as well as suture alignment and tightening. Stress–stretch curves of a representative load cycle were characterized by an incompressible Ogden model. The initial longitudinal elastic modulus was found to be considerably higher if determined based on optical displacement measurements than typical values reported in the literature. The present findings could change the understanding of the mechanics underlying vocal fold vibration. Given the high longitudinal elastic modulus the lamina propria appeared to demonstrate a substantial level of anisotropy. Consequently, transverse shear could play a significant role in vocal fold vibration, and fundamental frequencies of phonation should be predicted by beam theories accounting for such effects

ELRA: The exposure limiting robotic apparatus

A problem situation involving the handling of radioactive material at Argonne National Laboratory -- West (ANL-W) was solved through the use of remote handling techniques, providing significant exposure reduction to personnel. Robotic devices can be useful, but the cost of a robot is often prohibitive for many jobs. A low cost, disposable robot was built which successfully removed a highly radioactive and potentially explosive system from a hot cell at ANL-W

Iron(I)‐Based Carbonyl Complexes with Bridging Thiolate Ligands as Light‐Triggered CO Releasing Molecules (photoCORMs)

A series of thiolate ligands were used to synthesize diiron(I) hexacarbonyl bis(thiolates) for structural studies. Conversion of the corresponding thiols with triiron(0) dodecacarbonyl yields complexes of the type [{(CO) 3 Fe(μ‐SR)} 2 ] [R = C 6 H 5 ( 1 ), C 6 H 4 ‐4‐CH 3 ( 2 ), C 6 H 4 ‐4‐F ( 3 ), C 6 F 5 ( 4 ), C 6 H 4 ‐4‐CF 3 ( 5 ), C 6 H 2 ‐2,4,6‐(CH 3 ) 3 ( 6 ), CH 2 –C 6 H 4 ‐4‐Cl ( 7 )]. These complexes were isolated and fully characterized, including X‐ray crystal structures of complexes 2 – 7 . The bridging thiolate ligands mainly influence the Fe–CO bond which is trans ‐positioned to the second iron(I) center. In solution, the anti ‐isomer with one axially and one equatorially oriented thiolate is the major species; severe steric strain induced by mesityl groups only allows the formation of syn‐endo ‐isomeric molecules of 7 . Furthermore, light‐induced CO release at solid material at the three representative complexes 1 , 3 , and 6 verify suitability as photoCORMs.image John Wiley & Sons, Ltd