Modeling the Spatially Varying Water Balance Processes in a Semi- Arid Mountainous Watershed of Idaho

Mountainous watersheds in semi-arid regions are complex hydrologic systems. To critically evaluate the hydrological processes, high resolution spatio-temporal information is necessary. Also, calibrating and validating a watershed-scale model is necessary to enable our understanding of the water balance components in the gauged watersheds. The distributed Soil Water Assessment Tool (SWAT) hydrologic model was applied to a research watershed, the Dry Creek Experimental Watershed (DCEW), near Boise Idaho to investigate its water balance components both temporally and spatially. Daily streamflow data from four streamflow gauges were used for calibration and validation of the model. Monthly estimates of streamflow during the calibration phase by SWAT produced satisfactory results with a Nash Sutcliffe coefficient of model efficiency 0.79. Since it is a continuous simulation model, as opposed to an event-based model, it demonstrated the limited ability in capturing both streamflow and soil moisture for selected rain-on-snow events during the validation period between 2005-07. Our implementation of SWAT showed that seasonal and annual water balance partitioning of precipitation into evapotranspiration, streamflow, soil moisture and drainage was not only possible but closely followed the trends of a typical semiarid watershed in the intermountain west. This study highlights the necessity for better techniques to precisely identify and drive the model with commonly observed climatic inversion-related snowmelt or rain-on-snow weather events. Estimation of key parameters pertaining to soil (e.g., available water content and saturated hydraulic conductivity), snow (e.g., lapse rates, melting) and vegetation (e.g., leaf area index and maximum canopy index) using additional field observations in the watershed is critical for better prediction

Bodily tides near spin-orbit resonances

Spin-orbit coupling can be described in two approaches. The method known as "the MacDonald torque" is often combined with an assumption that the quality factor Q is frequency-independent. This makes the method inconsistent, because the MacDonald theory tacitly fixes the rheology by making Q scale as the inverse tidal frequency. Spin-orbit coupling can be treated also in an approach called "the Darwin torque". While this theory is general enough to accommodate an arbitrary frequency-dependence of Q, this advantage has not yet been exploited in the literature, where Q is assumed constant or is set to scale as inverse tidal frequency, the latter assertion making the Darwin torque equivalent to a corrected version of the MacDonald torque. However neither a constant nor an inverse-frequency Q reflect the properties of realistic mantles and crusts, because the actual frequency-dependence is more complex. Hence the necessity to enrich the theory of spin-orbit interaction with the right frequency-dependence. We accomplish this programme for the Darwin-torque-based model near resonances. We derive the frequency-dependence of the tidal torque from the first principles, i.e., from the expression for the mantle's compliance in the time domain. We also explain that the tidal torque includes not only the secular part, but also an oscillating part. We demonstrate that the lmpq term of the Darwin-Kaula expansion for the tidal torque smoothly goes through zero, when the secondary traverses the lmpq resonance (e.g., the principal tidal torque smoothly goes through nil as the secondary crosses the synchronous orbit). We also offer a possible explanation for the unexpected frequency-dependence of the tidal dissipation rate in the Moon, discovered by LLR

Special phase transformation and crystal growth pathways observed in nanoparticles†

Phase transformation and crystal growth in nanoparticles may happen via mechanisms distinct from those in bulk materials. We combine experimental studies of as-synthesized and hydrothermally coarsened titania (TiO(2)) and zinc sulfide (ZnS) with thermodynamic analysis, kinetic modeling and molecular dynamics (MD) simulations. The samples were characterized by transmission electron microscopy, X-ray diffraction, synchrotron X-ray absorption and scattering, and UV-vis spectroscopy. At low temperatures, phase transformation in titania nanoparticles occurs predominantly via interface nucleation at particle–particle contacts. Coarsening and crystal growth of titania nanoparticles can be described using the Smoluchowski equation. Oriented attachment-based crystal growth was common in both hydrothermal solutions and under dry conditions. MD simulations predict large structural perturbations within very fine particles, and are consistent with experimental results showing that ligand binding and change in aggregation state can cause phase transformation without particle coarsening. Such phenomena affect surface reactivity, thus may have important roles in geochemical cycling

Small Soil Storage Capacity Limits Benefit of Winter Snowpack to Upland Vegetation

In the western United States, the mountain snowpack is an important natural reservoir that extends spring and summer water delivery to downstream users and ecosystems. The importance of winter snow accumulation to upland ecosystems is not as clearly defined. This study investigates the relative contribution of winter precipitation to upland spring and summer soil moisture storage and availability in a semi-arid mountainous watershed. At this site, coarse soil textures and shallow soil depths limit soil storage capacity to 6–16 cm. Winter precipitation exceeds soil storage capacity by 2.5 times. Accordingly, soil moisture profiles at most locations in the watershed reach field capacity in early winter. With soil storage near capacity, water released by snowmelt primarily contributes to deep drainage and makes a limited contribution to the soil moisture reservoir. Water that is retained by the soil after the snowpack melts is lost to evapotranspiration in as little as 10 days. In contrast, spring precipitation extends moist soil conditions by up to 90 days into the warm season, when ecological water demand is highest. These field observations suggest that changes in spring precipitation, not winter snowpack, may have the greater impact on upland ecosystems in this environment. Furthermore, because winter precipitation is in excess compared to the soil storage capacity, soil moisture availability may be fairly insensitive to climate change-induced transitions from snow to rain