11,215 research outputs found
Composite Fermions in Quantum Dots
We demonstrate the formation of composite fermions in two-dimensional quantum
dots under high magnetic fields. The composite fermion interpretation provides
a simple way to understand several qualitative and quantitative features of the
numerical results obtained earlier in exact diagonalization studies. In
particular, the ground states are recognized as compactly filled quasi-Landau
levels of composite fermions.Comment: Revtex. Postscript files of figures are appended the tex
Stereoselective synthesis of hydroxyethylene dipeptide isostere from sugar
Regioselective opening of the aziridine ring in the carbohydrate-based precursor led to the stereoselective synthesis of N-Boc-O-benzyl-(4S,5S)-5-amino-4-hydroxy-6-phenylhexanoic acid methyl ester, the hydroxyethylene dipeptide isostere moiety of potent HIV-1 protease inhibitor
Facile oxidation of aldehydes to carboxylic acids with chromium(V) reagents
Recently we reported a convenient method of oxidation of alcohols to carbonyl compounds using chromium(V) reagents. Although a variety of reagents are available for effecting this transformation, there are only a few reagents which have been successfully used for the oxidation of aldehydes to carboxyllc adds. Chromic acid, silver oxide and potassium permanganate are commonly employed for this purpose and reactions are performed in protic media under conditions which are not that mild. The "non-aqueous" chromium(VI) reagent, pyridinium dichromate, recently reported by Corey oxidises alcohols and aldehydes to carboxylic acids in DMF at room temperature. Although Cr(V) species is postulated as an intermediate in all oxidations with Cr(VI), no systematic oxidation studies have been reported with these reagents. This note reports the results of some fruitful investigations on aldehyde → carboxylic acid conversion involving some "non-aqueous" chromium (V) complexes 1̲, 2̲, 3̲ and 5̲ under anhydrous conditions
Multi-Phase Manganese Mineralization in the Noamundi Synclinorium, East Indian Shield
Manganese mineralization associated with phyllites in and around Joda, Odisha belongs to the Iron Ore Group of Noamundi basin and is a part of Jamda-Koira belt of East Indian Shield. The present study area comprises low to medium grade tectonites containing economic resources of both iron and manganese. Present study is concentrated on Manganese mineralization. Field study and petro-mineralogical observations reveal syngenetic character of manganese ores comprising lowT higher oxides viz. pyrolusite, cryptomelane, manganite as major Mn-minerals along with highT lower oxides viz. jacobsite, bixbyite, braunite and hausmannite as minor Mn-minerals. The Mn-ore bodies and associated phyllites have undergone multiple phases of deformation and metamorphism followed by hydrothermal and supergene processes. Four deformational phases have been deciphered during field study. Geochemical analyses of ores and phyllitic host rocks show high values of Al2O3, TiO2, Ba, Co, Ni, Cr, Cu, Sc, V, As, Zn but depletion of Sr, Yb, Sm, Nb. Geochemical data infer ores to be a recycling product originally derived from a mafic crustal source of tholeiitic character. Age data obtained from Sm-Nd ratio of two rock samples are 3.46 Ga and 2.79 Ga. Present work provides a critical assessment on the multiphase mineralization of manganese ores
Theory of the Half-Polarized Quantum Hall States
We report a theoretical analysis of the half-polarized quantum Hall states
observed in a recent experiment. Our numerical results indicate that the ground
state energy of the quantum Hall and states versus spin
polarization has a downward cusp at half the maximal spin polarization. We map
the two-component fermion system onto a system of excitons and describe the
ground state as a liquid state of excitons with non-zero values of exciton
angular momentum.Comment: 4 pages (RevTeX), 3 figures (PostScript), added reference
Dynamic nuclear polarization induced by breakdown of fractional quantum Hall effect
We study dynamic nuclear polarization (DNP) induced by breakdown of the
fractional quantum Hall (FQH) effect. We find that voltage-current
characteristics depend on current sweep rates at the quantum Hall states of
Landau level filling factors = 1, 2/3, and 1/3. The sweep rate dependence
is attributed to DNP occurring in the breakdown regime of FQH states. Results
of a pump and probe experiment show that the polarities of the DNP induced in
the breakdown regimes of the FQH states is opposite to that of the DNP induced
in the breakdown regimes of odd-integer quantum Hall states.Comment: 4 pages, 4 figure
Density Functional Theory of Multicomponent Quantum Dots
Quantum dots with conduction electrons or holes originating from several
bands are considered. We assume the particles are confined in a harmonic
potential and assume the electrons (or holes) belonging to different bands to
be different types of fermions with isotropic effective masses. The density
functional method with the local density approximation is used. The increased
number of internal (Kohn-Sham) states leads to a generalisation of Hund's first
rule at high densities. At low densitites the formation of Wigner molecules is
favored by the increased internal freedom.Comment: 11 pages, 5 figure
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