Condensation and subsequent freezing delays as a result of using femtosecond laser functionalized surfaces

In this paper, the authors report on the use of femtosecond laser surface processing (FLSP) to enhance the anti-icing properties of a commonly used aircraft alloy, Al 7075-O Clad. By changing the surface morphology through FLSP and the surface chemistry through siloxane vapor deposition, the wettability of Al 7075-O Clad was altered. Tall mound and short mound FLSP functionalized surfaces were created through two sets of laser parameters. Condensation and the subsequent freezing of condensates on FLSP Al 7075-O Clad was studied. Both structure height and surface wettability were shown to play a role in the delay of freezing. Freezing occurred on the FLSP superhydrophilic surface faster than on the unprocessed Al 7075-O Clad surface; however, freezing was delayed for all superhydrophobic FLSP surfaces. Tall structure height FLSP functionalized surfaces delayed freezing time longer than short structure height FLSP functionalized surfaces although all were superhydrophobic. It was shown that FLSP functionalized surfaces were able to delay freezing by up to 530 s compared with unprocessed Al 7075-O Clad. The authors also report on self-propelled condensate jumping on FLSP surfaces during the condensing process. The selfpropelled jumping phenomena provide a means to promote anti-icing of materials, especially where jumping drops can be swept away in flow conditions

GASTROINTESTINAL SENSOR IMPLANTATION SYSTEM

A gastrointestinal ( GI ) sensor deployment device is dis closed . In implementations , the sensor deployment device includes an orally - administrable capsule with a tissue cap ture device removably coupled to the orally - administrable capsule . The tissue capture device includes a plurality of fasteners for connecting the tissue capture device to GI tissue within a body . A biometric sensor is coupled to the tissue capture device for continuous or periodic monitoring of the GI tract of the body at the GI tissue attachment location . A chamber within the orally - administrable capsule is configured to draw gastrointestinal tissue towards the plurality of fasteners when a fluid pressure of the chamber is increased . An actuator can be configured to cause an increase of the fluid pressure of the chamber . Control circuitry coupled to the actuator can be configured to trigger the actuator to cause the increase of the fluid pressure of the chamber at a selected tim

Quantifying Wicking in Functionlized Surfaces

Wicking remains the enigmatic key factor in many research areas. From boiling in power plants, to anti-icing on plane wings, to medical instruments, to heat pipes, efficiency and safety depend on how quickly a surface becomes wet. Yet wicking remains difficult to quantify and define as a property of the surface. This experiment strives to measure the wicking property by examining the rate that a liquid can be pulled out of a container. A superhydrophilic surface is placed in contact with the liquid at the bottom of a tube so that the volume flow rate across the surface can be monitored by a camera. By tracking the liquid level in the tube as a function of time, the wicking property of the surface can be quantified. Different tube sizes were compared to ensure that a property of the surface was being accurately measured

POOL BOILING INVERSION ON FEMTOSECOND LASER SURFACE PROCESSED 304 STAINLESS STEEL AND ITS IMPACT ON STEADY-STATE TIME CONSTANTS

FLSP surfaces resulting in boiling inversion require longer times to reach steady-state once inversion has occurred Boiling inversion has been shown to be the result of changing nucleation dynamics in which a large number of nucleation sites activate Increased time required to reach steady-state is linked to the rate at which these nucleation sites activate. Heat fluxes above the boiling inversion point can require up to an additional 3 hours to reach steady-state, compared to the typical 15-20 minutes reported in the literatur

Formation of aggregated nanoparticle spheres through femtosecond laser surface processing

A detailed structural and chemical analysis of a class of self-organized surface structures, termed aggregated nanoparticle spheres (AN-spheres), created using femtosecond laser surface processing (FLSP) on silicon, silicon carbide, and aluminum is reported in this paper. AN-spheres are spherical microstructures that are 20–100 μm in diameter and are composed entirely of nanoparticles produced during femtosecond laser ablation of material. AN-spheres have an onion-like layered morphology resulting from the build-up of nanoparticle layers over multiple passes of the laser beam. The material properties and chemical composition of the AN-spheres are presented in this paper based on scanning electron microscopy (SEM), focused ion beam (FIB) milling, transmission electron microscopy (TEM), and energy dispersive x-ray spectroscopy (EDX) analysis. There is a distinct difference in the density of nanoparticles between concentric rings of the onion-like morphology of the AN-sphere. Layers of high-density form when the laser sinters nanoparticles together and low-density layers form when nanoparticles redeposit while the laser ablates areas surrounding the AN-sphere. The dynamic nature of femtosecond laser ablation creates a variety of nanoparticles that make-up the AN-spheres including Si/C core-shell, nanoparticles that directly fragmented from the base material, nanoparticles with carbon shells that retarded oxidation, and amorphous, fully oxidized nanoparticles

Near-unity broadband omnidirectional emissivity via femtosecond laser surface processing

It is very challenging to achieve near perfect absorption/emission that is both broadband and omnidirectional while utilizing a scalable fabrication process. Femtosecond laser surface processing is an emerging low-cost and large-scale manufacturing technique used to directly and permanently modify the surface properties of a material. The versatility of this technique to produce tailored surface properties has resulted in a rapidly growing number of applications. Here, we demonstrate near perfect, broadband, omnidirectional emissivity from aluminum surfaces by tuning the laser surface processing parameters including fluence, pulse count, and the ambient gas. Full-wave simulations and experimental results prove that the obtained increase in emissivity is mainly a result of two distinct features produced by femtosecond laser surface processing: the introduction of microscale surface features and the thick oxide layer. This technique leads to functionalized metallic surfaces that are ideal for emerging applications, such as passive radiative cooling and thermal management of spacecraft

Micro/nanostructures formation by femtosecond laser surface processing on amorphous and polycrystalline Ni60Nb40

Femtosecond laser surface processing is a technology that can be used to functionalize many surfaces, imparting specialized properties such as increased broadband optical absorption or superhydrophilicity/superhydrophobicity. In this study, two unique classes of surface structures, below surface growth (BSG) and above surface growth (ASG) mounds, were formed by femtosecond laser surface processing on amorphous and polycrystalline Ni60Nb40 with two different grain sizes. Cross sectional imaging of these mounds revealed thermal evidence of the unique formation processes for each class of surface structure. BSG mounds formed on all three substrates using the same laser parameters had similar surface morphology. The microstructures in the mounds were unaltered compared with the substrate before laser processing, suggesting their formation was dominated by preferential valley ablation. ASG mounds had similar morphology when formed on the polycrystalline Ni60Nb40 substrates with 100 nm and 2 [H9262]m grain size. However, the ASG mounds had significantly wider diameter and higher peak-to-valley heights when the substrate was amorphous Ni60Nb40. Hydrodynamic melting was primarily responsible for ASG mound formation. On amorphous Ni60Nb40 substrates, the ASG mounds are most likely larger due to lower thermal diffusivity. There was clear difference in growth mechanism of femtosecond laser processed BSG and ASG mounds, and grain size does not appear to be a factor

Age and gender differences in physical capability levels from mid-life onwards: The Harmonisation and meta-analysis of data from eight UK cohort studies

Using data from eight UK cohorts participating in the Healthy Ageing across the Life Course (HALCyon) researchprogramme, with ages at physical capability assessment ranging from 50 to 90+ years, we harmonised data on objectivemeasures of physical capability (i.e. grip strength, chair rising ability, walking speed, timed get up and go, and standingbalance performance) and investigated the cross-sectional age and gender differences in these measures. Levels of physicalcapability were generally lower in study participants of older ages, and men performed better than women (for example,results from meta-analyses (N = 14,213 (5 studies)), found that men had 12.62 kg (11.34, 13.90) higher grip strength thanwomen after adjustment for age and body size), although for walking speed, this gender difference was attenuated afteradjustment for body size. There was also evidence that the gender difference in grip strength diminished with increasingage,whereas the gender difference in walking speed widened (p,0.01 for interactions between age and gender in bothcases). This study highlights not only the presence of age and gender differences in objective measures of physicalcapability but provides a demonstration that harmonisation of data from several large cohort studies is possible. Theseharmonised data are now being used within HALCyon to understand the lifetime social and biological determinants ofphysical capability and its changes with age

Subsurface Understanding of the Formation of Hierarchical Surface Structures Produced with Femtosecond Laser Pulses

Femtosecond lasers were first utilized for precision cutting/drilling and spectroscopy, but as peak laser power increased, so did the number of applications, including surface functionalization. Femtosecond laser pulses can create self-organized micro/nanostructures on the surface of most materials by controlling processing parameters such as laser fluence, number of pulses per area, and environment. Researchers primarily study the hierarchical structures by analyzing surface topology and chemistry, although, the complex processes that lead to structure formation cannot be understood solely with surface sensitive techniques. In this dissertation, self-organized structures are cross-sectioned and subsurface features are investigated to explain their formation mechanisms. A newly developed technique utilizing layers of aluminum and low carbon steel is presented. Visualizing the redistribution of material by each formation mechanism is possible by taking advantage of the chemical contrast of the different metals in energy dispersive x-ray spectroscopy maps and line scans. This work differentiates between areas that developed through each of the structure formation mechanisms: preferential ablation, redeposition of ablated materials, fluid flow, and resolidification of melted/sintered materials. Potential applications of multi-material, multi-layered structures are briefly explored. In addition, the effect of other processing parameters is investigated including processing gas, pressure, and laser polarization. Detailed studies of aluminum processed in nitrogen-rich gases is compared to processing in air. With the proper conditions, aluminum nitride is incorporated into the self-organized surface structures which has applications in heat transfer

POOL BOILING INVERSION ON FEMTOSECOND LASER SURFACE PROCESSED 304 STAINLESS STEEL AND ITS IMPACT ON STEADY-STATE TIME CONSTANTS

FLSP surfaces resulting in boiling inversion require longer times to reach steady-state once inversion has occurred Boiling inversion has been shown to be the result of changing nucleation dynamics in which a large number of nucleation sites activate Increased time required to reach steady-state is linked to the rate at which these nucleation sites activate. Heat fluxes above the boiling inversion point can require up to an additional 3 hours to reach steady-state, compared to the typical 15-20 minutes reported in the literatur