58 research outputs found
Spectroscopy of Na⁺.Rg and transport coefficients of Na⁺ in Rg(Rg=He ―Rn)
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Theoretical study of Cl ‾ RG (rare gas) complexes and transport of Cl‾ through RG (RG = He-Rn)
2011-2012 > Academic research: refereed > Publication in refereed journalVersion of RecordPublishe
Neutron scattering study of PbMgTaO and BaMgTaO complex perovskites
Neutron scattering investigations were carried out in
PbMgTaO and BaMgTaO complex
perovskites. The crystal structure of both compounds does not show any phase
transition in the temperature range 1.5 -- 730 K. Whereas the temperature
dependence of the lattice parameter of BaMgTaO follows the
classical expectations, the lattice parameter of relaxor ferroelectric
PbMgTaO exhibits anomalies. One of these anomalies is
observed in the same temperature range as the peak in the dielectric
susceptibility. We find that in PbMgTaO, lead ions are
displaced from the ideal positions in the perovskite structure at all
temperatures. Consequently short-range order is present. This induces strong
diffuse scattering with an anisotropic shape in wavevector space. The
temperature dependences of the diffuse neutron scattering intensity and of the
amplitude of the lead displacements are similar
Disorder and relaxation mode in the lattice dynamics of PbMgNbO relaxor ferroelectric
The low-energy part of vibration spectrum in PbMgNbO
relaxor ferroelectric was studied by inelastic neutron scattering. We observed
the coexistence of a resolution-limited central peak with strong quasielastic
scattering. The line-width of the quasielastic component follows a
dependence. We find that is temperature-dependent.
The relaxation time follows the Arrhenius law well. The presence of a
relaxation mode associated with quasi-elastic scattering in PMN indicates that
order-disorder behaviour plays an important r\^ole in the dynamics of diffuse
phase transitions
Evidence for and phases in the morphotropic phase boundary region of : A Rietveld study
We present here the results of the room temperature dielectric constant
measurements and Rietveld analysis of the powder x-ray diffraction data on
(PMN-PT) in the composition range
to show that the morphotropic phase boundary (MPB)
region contains two monoclinic phases with space groups Cm (or type) and
Pm (or type) stable in the composition ranges and
, respectively. The structure of PMN-PT in the
composition ranges 0.26, and is found to be
rhombohedral (R3m) and tetragonal (P4mm), respectively. These results are
compared with the predictions of Vanderbilt & Cohen's theory.Comment: 20 pages, 11 pdf figure
Phase diagram of the ferroelectric-relaxor (1-x)PbMg(1/3)Nb(2/3)O3-xPbTiO3
Synchrotron x-ray powder diffraction measurements have been performed on
unpoled ceramic samples of (1-x)PbMg(1/3)Nb(2/3)O3-xPbTiO3 (PMN-xPT) with 30%<=
x<= 39% as a function of temperature around the morphotropic phase boundary
(MPB), which is the line separating the rhombohedral and tetragonal phases in
the phase diagram. The experiments have revealed very interesting features
previously unknown in this or related systems. The sharp and well-defined
diffraction profiles observed at high and intermediate temperatures in the
cubic and tetragonal phases, respectively, are in contrast to the broad
features encountered at low temperatures. These peculiar characteristics, which
are associated with the monoclinic phase of MC-type previously reported by Kiat
et al and Singh et al., can only be interpreted as multiple coexisting
structures with MC as the major component. An analysis of the diffraction
profiles has allowed us to properly characterize the PMN-xPT phase diagram and
to determine the stability region of the monoclinic phase, which extends from
x= 31% to x= 37% at 20 K. The complex lansdcape of observed phases points to an
energy balance between the different PMN-xPT phases which is intrinsically much
more delicate than that of related systems such as PbZr(1-x)TixO3 or
(1-x)PbZn(1/3)Nb(1/3)O3-xPbTiO3. These observations are in good accord with an
optical study of x= 33% by Xu et al., who observed monoclinic domains with
several different polar directions coexisting with rhombohedral domains, in the
same single crystal.Comment: REVTeX4, 11 pages, 10 figures embedde
Universal Static and Dynamic Properties of the Structural Transition in Pb(Zn1/3Nb2/3)O3
The relaxors Pb(ZnNb)O (PZN) and
Pb(MgNb)O (PMN) have very similar properties based on the
dielectric response around the critical temperature (defined by the
structural transition under the application of an electric field). It has been
widely believed that these materials are quite different below with the
unit cell of PMN remaining cubic while in PZN the low temperature unit cell is
rhombohedral in shape. However, this has been clarified by recent high-energy
x-ray studies which have shown that PZN is rhombohedral only in the skin while
the shape of the unit cell in the bulk is nearly cubic. In this study we have
performed both neutron elastic and inelastic scattering to show that the
temperature dependence of both the diffuse and phonon scattering in PZN and PMN
is very similar. Both compounds show a nearly identical recovery of the soft
optic mode and a broadening of the acoustic mode below . The diffuse
scattering in PZN is suggestive of an onset at the high temperature Burns
temperature similar to that in PMN. In contrast to PMN, we observe a broadening
of the Bragg peaks in both the longitudinal and transverse directions below
. We reconcile this additional broadening, not observed in PMN, in terms
of structural inhomogeneity in PZN. Based on the strong similarities between
PMN and PZN, we suggest that both materials belong to the same universality
class and discuss the relaxor transition in terms of the three-dimensional
Heisenberg model with cubic anisotropy in a random field.Comment: 11 pages, 10 figures. Updated version after helpful referee comment
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