8 research outputs found

    1,1,2,2-Tetra­kis(1,3-benzoxazol-2-yl)ethene

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    The title compound, C30H16N4O4, reveals crystallographic and mol­ecular symmetry and accordingly the asymmetric unit comprises one half-mol­ecule. The dihedral angle between the planes of the two geminal benzoxazole rings is 74.39 (5)°. The packing features weak C—H⋯N and π–π inter­actions [centroid–centroid distance = 3.652 (1) Å]

    1,3-Dimesitylimidazolidinium tetra­chloridogold(III) dichloro­methane solvate

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    The title ionic compound, (C21H27N2)[AuCl4]·CH2Cl2, was obtained from the reaction of 1,3-dimesitylimidazolidinium chloride with t-BuOK and a solution of AuCl3 in tetra­hydro­furan. In the crystal structure, numerous weak C—H⋯Cl hydrogen bonds form double layers parallel to (100), which are further stabilized by π–π inter­actions between mesitylene rings [centroid–centroid distance = 4.308 (4) Å], resulting in the formation of a three-dimensional supra­molecular assembly

    1,1,2,2-Tetrakis(1,3-benzothiazol-2-yl)ethene chloroform disolvate

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    The asymmetric unit of the title solvate, C30H16N4S4·2CHCl3, contains one half-molecule of tetrakis(2-benzothiazolyl)ethene, the complete molecule being generated by inversion symmetry, and one molecule of chloroform. Pairs of the benzothiazole rings attached to the same carbon atom are almost perpendicular to each other, with an angle between planes of 85.74 (4)°. In the crystal, weak C—H...N and C—H...Cl interactions generate a three-dimensional network
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