946 research outputs found
Universal quasiparticle decoherence in hole- and electron-doped high-Tc cuprates
We use angle-resolved photoemission to unravel the quasiparticle decoherence
process in the high- cuprates. The coherent band is highly renormalized,
and the incoherent part manifests itself as a nearly vertical ``dive'' in the
- intensity plot that approaches the bare band bottom. We find that the
coherence-incoherence crossover energies in the hole- and electron-doped
cuprates are quite different, but scale to their corresponding bare bandwidth.
This rules out antiferromagnetic fluctuations as the main source for
decoherence. We also observe the coherent band bottom at the zone center, whose
intensity is strongly suppressed by the decoherence process. Consequently, the
coherent band dispersion for both hole- and electron-doped cuprates is
obtained, and is qualitatively consistent with the framework of Gutzwiller
projection.Comment: 4 pages, 4 figure
Further study on 5q configuration states in the chiral SU(3) quark model
The structure of the configuration states with strangeness
is further studied in the chiral SU(3) quark model based on our
previous work. We calculate the energies of fifteen low configurations of the
system, four lowest configurations of with
partition , four of with
partition and seven of
with partition . Some modifications are
made in this further study, i.e., the orbital wave function is extended as an
expansion of 4 different size harmonic oscillator forms; three various forms
(quadratic, linear and error function form) of the color confinement potential
are considered; the states with partition are added, which are unnegligible in the case and were
not considered in our previous paper, further the mixing between configurations
and is
also investigated. The results show that the T=0 state is still always the
lowest one for both and states, and
state is always lower than that of .
All of these modifications can only offer several tens to hundred MeV effect,
and the theoretical value of the lowest state is still about 245 MeV higher
than the experimental mass of . It seems to be difficult to get the
calculated mass close to the observed one with the reasonable parameters in the
framework of the chiral SU(3) quark model when the model space is chosen as a
cluster.Comment: 16 page
Effect of Langmuir monolayer of bovine serum albumin protein on the morphology of calcium carbonate
Bovine serum albumin (BSA) Langmuir monolayer, as a model of
biomineralization-associated proteins, was used to study its effect on
regulated biomineralization of calcium carbonate. The effects of the BSA
Langmuir monolayer and the concentration of the subphase solution on the
nucleation and growth processes and morphology of the calcium carbonate crystal
were investigated. The morphology and polymorphic phase of the resulting
calcium carbonate crystals were characterized by scanning electron microscopy
(SEM) and X-ray diffraction analysis (XRD). Moreover, the interaction
mechanisms of the subphase solution with the BSA Langmuir monolayer were
discussed. It was found that BSA Langmuir monolayer could be used as a template
to successfully manipulate the polymorphic phase and crystal morphology of
calcium carbonate and had obvious influence on the oriented crystallization and
growth. The final morphology or aggregation mode of the calcite crystal was
closely dependent on the concentration of calcium bicarbonate solution. It is
expected that this research would help to better understand the mechanism of
biomineralization by revealing the interactions between protein matrices and
crystallization of calcium carbonate crystal.Comment: 4 pages, 4 figure
X-ray absorption spectroscopy and novel electronic properties in heavy fermion compounds YbT2Zn20 (T: Rh and Ir)
YbT2Zn20 (T: Rh and Ir), which crystallizes in the cubic CeCr2Al20-type structure, is a member of the well-known heavy fermion compounds, indicating a huge electronic specific heat coefficient γ ≊ 500 mJ/(K2centerdotmol). We have measured temperature and magnetic field dependences of Yb valence in YbT2Zn20(T: Rh and Ir) at ambient pressure by the Lm edge x- ray absorption spectroscopy in order to investigate the valence state of Yb 4f electrons in these compounds. It is revealed that the Yb valence in both compounds significantly decreases with temperature below about 100 K and increases with increasing magnetic field at low temperatures in contrast to the case of YbCo2Zn20.International Conference on Strongly Correlated Electron Systems 2014 (SCES2014), 7–14 July 2014, Grenoble, Franc
Demonstration of Magnetoelectric Scanning Probe Microscopy
A near-field room temperature scanning magnetic probe microscope has been developed using a laminated magnetoelectric sensor. The simple trilayer longitudinal-transverse mode sensor, fabricated using Metglas as the magnetostrictive layer and polyvinylidene fluoride as the piezoelectric layer, shows an ac field sensitivity of 467±3μV∕Oe in the measured frequency range of 200Hz–8kHz. The microscope was used to image a 2mm diameter ring carrying an ac current as low as 10−5A. ac fields as small as 3×10−10T have been detected
A study of the inclusion of prelayers in InGaN/GaN single- and multiple-quantum-well structures
We report on the effects on the optical properties of blue-light emitting InGaN/GaN single- and multiple-quantum-well structures including a variety of prelayers. For each single-quantum-well structure containing a Si-doped prelayer, we measured a large blue shift of the photoluminescence peak energy and a significant increase in radiative recombination rate at 10 K. Calculations of the conduction and valence band energies show a strong reduction in the built-in electric field across the quantum well (QW) occurs when including Si-doped prelayers, due to enhancement of the surface polarization field which opposes the built-in field. The reduction in built-in field across the QW results in an increase in the electron–hole wavefunction overlap, increasing the radiative recombination rate, and a reduction in the strength of the quantum confined Stark effect, leading to the observed blue shift of the emission peak. The largest reduction of the built-in field occurred for an InGaN:Si prelayer, in which the additional InGaN/GaN interface of the prelayer, in close proximity to the QW, was shown to further reduce the built-in field. Study of multiple QW structures with and without an InGaN:Si prelayer showed the same mechanisms identified in the equivalent single-quantum-well structure.This work was carried out with the financial support of the United Kingdom Engineering and Physical Sciences Research Council under Grant Numbers EP/I012591/1 and EP/H011676/1.This is the accepted manuscript. The final version's available from Wiley at http://dx.doi.org/10.1002/pssb.20145153
A three-component monooxygenase from Rhodococcus wratislaviensis may expand industrial applications of bacterial enzymes
地球外有機化合物に対する微生物代謝の解明から全く新規な酵素系を発見 --生命分子進化の理解や産業応用に期待--. 京都大学プレスリリース. 2021-01-20.The high-valent iron-oxo species formed in the non-heme diiron enzymes have high oxidative reactivity and catalyze difficult chemical reactions. Although the hydroxylation of inert methyl groups is an industrially promising reaction, utilizing non-heme diiron enzymes as such a biocatalyst has been difficult. Here we show a three-component monooxygenase system for the selective terminal hydroxylation of α-aminoisobutyric acid (Aib) into α-methyl-D-serine. It consists of the hydroxylase component, AibH1H2, and the electron transfer component. Aib hydroxylation is the initial step of Aib catabolism in Rhodococcus wratislaviensis C31-06, which has been fully elucidated through a proteome analysis. The crystal structure analysis revealed that AibH1H2 forms a heterotetramer of two amidohydrolase superfamily proteins, of which AibHm2 is a non-heme diiron protein and functions as a catalytic subunit. The Aib monooxygenase was demonstrated to be a promising biocatalyst that is suitable for bioprocesses in which the inert C–H bond in methyl groups need to be activated
The velocity field of 2MRS Ks=11.75 galaxies: constraints on beta and bulk flow from the luminosity function
Using the nearly full sky Ks=11.75 2MASS Redshift Survey [2MRS]of ~45,000
galaxies we reconstruct the underlying peculiar velocity field and constrain
the cosmological bulk flow within ~100. These results are obtained by
maximizing the probability to estimate the absolute magnitude of a galaxy given
its observed apparent magnitude and redshift. At a depth of ~60 Mpc/h we find a
bulk flow Vb=(90\pm65,-230\pm65,50\pm65) km/s in agreement with the theoretical
predictions of the LCDM model. The reconstructed peculiar velocity field that
maximizes the likelihood is characterized by the parameter beta=0.323 +/- 0.08.
Both results are in agreement with those obtained previously using the ~23,000
galaxies of the shallower Ks=11.25 2MRS survey. In our analysis we find that
the luminosity function of 2MRS galaxies is poorly fitted by the Schechter form
and that luminosity evolves such that objects become fainter with increasing
redshift according to L(z)=L(z=0)(1+z)^(+2.7 +/-0.15).Comment: 10 pages, 6 figure
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