Disordered Crystal Structure and Anomalously High Solubility of Radium Carbonate

XRD measurements of RaCO3 revealedthat it isnot isostructural with witherite, and direct-space ab initio modeling showed that the carbonate oxygens are highly disordered.It was found that the solubility of RaCO3 is unexpectedlyhigher than the solubility of witherite (log(10) K (sp) (0) = -7.5 and -8.56,respectively), supporting the disordered nature of RaCO3. EXAFS data revealed an ionic radius of Ra2+ of 1.55 & ANGS;. Radium is the only alkaline-earth metal which forms disorderedcrystals in its carbonate phase.Radium-226 carbonate was synthesized from radium-bariumsulfate ((Ra0.76Ba0.24SO4)-Ra-226) at room temperature and characterized by X-ray powder diffraction(XRPD) and extended X-ray absorption fine structure (EXAFS) techniques.XRPD revealed that fractional crystallization occurred and that twophases were formed the major Ra-rich phase, Ra(Ba)CO3, and a minor Ba-rich phase, Ba(Ra)CO3, crystallizingin the orthorhombic space group Pnma (no. 62) thatis isostructural with witherite (BaCO3) but with slightlylarger unit cell dimensions. Direct-space ab initio modeling shows that the carbonate oxygens in the major Ra(Ba)CO3 phase are highly disordered. The solubility of the synthesizedmajor Ra(Ba)CO3 phase was studied from under- and oversaturationat 25.1 & DEG;C as a function of ionic strength using NaCl as thesupporting electrolyte. It was found that the decimal logarithm ofthe solubility product of Ra(Ba)CO3 at zero ionic strength(log(10) K (sp) (0)) is-7.5(1) (2 & sigma;) (s = 0.05 g & BULL;L-1). This is significantly higher than the log(10) K (sp) (0) of witheriteof -8.56 (s = 0.01 g & BULL;L-1), supporting the disordered nature of the major Ra(Ba)CO3 phase. The limited co-precipitation of Ra2+ within witherite,the significantly higher solubility of pure RaCO3 comparedto witherite, and thermodynamic modeling show that the results obtainedin this work for the major Ra(Ba)CO3 phase are also applicableto pure RaCO3. The refinement of the EXAFS data revealsthat radium is coordinated by nine oxygens in a broad bond distancedistribution with a mean Ra-O bond distance of 2.885(3) & ANGS;(1 & sigma;). The Ra-O bond distance gives an ionic radius ofRa(2+) in a 9-fold coordination of 1.545(6) & ANGS; (1 & sigma;)

Geodesic Flow on the Diffeomorphism Group of the circle

We show that certain right-invariant metrics endow the infinite-dimensional Lie group of all smooth orientation-preserving diffeomorphisms of the circle with a Riemannian structure. The study of the Riemannian exponential map allows us to prove infinite-dimensional counterparts of results from classical Riemannian geometry: the Riemannian exponential map is a smooth local diffeomorphism and the length-minimizing property of the geodesics holds.Comment: 15 page

Geodesics in the space of measure-preserving maps and plans

We study Brenier's variational models for incompressible Euler equations. These models give rise to a relaxation of the Arnold distance in the space of measure-preserving maps and, more generally, measure-preserving plans. We analyze the properties of the relaxed distance, we show a close link between the Lagrangian and the Eulerian model, and we derive necessary and sufficient optimality conditions for minimizers. These conditions take into account a modified Lagrangian induced by the pressure field. Moreover, adapting some ideas of Shnirelman, we show that, even for non-deterministic final conditions, generalized flows can be approximated in energy by flows associated to measure-preserving maps

An Introduction to Conformal Ricci Flow

We introduce a variation of the classical Ricci flow equation that modifies the unit volume constraint of that equation to a scalar curvature constraint. The resulting equations are named the Conformal Ricci Flow Equations because of the role that conformal geometry plays in constraining the scalar curvature. These equations are analogous to the incompressible Navier-Stokes equations of fluid mechanics inasmuch as a conformal pressure arises as a Lagrange multiplier to conformally deform the metric flow so as to maintain the scalar curvature constraint. The equilibrium points are Einstein metrics with a negative Einstein constant and the conformal pressue is shown to be zero at an equilibrium point and strictly positive otherwise. The geometry of the conformal Ricci flow is discussed as well as the remarkable analytic fact that the constraint force does not lose derivatives and thus analytically the conformal Ricci equation is a bounded perturbation of the classical unnormalized Ricci equation. That the constraint force does not lose derivatives is exactly analogous to the fact that the real physical pressure force that occurs in the Navier-Stokes equations is a bounded function of the velocity. Using a nonlinear Trotter product formula, existence and uniqueness of solutions to the conformal Ricci flow equations is proven. Lastly, we discuss potential applications to Perelman's proposed implementation of Hamilton's program to prove Thurston's 3-manifold geometrization conjectures.Comment: 52 pages, 1 figur

Affine symmetry in mechanics of collective and internal modes. Part I. Classical models

Discussed is a model of collective and internal degrees of freedom with kinematics based on affine group and its subgroups. The main novelty in comparison with the previous attempts of this kind is that it is not only kinematics but also dynamics that is affinely-invariant. The relationship with the dynamics of integrable one-dimensional lattices is discussed. It is shown that affinely-invariant geodetic models may encode the dynamics of something like elastic vibrations

Toeplitz Quantization of K\"ahler Manifolds and gl(N)gl(N) N→∞N\to\infty

For general compact K\"ahler manifolds it is shown that both Toeplitz quantization and geometric quantization lead to a well-defined (by operator norm estimates) classical limit. This generalizes earlier results of the authors and Klimek and Lesniewski obtained for the torus and higher genus Riemann surfaces, respectively. We thereby arrive at an approximation of the Poisson algebra by a sequence of finite-dimensional matrix algebras $gl(N)$, $N\to\infty$.Comment: 17 pages, AmsTeX 2.1, Sept. 93 (rev: only typos are corrected

The Dynamics of a Rigid Body in Potential Flow with Circulation

We consider the motion of a two-dimensional body of arbitrary shape in a planar irrotational, incompressible fluid with a given amount of circulation around the body. We derive the equations of motion for this system by performing symplectic reduction with respect to the group of volume-preserving diffeomorphisms and obtain the relevant Poisson structures after a further Poisson reduction with respect to the group of translations and rotations. In this way, we recover the equations of motion given for this system by Chaplygin and Lamb, and we give a geometric interpretation for the Kutta-Zhukowski force as a curvature-related effect. In addition, we show that the motion of a rigid body with circulation can be understood as a geodesic flow on a central extension of the special Euclidian group SE(2), and we relate the cocycle in the description of this central extension to a certain curvature tensor.Comment: 28 pages, 2 figures; v2: typos correcte

Normal families of functions and groups of pseudoconformal diffeomorphisms of quaternion and octonion variables

This paper is devoted to the specific class of pseudoconformal mappings of quaternion and octonion variables. Normal families of functions are defined and investigated. Four criteria of a family being normal are proven. Then groups of pseudoconformal diffeomorphisms of quaternion and octonion manifolds are investigated. It is proven, that they are finite dimensional Lie groups for compact manifolds. Their examples are given. Many charactersitic features are found in comparison with commutative geometry over $\bf R$ or $\bf C$.Comment: 55 pages, 53 reference

Controllability of 2D Euler and Navier-Stokes equations by degenerate forcing

We study controllability issues for the 2D Euler and Navier- Stokes (NS) systems under periodic boundary conditions. These systems describe motion of homogeneous ideal or viscous incompressible fluid on a two-dimensional torus T^2. We assume the system to be controlled by a degenerate forcing applied to fixed number of modes. In our previous work [3, 5, 4] we studied global controllability by means of degenerate forcing for Navier-Stokes (NS) systems with nonvanishing viscosity (\nu > 0). Methods of dfferential geometric/Lie algebraic control theory have been used for that study. In [3] criteria for global controllability of nite-dimensional Galerkin approximations of 2D and 3D NS systems have been established. It is almost immediate to see that these criteria are also valid for the Galerkin approximations of the Euler systems. In [5, 4] we established a much more intricate suf- cient criteria for global controllability in finite-dimensional observed component and for L2-approximate controllability for 2D NS system. The justication of these criteria was based on a Lyapunov-Schmidt reduction to a finite-dimensional system. Possibility of such a reduction rested upon the dissipativity of NS system, and hence the previous approach can not be adapted for Euler system. In the present contribution we improve and extend the controllability results in several aspects: 1) we obtain a stronger sufficient condition for controllability of 2D NS system in an observed component and for L2- approximate controllability; 2) we prove that these criteria are valid for the case of ideal incompressible uid (\nu = 0); 3) we study solid controllability in projection on any finite-dimensional subspace and establish a sufficient criterion for such controllability

Interaction of vortices in viscous planar flows

We consider the inviscid limit for the two-dimensional incompressible Navier-Stokes equation in the particular case where the initial flow is a finite collection of point vortices. We suppose that the initial positions and the circulations of the vortices do not depend on the viscosity parameter \nu, and we choose a time T > 0 such that the Helmholtz-Kirchhoff point vortex system is well-posed on the interval [0,T]. Under these assumptions, we prove that the solution of the Navier-Stokes equation converges, as \nu -> 0, to a superposition of Lamb-Oseen vortices whose centers evolve according to a viscous regularization of the point vortex system. Convergence holds uniformly in time, in a strong topology which allows to give an accurate description of the asymptotic profile of each individual vortex. In particular, we compute to leading order the deformations of the vortices due to mutual interactions. This allows to estimate the self-interactions, which play an important role in the convergence proof.Comment: 39 pages, 1 figur