21 research outputs found
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SYNTHESIS, STRUCTURE, AND PHOTOCHEMISTRY OF FULVALENE DIRUTHENIUM TETRACARBONYL. THERMALLY REVERSIBLE PHOTOISOMERIZATION INVOLVING CARBON-CARBON BOND ACTIVATION AT A DIMETAL CENTER
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ON THE MECHANISM OF THE REPPE CYCLOOCTATE-TRAENE SYNTHESIS FROM ETHYNE: A LABELING EXPERIMENT
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THERMAL EXTRUSION OF SULFUR DIOXIDE FROM (n5-C5H5)Co-n4-thiophene-l,l-dioxides: A NEW ORGANOMETALLIC REACTION
No full textRetention of stereochemistry in the extrusion of sulfur monoxide from thiirane oxides. Synthesis and thermal decomposition of cis and trans-dideuteriothiirane oxide
No full textThe synthesis of the simplest stereochemically labeled thiirane oxides, cis- and trans-dideuteriothiirane oxide via the stereospecific formation of the corresponding deuterated epoxides and thiiranes was reported. The stereochemical results of their decomposition both in the gas and solution phase was also reported. The results provide an unambiguous stereochemical test for the mode of decomposition of simple thiirane oxides. (DDA
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SOME REMARKABLE REACTIONS OF THE BISCARBYNE CLUSTERS [u3 n1 - CR1] [u3 n1 - cr2][(n5-C5H5)Co3 WITH ELECTROPHILES
No full textTransition metal catalysed acetylene cyclisations: 4, 5-Bis (trimethylsilyl) benzocyclobutene, a highly strained, versatile, synthetic intermediate
No full textIntramolecular cycloaddition of bis-o-xylylenes – an extremely short route to (2.2.2) cyclophanes
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ON THE REVERSIBILITY OF n4-CYCLOBUTADIENE METAL FORMATION FROM COMPLEXED ALKYNES: UNIMOLECULAR ISOMERIZATION OF LABELED RACEMIC AND ENANTIOMERICALLY ENRICHED n5-CYCLOPENTADIENYL-n4 -CYCLOBUTADIENE COBALT COMPLEXES
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TRANSITION METAL ACTIVATION OF n-COMPLEXED BENZENE: DOUBLE NUCLEOPHILIC ADDITIONS
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