Organopalladium catalyst on S-terminated GaAs(001)-(2×6) surface

Organopalladium molecules, such as Pd(CH3COO)2 ({Pd}), immobilized on the S-terminated GaAs(001), termed GaAs–S–{Pd} have high catalytic activity and cycle durability in the Mizoroki–Heck reaction. It is thought that the presence of Ga–S bonds in the single atomic layer S-termination is essential for these catalytic properties despite the much higher thickness (~100 nm) of the {Pd} films. In this study, the authors demonstrate the retention of Ga–S bonds in ultrathin GaAs–S–{Pd} by using reflection high-energy electron diffraction and scanning tunneling microscopy (STM). The ultrathin GaAs–S–{Pd} was prepared by using a vapor-deposition technique. Deposited {Pd} was observed as ~1 nm dotlike structures with STM. The adsorption rate of {Pd} was also investigated

Molecular beam epitaxial growth of high-quality InSb on InP and GaAs substrates

Epitaxial layers of InSb were grown on InP and GaAs substrates by molecular beam epitaxy. The dependence of the epilayer quality on flux ratio, J sub Sb4/J sub In, was studied. Deviation from an optimum value of J sub Sb4/J sub In (approx. 2) during growth led to deterioration in the surface morphology and the electrical and crystalline qualities of the films. Room temperature electron mobilities as high as 70,000 and 53,000 sq cm /V-s were measured in InSb layers grown on InP and GaAs substrates, respectively. Unlike the previous results, the conductivity in these films is n-type even at T = 13 K, and no degradation of the electron mobility due to the high density of dislocations was observed. The measured electron mobilities (and carrier concentrations) at 77 K in InSb layers grown on InP and GaAs substrates are 110,000 sq cm/V-s (3 x 10(15) cm(-3)) and 55,000 sq cm/V-s (4.95 x 10(15) cm(-3)), respectively, suggesting their application to electronic devices at cryogenic temperatures

Energy Loss Function and Source Function for Au 4f Photoelectrons Derived by Monte Carlo Analysis of Reflection Electron Energy Loss Spectroscopy (REELS) and X-Ray Photoelectron Spectroscopy (XPS) Spectra

We have derived the energy loss function of Au for 1 keV electrons by Monte Carlo analysis of the reflection electron energy loss spectroscopy (REELS) spectra. This energy loss function was significantly different from the optical loss function widely used and has revealed that the surface excitation affects the energy loss spectrum of keV electrons. X-ray photoelectron spectroscopy (XPS) background subtraction has been recently developed by using the energy loss function derived from the transmission electron energy loss spectroscopy (TEELS). We have demonstrated that the energy loss function derived from REELS has enabled a more accurate Au 4f XPS spectrum to be obtained after subtraction of the inelastic background

Comparison of Lidocaine-Xylazine and Procaine-Xylazine for Lumbar Epidural Anesthesia in Cattle

NO ABSTRACT AVAILABLELumbar epidural anesthesia is commonly utilized in veterinary medicine for diagnostic, obstetrical, and surgical intervention in the abdominal and perineal regions of large animals. The aim of this study was to directly compare the time to onset and duration of epidural anesthesia produced by lidocaine-xylazine and procaine-xylazine combinations to that produced by xylazine alone in cattle. A total of 24 healthy adult Holstein dairy cows were included in this study. The time to onset and duration of anesthesia were recorded. The heart rate, respiratory rate, and rectal temperature were recorded at 0 minute and at 10, 20, 30, 60, and 90 minutes after the epidural administration of each treatment. The time to onset of anesthesia did not significantly differ between the xylazine only group and the lidocaine-xylazine and procaine-xylazine combination groups. The duration of anesthesia in the xylazine only group was significantly shorter than that in the lidocaine-xylazine and procaine-xylazine combination groups (p < 0.05). Ataxia was not observed in any group. The heart rate, respiratory rate, and rectal temperature values in all the treatment groups throughout the study did not significantly differ from those at baseline. We found that administration of procaine hydrochloride in combination with xylazine hydrochloride, an α2-adrenergic receptor agonist, offers the same time to onset and duration of anesthesia as does epidural anesthesia using a combination of lidocaine hydrochloride and xylazine hydrochloride. Furthermore, this combination of treatments did not cause adverse effects in the cardiovascular and respiratory systems. These findings indicate that combined administration of procaine and xylazine is an economic and useful approach for epidural anesthesia

Formation of Protoplanets from Massive Planetesimals in Binary Systems

More than half of stars reside in binary or multiple star systems and many planets have been found in binary systems. From theoretical point of view, however, whether or not the planetary formation proceeds in a binary system is a very complex problem, because secular perturbation from the companion star can easily stir up the eccentricity of the planetesimals and cause high-velocity, destructive collisions between planetesimals. Early stage of planetary formation process in binary systems has been studied by restricted three-body approach with gas drag and it is commonly accepted that accretion of planetesimals can proceed due to orbital phasing by gas drag. However, the gas drag becomes less effective as the planetesimals become massive. Therefore it is still uncertain whether the collision velocity remains small and planetary accretion can proceed, once the planetesimals become massive. We performed {\it N}-body simulations of planetary formation in binary systems starting from massive planetesimals whose size is about 100-500 km. We found that the eccentricity vectors of planetesimals quickly converge to the forced eccentricity due to the coupling of the perturbation of the companion and the mutual interaction of planetesimals if the initial disk model is sufficiently wide in radial distribution. This convergence decreases the collision velocity and as a result accretion can proceed much in the same way as in isolated systems. The basic processes of the planetary formation, such as runaway growth and oligarchic growth and final configuration of the protoplanets are essentially the same in binary systems and single star systems, at least in the late stage where the effect of gas drag is small.Comment: 26pages, 11 figures. ApJ accepte

A New Analysis Method for Simulations Using Node Categorizations

Most research concerning the influence of network structure on phenomena taking place on the network focus on relationships between global statistics of the network structure and characteristic properties of those phenomena, even though local structure has a significant effect on the dynamics of some phenomena. In the present paper, we propose a new analysis method for phenomena on networks based on a categorization of nodes. First, local statistics such as the average path length and the clustering coefficient for a node are calculated and assigned to the respective node. Then, the nodes are categorized using the self-organizing map (SOM) algorithm. Characteristic properties of the phenomena of interest are visualized for each category of nodes. The validity of our method is demonstrated using the results of two simulation models. The proposed method is useful as a research tool to understand the behavior of networks, in particular, for the large-scale networks that existing visualization techniques cannot work well.Comment: 9 pages, 8 figures. This paper will be published in Social Network Analysis and Mining(www.springerlink.com

Rescue with an anti-inflammatory peptide of chickens infected H5N1 avian flu

Chickens suffering from avian flu caused by H5N1 influenza virus are destined to die within 2 days due to a systemic inflammatory response. Since HVJ infection (1,2) and influenza virus infection (3,4) cause infected cells to activate homologous serum complement, the systemic inflammatory response elicited could be attributed to the unlimited generation of C5a anaphylatoxin of the complement system, which is a causative peptide of serious inflammation. In monkeys inoculated with a lethal dose of LPS (4 mg/kg body weight), inhibition of C5a by an inhibitory peptide termed AcPepA (5) rescued these animals from serious septic shock which would have resulted in death within a day (6). Therefore, we tested whether AcPepA could also have a beneficial effect on chickens with bird flu. On another front, enhanced production of endothelin-1 (ET-1) and the activation of mast cells (MCs) have been implicated in granulocyte sequestration (7). An endothelin receptor derived antisense homology box peptide (8) designated ETR-P1/fl was shown to antagonize endothelin A receptor (ET-A receptor) (9) and reduce such inflammatory responses as endotoxin-shock (10) and hemorrhagic shock (11), thereby suppressing histamine release in the circulation (12). Thus, we also administered ETR-P1/fl to bird flu chickens expecting suppression of a systemic inflammatory response

Evidence of Luttinger liquid behavior in one-dimensional dipolar quantum gases

The ground state and structure of a one-dimensional Bose gas with dipolar repulsions is investigated at zero temperature by a combined Reptation Quantum Monte Carlo (RQMC) and bosonization approach. A non trivial Luttinger-liquid behavior emerges in a wide range of intermediate densities, evolving into a Tonks-Girardeau gas at low density and into a classical quasi-ordered state at high density. The density dependence of the Luttinger exponent is extracted from the numerical data, providing analytical predictions for observable quantities, such as the structure factor and the momentum distribution. We discuss the accessibility of such predictions in current experiments with ultracold atomic and molecular gases.Comment: 4 pages, 3 EPS figures, Revtex