A new method for the determination of thin film porosity

Internal reflection spectroscopy may be used to determine presence of water in thin film pores. Presence of water in such pores is function of relative humidity and pore size. Thus, one can determine pore size by controlling humidity. Fluids with surface tension different from that of water can be used to detect pores

Dosimetry for radiobiological studies of the human hematopoietic system

A system for estimating individual bone marrow doses in therapeutic radiation exposures of leukemia patients was studied. These measurements are used to make dose response correlations and to study the effect of dose protraction on peripheral blood cell levels. Three irradiators designed to produce a uniform field of high energy gamma radiation for total body exposures of large animals and man are also used for radiobiological studies

Supranational Supervision - How Much and for Whom?

We argue that the extent to which supervision of banks takes place on the supranational level should be guided by two factors: cross-border externalities from bank failure and heterogeneity in bank failure costs. Based on a simple model we show that supranational supervision is more likely to be welfare enhancing when externalities are high and country heterogeneity is low. This suggests that different sets of countries (or regions) should differ in the extent to which their regulators cooperate across border. We apply the insights of our model to discuss optimal supervisory arrangements for different regions of the world and contrast them with existing arrangements and current policy initiatives. We also offer a political economy discussion on the likelihood with which countries delegate supervisory authority to supranational authorities

Stress corrosion cracking of titanium alloys: Studies of cracks in thin specimens; SCC of Ti-6Al-4V in chloride, iodide and fluoride solutions; stress corrosion cracking in molten salts; electrochemistry of freshly generated titanium surfaces

Electrochemistry of freshly generated titanium surfaces and stress corrosion cracking in aqueous solutions and in molten salt

Fundamental investigation of stress corrosion cracking

Two principle areas studied were stress corrosion crack growth rates of a titanium alloy in liquid environments containing halide ions and pitting corrosion of titanium in bromide solutions. Two initial assumptions were made, that the rate of propagation was controlled by a macroscopic solution parameter and that this parameter was viscosity. A series of solutions were prepared using lithium chloride as the solute and water, methanol, glycerin, formic acid, acetone, dimethyl sulphoxide, etc. As solvents, these solutions were prepared with a 5:1 solvent-solute ratio. Viscosity was varied by changing the temperature and it was found: (1) In all solvents the velocity of cracking was proportional to the reciprocal of the viscosity. (2) Each solvent gave a separate relationship, (3) The temperature dependence and numerical values for the apparent activation energy of cracking and viscosity were the same

Hydrazine monitoring in spacecraft

Hydrazine (HZ) and monomethyl hydrazine (MMH) are highly toxic compounds used as fuels in the Space Shuttle Orbiter Main Engines and in its maneuvering and reaction control system. Satellite refueling during a mission may also result in release of hydrazines. During extravehicular activities, the potential exists for hydrazines to contaminate the suit and to be brought into the internal atmosphere inadvertantly. Because of the high toxicity of hydrazines, a very sensitive, reliable, interference-free, and real-time method of measurement is required. A portable ion mobility spectrometer (IMS) has exhibited a low ppb detection limit for hydrazines suggesting a promising technology for the detection of hydrazines in spacecraft air. The Hydrazine Monitor is a modified airborne vapor monitor (AVM) with a custom-built datalogger. This off-the-shelf IMS was developed for the detection of chemical warfare agents on the battlefield. After early evaluations of the AVM for hydrazine measurements showed a serious interference from ammonia, the AVM was modified to measure HZ and MMH in the ppb concentration range without interference from ammonia in the low ppm range. A description of the Hydrazine Monitor and how it functions is presented

ALMA observations of the vibrationally-excited rotational CO transition v=1,J=3−2v=1, J=3-2 towards five AGB stars

We report the serendipitous detection with ALMA of the vibrationally-excited pure-rotational CO transition $v=1, J=3-2$ towards five asymptotic giant branch (AGB) stars, $o$ Cet, R Aqr, R Scl, W Aql, and $\pi^1$ Gru. The observed lines are formed in the poorly-understood region located between the stellar surface and the region where the wind starts, the so-called warm molecular layer. We successfully reproduce the observed lines profiles using a simple model. We constrain the extents, densities, and kinematics of the region where the lines are produced. R Aqr and R Scl show inverse P-Cygni line profiles which indicate infall of material onto the stars. The line profiles of $o$ Cet and R Scl show variability. The serendipitous detection towards these five sources shows that vibrationally-excited rotational lines can be observed towards a large number of nearby AGB stars using ALMA. This opens a new possibility for the study of the innermost regions of AGB circumstellar envelopes.Comment: 6 pages, 2 figures, 2 tables, 2016MNRAS.463L..74

CO and HCN isotopologue ratios in the outflows of AGB stars

Isotopologue line intensity ratios of circumstellar molecules have been widely used to trace the photospheric elemental isotopic ratios of evolved stars. However, depending on the molecular species and the physical conditions of the environment, the circumstellar isotopologue ratio may deviate considerably from the stellar atmospheric value. In this paper, we aim to examine how the CO and HCN abundance ratios vary radially due to chemical reactions in the outflows of AGB stars and the effect of excitation and optical depth on the resulting line intensity ratios. We find that the circumstellar 12CO/13CO can deviate from its atmospheric value by up to 25-94% and 6-60% for C- and O-type CSEs, respectively. We show that variations of the intensity of the ISRF and the gas kinetic temperature can significantly influence the CO isotopologue ratio in the outer CSEs. On the contrary, the H12CN/H13CN ratio is stable for all tested mass-loss rates. The RT modeling shows that the integrated line intensity ratio of CO of different rotational transitions varies significantly for stars with intermediate mass-loss rates due to combined chemical and excitation effects. In contrast, the excitation conditions for the both HCN isotopologues are the same. We demonstrate the importance of using the isotopologue abundance profiles from chemical models as inputs to RT models in the interpretation of isotopologue observations. Previous studies of CO isotopologue ratios are based on multi-transition data for individual sources and it is difficult to estimate the errors in the reported values due to assumptions that are not entirely correct according to this study. If anything, previous studies may have overestimated the circumstellar 12CO/13CO abundance ratio. The use of the HCN as a tracer of C isotope ratios is affected by fewer complicating problems, provided one accounts corrections for high optical depths.Comment: 14 pages, 11 figure

On, Wisconsin! : With Vocal Chorus

https://digitalcommons.library.umaine.edu/mmb-vp/5911/thumbnail.jp

Longitudinal response functions of 3H and 3He

Trinucleon longitudinal response functions R_L(q,omega) are calculated for q values up to 500 MeV/c. These are the first calculations beyond the threshold region in which both three-nucleon (3N) and Coulomb forces are fully included. We employ two realistic NN potentials (configuration space BonnA, AV18) and two 3N potentials (UrbanaIX, Tucson-Melbourne). Complete final state interactions are taken into account via the Lorentz integral transform technique. We study relativistic corrections arising from first order corrections to the nuclear charge operator. In addition the reference frame dependence due to our non-relativistic framework is investigated. For q less equal 350 MeV/c we find a 3N force effect between 5 and 15 %, while the dependence on other theoretical ingredients is small. At q greater equal 400 MeV/c relativistic corrections to the charge operator and effects of frame dependence, especially for large omega, become more important. In comparison with experimental data there is generally a rather good agreement. Exceptions are the responses at excitation energies close to threshold, where there exists a large discrepancy with experiment at higher q. Concerning the effect of 3N forces there are a few cases, in particular for the R_L of 3He, where one finds a much improved agreement with experiment if 3N forces are included.Comment: 26 pages, 9 figure