11 research outputs found
Electrosynthesis of Polyaniline Film on AA 7075 Alloy and Its Corrosion Protection Ability
Polyaniline has been electrodeposited on an AA 7075 alloy by a potentiostatic method, and its corrosion protection ability has been
studied by Tafel polarization and electrochemical impedance spectroscopic techniques in 1% NaCl. A pure polyaniline film
protects the aluminum alloy up to 70%. However, the corrosion resistance property of the polyaniline film has substantially
increased to 90% by post-treatment in a cerium salt solution. X-ray photoelectron spectra studies have shown that the film formed
due to the post-treatment of polyaniline with the AA 7075 alloy in the cerium salt solution is composed of both Ce3+ and Ce4+
oxides
Soft template synthesis of poly(o-phenylenediamine) nanotubes and its application in self healing coatings
Poly(o-phenylenediamine) (PoPD) nanotubes were fabricated through chemical oxidative polymerization
of o-phenylenediamine in cetyl trimethyl ammonium bromide (CTAB) microemulsion
polymerization using �-cyclodextrin (�-CD). Iron (III) chloride (FeCl3) was used as a structure directing
agent as well as an oxidant. The polymer nanotubes thus synthesized were characterized by FTIR,
UV–vis, NMR and XPS techniques and the surface morphology of nanotubes was analyzed by using SEM
and TEM. A study has been made on the corrosion protection performance of mild steel by epoxy coating
containing synthesized PoPD nanotubes using EIS technique and OCP measurements
Electrosysnthesis of poly(aniline-co-m-amino benzoic acid) for corrosion protection of steel
Conducting polymer (poly(aniline-co-m-amino benzoic acid)) has been deposited on steel surface by
cyclic voltammetric technique. The copolymer film was characterized by FTIR, XPS and SEM techniques.
The corrosion protection performance of copolymer film on steel was found out by impedance and tafel
polarization methods in 1N HCl. The copolymer film was found to be highly corrosion resistant
Synthesis of tungstate doped polyaniline and its usefulness in corrosion protective coatings
A study has been made on the corrosion protection performance of tungstate doped polyaniline containing
vinyl coating on steel. The tungstate doped polyaniline was chemically synthesized and characterized by FTIR, XRD, UV-VIS and TGA studies. The corrosion protection performance of vinyl coating containing tungstate doped polyaniline on steel was assessed in 3% NaCl by electrochemical impedance studies (EIS). The coating has been found to offer protection more than 60 days in salt spray and immersion in 3% NaCl. FTIR studies have shown that the formation of iron–tungstate complex along with the passive film on stee
Sulphonate doped polyaniline containing coatings for corrosion protection of iron
Polyaniline containing organic coatings are found to protect steel in acid and in neutral media. Since dopants
play an important role in the protection ability of polyaniline, a study has been made on the corrosion
protection performance of sulphonate doped polyaniline containing vinyl coating in 0.1 N HCl and 3% NaCl
by open circuit potential and impedance measurements. The open circuit potential measurements have
shown that the coatings with polyaniline maintain the potential in the noble range whereas the coating
without polyaniline exhibit potentials in the active range. EIS studies have shown that the sulphonate doped
polyaniline is able to protect steel in acid and in neutral media since the impedance values of the coating
remained at 1010 Ω cm2 even after 100 days exposure whereas the coatings without polyaniline have lost
their protection ability after 50 days and 100 days in the acid and neutral media. FTIR studies have shown
that PANI is able to protect by forming iron–PANI complexes beneath the coating along with a passive oxide
layer
Electrosynthesis of polyaniline–molybdate coating on steel and its corrosion protection performance
Electrosynthesis of polyaniline–molybdate (PANI–MoO42−) on mild steel was achieved in oxalic acid medium using cyclic voltammetry technique. Adherent and homogeneous PANI–MoO4
2− coating was obtained. The corrosion behavior of steel with PANI–MoO4 2− coatings in 1% NaCl solutions was investigated by potentiodynamic polarization and electrochemical impedance spectroscopy techniques. The
coating was characterized by SEM, XPS, EDAX and FTIR. The self-healing ability of PANI–MoO4 2− coating
was confirmed by SVET technique. It has been found that the PANI–MoO42− coating is able to offer higher corrosion protection in comparison to that of pure PANI coating due to inhibitive nature of molybdate ion