Nanocrystalline cathodes for PC-SOFCs based on BCZY

Perovskites based on BaCeO3-δ exhibit the highest proton conductivity among this class of materials, however, they are susceptible to hydration and carbonation in presence of water vapor and CO2 [1]. In contrast, the chemical stability of BaZrO3-based protonic conductors is better, but they require sintering temperatures as high as 1700 ºC and suffer from high intrinsic grain boundary resistance, limiting the final performance. Partial substitution of Zr for Ce in Ba(Ce0.9-xZrx)Y0.2O3-δ allows obtaining electrolytes with both high proton conductivity and good chemical stability. The performance of a PC-SOFC at low temperatures depends significantly on the ohmic resistance of the electrolyte, although it can be lowered by reducing the electrolyte thickness. Another important limiting factor is the increase of the cathode polarization resistance due to the thermally activated nature of the oxygen reduction reaction. For this reason, it is essential to obtain high efficiency cathodes operating at reduced temperatures. In this work, BaCe0.6Zr0.2Y0.2O3-δ (BCZY) powders were prepared by freeze-drying precursor method. These powders were mixed with a Zn-containing solution as sintering additive in order to obtain dense pellets with submicrometric grain size at only 1200 ºC. After that, La0.6Sr0.4Co0.8Fe0.2O3 nanocrystalline electrodes were deposited symmetrically onto dense pellets BCZY by conventional spray-pyrolysis [3]. The structure, microstructure and electrochemical properties of these electrodes have been examined by XRD, FE-SEM and impedance spectroscopy. The stability of these electrodes at intermediate temperatures was evaluated as a function of time. These nanocrystalline cathodes exhibit a substantial improvement of the electrode polarization resistance with respect to the same materials prepared by screen-printing method at high sintering temperatures, e.g. 0.7 and 3.2 cm2 at 600 ºC for LSCF cathodes prepared by spray-pyrolysis and screen-printing method respectively (Figure). An anode supported cell with composition LSCF/BCZY/NiO-BCZY was also prepared to test the electrochemical performance.Universidad de Málaga. Campus de Excelencia Internacional Andalucía Tech

Effects of Non-Circular Motions on Azimuthal Color Gradients

Assuming that density waves trigger star formation, and that young stars preserve the velocity components of the molecular gas where they are born, we analyze the effects that non-circular gas orbits have on color gradients across spiral arms. We try two approaches, one involving semi-analytical solutions for spiral shocks, and another with magnetohydrodynamic (MHD) numerical simulation data. We find that, if non-circular motions are ignored, the comparison between observed color gradients and stellar population synthesis models would in principle yield pattern speed values that are systematically too high for regions inside corotation, with the difference between the real and the measured pattern speeds increasing with decreasing radius. On the other hand, image processing and pixel averaging result in systematically lower measured spiral pattern speed values, regardless of the kinematics of stellar orbits. The net effect is that roughly the correct pattern speeds are recovered, although the trend of higher measured $\Omega_p$ at lower radii (as expected when non-circular motions exist but are neglected) should still be observed. We examine the Martinez-Garcia et al. (2009) photometric data and confirm that this is indeed the case. The comparison of the size of the systematic pattern speed offset in the data with the predictions of the semi-analytical and MHD models corroborates that spirals are more likely to end at Outer Lindblad Resonance, as these authors had already found.Comment: 32 pages, 15 figures, accepted to Ap

Clump morphology and evolution in MHD simulations of molecular cloud formation

Abridged: We study the properties of clumps formed in three-dimensional weakly magnetized magneto-hydrodynamic simulations of converging flows in the thermally bistable, warm neutral medium (WNM). We find that: (1) Similarly to the situation in the classical two-phase medium, cold, dense clumps form through dynamically-triggered thermal instability in the compressed layer between the convergent flows, and are often characterised by a sharp density jump at their boundaries though not always. (2) However, the clumps are bounded by phase-transition fronts rather than by contact discontinuities, and thus they grow in size and mass mainly by accretion of WNM material through their boundaries. (3) The clump boundaries generally consist of thin layers of thermally unstable gas, but these layers are often widened by the turbulence, and penetrate deep into the clumps. (4) The clumps are approximately in both ram and thermal pressure balance with their surroundings, a condition which causes their internal Mach numbers to be comparable to the bulk Mach number of the colliding WNM flows. (5) The clumps typically have mean temperatures 20 < T < 50 K, corresponding to the wide range of densities they contain (20 < n < 5000 pcc) under a nearly-isothermal equation of state. (6) The turbulent ram pressure fluctuations of the WNM induce density fluctuations that then serve as seeds for local gravitational collapse within the clumps. (7) The velocity and magnetic fields tend to be aligned with each other within the clumps, although both are significantly fluctuating, suggesting that the velocity tends to stretch and align the magnetic field with it. (8) The typical mean field strength in the clumps is a few times larger than that in the WNM. (9) The magnetic field strength has a mean value of B ~ 6 mu G ...Comment: substantially revised version, accepted by MNRAS, 13 pages, 14 figures, high resolution version: http://www.ita.uni-heidelberg.de/~banerjee/publications/MC_Formation_Paper2.pd

Factores que condicionan el acabado de terneros de raza Tudanca en Cantabria

UnpublishedTomo I. Sección: Sistemas Ganaderos - Economía y Gestión. Sesión: Vacuno carne

Bounds for the time to failure of hierarchical systems of fracture

For years limited Monte Carlo simulations have led to the suspicion that the time to failure of hierarchically organized load-transfer models of fracture is non-zero for sets of infinite size. This fact could have a profound significance in engineering practice and also in geophysics. Here, we develop an exact algebraic iterative method to compute the successive time intervals for individual breaking in systems of height $n$ in terms of the information calculated in the previous height $n-1$. As a byproduct of this method, rigorous lower and higher bounds for the time to failure of very large systems are easily obtained. The asymptotic behavior of the resulting lower bound leads to the evidence that the above mentioned suspicion is actually true.Comment: Final version. To appear in Phys. Rev. E, Feb 199

Feeding entrainment of locomotor activity rhythms, digestive enzymes and neuroendocrine factors in goldfish

©2007. This manuscript version is made available under the CC-BY-NC-ND 4.0 license http://creativecommons.org/licenses/by-nc-nd/4.0/ This document is the Accepted version of a Published Work that appeared in final form in Journal of PHYSIOL BEHAV. To access the final edited and published work see http://doi: 10.1016/j.physbeh.2006.10.017L.M. VERA, N. DE PEDRO, E. GÓMEZ-MILÁN, M.J. DELGADO, M.J. SÁNCHEZ MUROS, J.A. MADRID, F.J. SÁNCHEZ-VÁZQUEZ. Feeding entrainment of locomotor activity, digestive enzymes and neuroendocrine factors in goldfish. PHYSIOL BEHAV 90 (2-3) 518-524, 2007. The existence of food anticipatory activity (FAA) in animals subjected to daily feeding schedules seems to be mediated by a feeding-entrainable oscillator (FEO). Such an FEO may help in anticipating meal time and so optimizing food acquisition and nutrient utilization. In this study we investigated the existence of FAA and whether digestive enzymes, plasma cortisol, hypothalamic NPY and gastrointestinal tract (GIT) and plasma melatonin were entrained by periodic feeding in goldfish. We observed that periodically fed goldfish showed FAA in locomotor activity as well as in amylase and NPY. Alkaline protease and GIT melatonin were higher after feeding, whereas plasma cortisol levels were reduced. Plasma melatonin remained unmodified before and after meal time. These results suggested that scheduled feeding entrained both behavioral and certain physiological patterns in goldfish, FAA being of adaptive value to anticipate a meal and prepare the digestive physiology of fish

Non-Linear Models for Growth, Development, and Posture of L-33 White Leghorn Hens, according to Economic Indicators

The Zootechnical Factors established by the main indicators of bioeconomic behavior were determined for the pro-ductive-commercial cycle of L-33 White Leghorn hens in the province of Ciego de Ávila, Cuba. A number of 55 cycles were analyzed for validation of mathematical models between 2002 and 2014; other 18 cycles were studied between 2014 and 2016. Descriptive statistics, generalized mixed models (GLIMMIX), and five-function modelling were used. SAS 9.3 for Windows was also used. The productive cycles were similar to the standard set up for the breed and line in Cuba. Laying was 293 eggs/poultry, with a conversion of 1.40 feed kg/10 eggs, and a cost of $ 0.36 CUP an egg. The starting sheds and year had effects on live weight, tarsus length, uniformity, and daily weight gain up to 175 days. Sexual maturity, conversion, egg production, egg cost, and net income were influenced by farm, whereas each farm´s starting shed and the years, had negative effects on most biological indicators. Low, but significant effects of combined climate variables were observed in the bioeconomic indicators. The Gompertz´s model for growth, and Mc Nally´s for laying, were the best predicting tools for production. Along with GLIMMIX, they will contribute with suitable criteria for better decision making to increase egg production