The Effect of Dissolved Water on the Tribological Properties of Polyalkylene Glycol and Polyolester Oils

The effect of water dissolved in polyalkylene glycol and polyolester oils on the tribological behavior of two material contact pairs in three test environments is evaluated. The material contact pairs are M2 tool steel against 390 aluminum and M2 tool steel against gray cast iron. The three oils are a polyalkylene glycol (PAG) and two polyolester (PEl and PE2) oils. The test environments are R134a, air and argon. The tests are conducted in a specially designed high pressure tribometer which provides an accurate control of the test variables. The results indicate that the P AG oil performed better than the esters for both material contact pairs. The wear on the aluminum plates for the tests conducted with the P AG oil in all three environments is greatest at the lowest moisture content levels. From the stand point of friction and wear, it is beneficial to have a water content level of 5000 ppm or greater in the PAG oil when the plate material is 390 aluminum. The wear on the cast iron plates, when using a PAG oil as the lubricant showed a slight increase with water content in a R134a environment. This trend is opposite when air is the test environment. Both ester oils lubricated aluminum much better than the cast iron . The difference in the amount of wear can be as high as two orders of magnitude. This is probably due to the ability of the esters to form bidentate bonds with aluminum. Esters do not form such bonds with iron. The plate wear is greater for the PEl tests than for the PE2 tests for both material contact pairs. This is most likely due to the difference in the viscosity of the oils. In PE2 oil, water does not seem to affect the friction and wear of both aluminum/steel and cast iron/steel contacts when R134a is the test environment. On the contrary, for the aluminum/steel contacts, the water content significantly influences wear when argon or air is the test environment. For the cast iron/steel contacts, the wear is strongly influenced by the water content when the test is conducted in argon, but it is not influenced by the water content when the test is conducted in air.Air Conditioning and Refrigeration Center Project 0

Proofs for some conjectures of Rajaratnam and Takawira on the peakedness of handoff traffic

The purpose of this paper is to supplement a recent paper by M. Rajaratnam and F. Takawira (see ibid., vol.49, p.817-34, 2000), which deals with a model for the performance analysis of cellular mobile networks. The key performance measure is a second-order characteristic (peakedness) of the traffic stream that serves as a model for handoff traffic. We show that this quantity may be obtained by evaluating an explicit formula rather than by solving a set of equations. This result enables us to verify some conjectures formulated by Rajaratnam and Takawira on the basis of numerical experiments. We also show the uniqueness of the solution to a system of nonlinear equations, required in the performance analysis, as conjectured by Rajaratnam and Takawira

Litter dynamics and phenology of Melaleuca quinquenervia in south Florida

We monitored litterfall biomass at six different sites of melaleuca (Melaleuca quinquenervia (Cav.) S.T. Blake) forested wetlands in South Florida from July 1997 to June 1999. Annual litterfall of melaleuca varied between sites from 6.5 to 9.9 t dry wt ha(-1) yr(1) over the two-year period. Litterfall was significantly higher (p < 0.0001) in scasonally flooded habitats (9.3 t ha(-1) yr(1)) than in non-flooded (7.5 t ha(-1) yr(1)) and permanently flooded habitats (8.0 t ha(-1) yr(1)). Leaf fall was the major component forming 70% of the total litter, woody material 16%, and reproductive material 11%. Phenology of flowering and leaf flush was investigated by examination of the timing and duration of the fall of different plant parts in the litter traps, coupled with monthly field observations during the two-year study. In both years, flowering began in October and November, with peak flowers production around December, and was essentially completed by February and March. New shoot growth began in mid winter after peak flowering, and extended into the spring. Very little new growth was observed in melaleuca forests during the summer months, from May to August, in South Florida. In contrast, the fall of leaves and small wood was recorded in every month of the year, but generally increased during the dry season with higher levels observed from February to April. Also, no seasonality was recorded in the fall of seed capsules, which apparently resulted from the continual self-thinning of small branches and twigs inside the forest stand. In planning management for perennial weeds, it is important to determine the period during its annual growth cycle when the plant is most susceptible to control measures. These phenological data suggest that the appropriate time for melaleuca control in South Florida might be during late winter and early spring, when the plant is most active

Risk and ambiguity aversion behavior in index-based insurance uptake decisions:Experimental evidence from Ethiopia

Index-based insurance (IBI) is an innovative pro-poor climate risk management strategy that suffers from low uptake. Evidence on the role of behavioral impediments in adoption of IBI is scant. We conducted lab-in-the-field experiments with 1139 smallholders out of whom 596 have adopted IBI in Ethiopia to elicit their risk and ambiguity aversion behavior, and examine whether risk and/or ambiguity aversion can explain actual IBI uptake decisions. Our study suggests that an increase in risk-aversion increases uptake, but an increase in ambiguity-aversion lowers uptake of IBI. We also find evidence that an increase in risk aversion speeds-up the uptake of IBI, while an increase in ambiguity aversion delays the adoption of IBI

Narrative Companionship: Philosophy, Gender Stereotypes, and Young Adult Literature

Zuidervaart, L. [Promotor]Musschenga, A.W. [Promotor

Cooperative Catalysis for Selective Alcohol Oxidation with Molecular Oxygen

The activation of dioxygen for selective oxidation of organic molecules is a major catalytic challenge. Inspired by the activity of nitrogen-doped carbons in electrocatalytic oxygen reduction, we combined such a carbon with metal-oxide catalysts to yield cooperative catalysts. These simple materials boost the catalytic oxidation of several alcohols, using molecular oxygen at atmospheric pressure and low temperature (80 degrees C). Cobalt and copper oxide demonstrate the highest activities. The high activity and selectivity of these catalysts arises from the cooperative action of their components, as proven by various control experiments and spectroscopic techniques. We propose that the reaction should not be viewed as occurring at an active site', but rather at an active doughnut'-the volume surrounding the base of a carbon-supported metal-oxide particle

Maximum-entropy theory of steady-state quantum transport

We develop a theoretical framework for describing steady-state quantum transport phenomena, based on the general maximum-entropy principle of nonequilibrium statistical mechanics. The general form of the many-body density matrix is derived, which contains the invariant part of the current operator that guarantees the nonequilibrium and steady-state character of the ensemble. Several examples of the theory are given, demonstrating the relationship of the present treatment to the widely used scattering-state occupation schemes at the level of the self-consistent single-particle approximation. The latter schemes are shown not to maximize the entropy, except in certain limits