Experimental and modeling study of the autoignition of 1-hexene/iso-octane mixtures at low temperatures

Autoignition delay times have been measured in a rapid compression machine at Lille at temperatures after compression from 630 to 840 K, pressures from 8 to 14 bar, \Phi = 1 and for a iso octane/1 hexene mixture containing 82% iso-octane and 18% 1 hexene. Results have shown that this mixture is strongly more reactive than pure iso-octane, but less reactive than pure 1 hexene. It exhibits a classical low temperature behaviour, with the appearance of cool flame and a negative temperature coefficient region. The composition of the reactive mixture obtained after the cool flame has also been determined. A detailed kinetic model has been obtained by using the system EXGAS, developed in Nancy for the automatic generation of kinetic mechanisms, and an acceptable agreement with the experimental results has been obtained both for autoignition delay times and for the distribution of products. A flow rate analysis reveals that the crossed reactions between species coming from both reactants (like H-abstractions or combinations) are negligible in the main flow consumption of the studied hydrocarbons. The ways of formation of the main primary products observed and the most sensitive rate constants have been identified

Progress on the Beam Energy Monitor for the SPIRAL2 Accelerator.

WEPF29, posterInternational audienceThe first part of the SPIRAL2 project entered last year in the end of the construction phase at GANIL in France. The facility will be composed by an ion source, a deuteron/proton source, a RFQ and a superconducting linear accelerator. The driver is planned to accelerate high intensities, up to 5 mA and 40 MeV for the deuteron beams. A monitoring system was built to measure the beam energy on the BTI line (Bench of Intermediate Test) at the exit of the RFQ. As part of theMEBT commissioning, the beamenergy will be measured on the BTI with an Epics monitoring application. At the exit of the LINAC, another system will have to measure and control the beam energy. The control consists in ensuring that the beam energy stays under a limit by taking account of the measurement uncertainty. The energy is measured by a method of time of flight; the signal is captured by non-intercepting capacitive pick-ups. This paper describes the BTI monitor interface and presents the system evolution following the design review

A transfer matrix approach to the enumeration of plane meanders

A closed plane meander of order $n$ is a closed self-avoiding curve intersecting an infinite line $2n$ times. Meanders are considered distinct up to any smooth deformation leaving the line fixed. We have developed an improved algorithm, based on transfer matrix methods, for the enumeration of plane meanders. While the algorithm has exponential complexity, its rate of growth is much smaller than that of previous algorithms. The algorithm is easily modified to enumerate various systems of closed meanders, semi-meanders, open meanders and many other geometries.Comment: 13 pages, 9 eps figures, to appear in J. Phys.

Modelization of flow electrification in a polymer melt

Flow electrification of polymer melts is an important side effect of polymer processing. The studies dealing with this phenomenon are seldom and most of the scientific work has been focused on flow electrification of aqueous and insulating Newtonian liquids. From that prior art it is well established that the flow electrification in Newtonian liquids is a consequence of the formation of an ionic double layer. Convection of this layer induces the electrification of the liquid at the outlet of the pipe. In those models, the key parameters governing the flow electrification are thus the intrinsic electrical properties of the polymer and the flow characteristics. In this work, we reconsider the assumptions made previously and we propose a new approach to modelise the flow electrification in the particular case of non-Newtonian polymer materials in laminar flow conditions. We establish that, a key parameter for the electrification quantification in the polymer melt is the shape of the velocity profile. Additionally, in some cases, we show that a slip velocity at the polymer/die wall interface must be considered to describe accurately the electrification. As a consequence, we deduce that the slip velocity at the interface can be calculated by measuring the electrification: this work gives an alternative manner to measure the slip velocity during polymer flow

Prospects of airflow control by a gliding arc in a static magnetic field

Abstract The electrical properties of a gliding arc operating in air at atmospheric pressure are studied to evaluate its possible applications to flow control. The electromechanical behaviour of the discharge travelling at 4 m s −1 along diverging electrodes in a static magnetic field is analysed in detail. Two different methods are proposed to evaluate the velocity of the arc. An initial estimation is based on the arc current evolution during its transit and additional information is gained from fast digital imaging with a CCD camera. The displacement of the arc observed with short exposure time corroborates the electrical measurement and also exhibits the existence of luminous points on the cathode that can slow down the arc motion. In addition, a particle image velocimetry system is used to investigate the interaction between the gliding arc and the surrounding air. The displacement of the low current glidarc creates a low velocity convection (around 0.2 m s −1 ) in the gas and also generate faster structures up to 1 m s −1 directly in front of the discharge. These electromechanical effects could be used to manipulate the boundary layer region of various aerodynamic shapes

Isotope shift calculations for atoms with one valence electron

This work presents a method for the ab initio calculation of isotope shift in atoms and ions with one valence electron above closed shells. As a zero approximation we use relativistic Hartree-Fock and then calculate correlation corrections. The main motivation for developing the method comes from the need to analyse whether different isotope abundances in early universe can contribute to the observed anomalies in quasar absorption spectra. The current best explanation for these anomalies is the assumption that the fine structure constant, alpha, was smaller at early epoch. We test the isotope shift method by comparing the calculated and experimental isotope shift for the alkali and alkali-like atoms Na, MgII, K, CaII and BaII. The agreement is found to be good. We then calculate the isotope shift for some astronomically relevant transitions in SiII and SiIV, MgII, ZnII and GeII.Comment: 11 page

The SPIRAL2 control system progress towards the commissioning phase

MOCOAAB03, http://accelconf.web.cern.ch/AccelConf/ICALEPCS2013/papers/mocoaab03.pdfInternational audienceThe commissioning of the first phase of the Spiral2 Radioactive Ion Beams facility at Ganil will soon start, so requiring the control system components to be delivered in time. Yet, parts of the system were validated during preliminary tests performed with ions and deuterons beams at low energy. The control system development results from the collaboration between Ganil, CEA-IRFU, CNRS-IPHC laboratories, using appropriate tools and approach. Based on Epics, the control system follows a classical architecture. At the lowest level, Modbus/TCP protocol is considered as a field bus. Then, equipment are handled by IOCs (soft or VME/VxWorks) with a software standardized interface between IOCs and clients applications on top. This last upper layer consists of Epics standard tools, CSS/BOY user interfaces within the socalled CSSop Spiral2 context suited for operation and, for machine tunings, high level applications implemented by Java programs developed within a Spiral2 framework derived from the open-Xal one. Databases are used for equipment data and alarms archiving, to configure equipment and to manage the machine lattice and beam settings. A global overview of the system is therefore here proposed

Shape Coexistence and the Effective Nucleon-Nucleon Interaction

The phenomenon of shape coexistence is discussed within the self-consistent Hartree-Fock method and the nuclear shell model. The occurrence of the coexisting configurations with different intrinsic shapes is traced back to the properties of the effective Hamiltonian.Comment: 40 pages (16 text, 24 figures). The file may also be retrieved at http://csep2.phy.ornl.gov/theory_group/people/dean/shape_coex/shapes.htm