125 research outputs found
17O NMR study of the intrinsic magnetic susceptibility and spin dynamics of the quantum kagome antiferromagnet ZnCu3(OH)6Cl2
We report through 17O NMR, an unambiguous local determination of the
intrinsic kagome lattice spin susceptibility as well as that created around
non-magnetic defects issued from natural Zn/ Cu exchange in the S=1/2 (Cu2+)
herbertsmithite ZnCu3(OH)6Cl2 compound. The issue of a singlet-triplet gap is
addressed. The magnetic response around a defect is found to markedly differ
from that observed in non-frustrated antiferromagnetic materials. Finally, we
discuss our relaxation measurements in the light of Cu and Cl NMR data
[cond-mat 070314] and suggest a flat q-dependence of the excitations.Comment: Accepted for publication in Phys. Rev. Lett., 3 jan. 2008 Figure 1
has been modified to include a two-components fit of the 17O NMR spectru
Ground state of the Kagome-like S=1/2 antiferromagnet, Volborthite Cu3V2O7(OH)2.2H2O
Volborthite compound is one of the very few realizations of S=1/2 quantum
spins on a highly frustrated kagome-like lattice. Low-T SQUID measurements
reveal a broad magnetic transition below 2K which is further confirmed by a
peak in the 51V nuclear spin relaxation rate (1/T1) at 1.4K0.2K. Through
51V NMR, the ground state (GS) appears to be a mixture of different spin
configurations, among which 20% correspond to a well defined short range order,
possibly of the type. While the freezing involve all
the Cu spins, only 40% of the copper moment is actually frozen which
suggests that quantum fluctuations strongly renormalize the GS.Comment: 4 pages, 4 figures, to appear in PR
Dzyaloshinsky-Moriya Anisotropy in the Spin-1/2 Kagom\'e Compound ZnCu(OH)Cl
We report the determination of the Dzyaloshinsky-Moriya interaction, the
dominant magnetic anisotropy term in the \kagome spin-1/2 compound {\herbert}.
Based on the analysis of the high-temperature electron spin resonance (ESR)
spectra, we find its main component K to be perpendicular to the
\kagome planes. Through the temperature dependent ESR line-width we observe a
building up of nearest-neighbor spin-spin correlations below 150 K.Comment: 4 pages, 3 figures, minor modification
Field-Induced Freezing of a Quantum Spin Liquid on the Kagome Lattice
We report 17O NMR measurements in the S=1/2 Cu2+ kagome antiferromagnet
Herbertsmithite ZnCu3(OH)6Cl2 down to 45mK in magnetic fields ranging from 2T
to 12T. While Herbertsmithite displays a gapless spin-liquid behavior in zero
field, we uncover an instability toward a spin-solid phase at sub-kelvin
temperature induced by an applied magnetic field. The latter phase shows
largely suppressed moments \lesssim 0.1\muB and gapped excitations. The H-T
phase diagram suggests the existence of a quantum critical point at the small
but finite magnetic field mu0 Hc=1.55(25)T. We discuss this finding in light of
the perturbative Dzyaloshinskii-Moriya interaction which was theoretically
proposed to sustain a quantum critical regime for the quantum kagome Heisenberg
antiferromagnet model.Comment: One link added for supplemental materials. Published in : Phys. Rev.
Lett. 107, 237201 (2011
Ab initio investigation of VOSeO3, a spin gap system with coupled spin dimers
Motivated by an early experimental study of VOSeO3, which suggested that it
is a quasi-2D system of weakly coupled spin dimers with a small spin gap, we
have investigated the electronic structure of this material via
density-functional calculations. These ab initio results indicate that the
system is better thought of as an alternating spin-1/2 chain with moderate
interchain interactions, an analog of (VO)2P2O7. The potential interest of this
system for studies in high magnetic field given the presumably small value of
the spin gap is emphasized.Comment: 4 pages, 5 figure
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