Numerical Study of the Bond Strength Evolution of Corroded Reinforcement in Concrete in Pull‐Out Tests

The corrosion of rebars in reinforced concrete structures impacts their geometry (diameter and ribs) and mass, damages the concrete at the interface between the two materials, deteriorates the bond strength, and causes the cracking of the concrete cover. In the following study, a 2D numerical model of the pull‐out test is presented in order to study the impact of corrosion on the bond strength. Several parameters are investigated: the embedment depth, the rebar’s diameter, and the width of the concrete cover. The model reproduces the slip of the rebar and the failure through the splitting of concrete. It integrates an interface between the two materials and a concrete damage model that simulate the deterioration of concrete in compression and tension. The results obtained are validated with experimental data from the literature. Moreover, a parametric study is carried out to determine the impact of the embedment depth, the diameter of the rebar, and the concrete cover on the bond strength. The present study confirms that a greater embedment depth increases the pulling load. The study also confirms that the rebar’s diameter impacts highly the loss of bond between the rebar and the concrete cover. Lastly, the final main result of this paper is that the width of the concrete cover slows the loss of bond strength between the two materials

Thermal decomposition kinetics of the antiparkinson drug “entacapone” under isothermal and non-isothermal conditions

© 2017 Akadémiai Kiadó, Budapest, Hungary The thermal decomposition kinetics of entacapone (ENT) have been investigated via thermogravimetric analysis under non-isothermal and isothermal conditions which provide useful stability information for their processing in the pharmaceutical industry and also for predicting shelf life and suitable storage conditions. The determination of the kinetic parameters for the decomposition process under non-isothermal conditions in a nitrogen atmosphere at four heating rates (5, 10, 15, and 20 °C min −1 ) was performed. Kinetic parameters of the decomposition process for ENT were calculated through Friedman, Flynn–Wall–Ozawa, Kissinger–Akahira–Sunose, and Li–Tang methods. This work demonstrates that the activation energies calculated from the decomposition reactions by different methods are consistent with each other. Moreover, the thermodynamic functions of the decomposition reaction were also calculated

Intentions on desired length of stay among immigrants in Italy

Abstract The decision to emigrate from the country of origin may not be a permanent one: migrants can decide to return home or to emigrate to a third country. This phenomenon, established for some time in certain other European countries, has become an important one for Italy only recently. This paper contributes to the knowledge of migrants’ intentions in two ways: on the one hand, it analyses the factors associated with indecision about future plans; on the other, it focuses on the desired length of stay and its relationship with attachments (family, economic, socio-cultural and psychological) to host and home country. We used two logistic regression models: one for migrants’ indecision and the other for migrants’ desired length of stay. The data were collected by survey, coordinated by the ISMU Foundation and conducted in 2008 and 2009 with more than 12,000 migrants living in Italy. According to our results, indecision seems to be associated with an intermediate phase of migration at the early stage of family development in the case of negative balance of the migration experience, while attachment to the host country is associated with longer stay, and no attachments or attachment to the country of origin are associated with shorter stay