A global model for the combustion of gas mixtures released from forest fuels

International audienc

Direct synthesis of mesoporous silica containing cobalt: A new strategy using a cobalt soap as a co-template

A novel approach to incorporate transition metals into porous structures is presented, which makes use of a cobalt soap in combination with the templating agent C16TMABr. An ordered mesoporous silica MCM-41 type material doped with Co is obtained after removal of the organic part by calcination. The a unit cell parameter of the cobalt containing mesoporous matrices is larger than that of pure MCM-41 and increases with the amount of cobalt present in the sample as well as the diameter of the pores. This is not observed when e.g. cobalt acetate is employed instead of the metal soap. The procedure presented establishes a new route for the incorporation of a transition metal into MCM-41 together with a tuning of the porous structure

Skeletal and global mechanisms for the combustion of gases released by crushed forest fuels

International audienc

Evolution of Ossoue Glacier (French Pyrenees) since the end of the Little Ice Age

International audienceLittle is known about the fluctuations of the Pyre-nean glaciers. In this study, we reconstructed the evolution of Ossoue Glacier (42 • 46 N, 0.45 km 2), which is located in the central Pyrenees, from the Little Ice Age (LIA) onwards. To do so, length, area, thickness, and mass changes in the glacier were generated from historical data sets, topo-graphical surveys, glaciological measurements (2001–2013), a ground penetrating radar (GPR) survey (2006), and stereo-scopic satellite images (2013). The glacier has receded considerably since the end of the LIA, losing 40 % of its length and 60 % of its area

Molecular Clusters in Mesoporous Materials as Precursors to Nanoparticles of a New Lacunar Ternary Compound PdxMoyP

Bimetallic clusters of composition Pd2Mo2(g5-C5H5)2(l3-CO)2(l2-CO)4 (PR3)2 (R = ethyl or phenyl) were incorporated by impregnation from solution into two different silica matrices, amorphous xerogels and ordered SBA-15, and a study of their thermal decomposition under a reducing atmosphere is reported. With both matrices, a suitable thermal treatment afforded nanoparticles of a new bimetallic phosphide. Although nanoparticles of composition PdxMoyP, isostructural with Mo3P, were formed in both matrices, they were more uniformly distributed in the SBA-15 framework and showed a narrower size distribution. The samples have been characterized by powder XRD, chemical analysis, FT-IR spectroscopy, TEM and electron tomography (3D TEM)

Crystallinity depends on choice of iron salt precursor in the continuous hydrothermal synthesis of Fe–Co oxide nanoparticles

A series of Fe–Co oxide nanoparticles (NPs) were prepared by a continuous hydrothermal method using iron nitrate and ammonium iron citrate as alternative iron precursors. The crystallinity, Fe/Co composition and element spatial distribution in the synthesised NPs were investigated using X-ray diffraction (XRD), aberration-corrected scanning transmission electron microscopy (ac-STEM) imaging, energy-dispersive X-ray spectroscopy (EDX) and electron energy loss spectroscopy (EELS). Strong dependence on the choice of iron salt was observed. We demonstrate that the presence of ammonium citrate markedly improves the crystallinity of the NPs; an ordered cobalt ferrite alloy is formed. We suggest this is due to the formation of a homogenous reaction environment during the thermal decomposition of ammonium citrate, and the formation of complexes among citrate, Fe and Co ions

On the interest of studying degradation gases for forest fuel combustion modeling

International audienc