16 research outputs found

    Charge Ordering in Organic ET Compounds

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    The charge ordering phenomena in quasi two-dimensional 1/4-filled organic compounds (ET)_2X (ET=BEDT-TTF) are investigated theoretically for the θ\theta and α\alpha-type structures, based on the Hartree approximation for the extended Hubbard models with both on-site and intersite Coulomb interactions. It is found that charge ordered states of stripe-type are stabilized for the relevant values of Coulomb energies, while the spatial pattern of the stripes sensitively depends on the anisotropy of the models. By comparing the results of calculations with the experimental facts, where the effects of quantum fluctuation is incorporated by mapping the stripe-type charge ordered states to the S=1/2 Heisenberg Hamiltonians, the actual charge patterns in the insulating phases of θ\theta-(ET)_2MM'(SCN)_4 and α\alpha-(ET)_2I_3 are deduced. Furthermore, to obtain a unified view among the θ\theta, α\alpha and κ\kappa-(ET)_2X families, the stability of the charge ordered state in competition with the dimeric antiferromagnetic state viewed as the Mott insulating state, which is typically realized in κ\kappa-type compounds, and with the paramagnetic metallic state, is also pursued by extracting essential parameters.Comment: 35 pages, 27 figures, submitted to J. Phys. Soc. Jp

    A Novel Vision for Navigation and Enrichment in Cultural Heritage Collections

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    International audienceIn the cultural heritage domain, there is a huge interest in utilizing semantic web technology and build services enabling users to query, explore and access the vast body of cultural heritage information that has been created over decades by memory institutions. For successful conversion of existing data into semantic web data, however, there is often a need to enhance and enrich the legacy data to validate and align it with other resources and reveal its full potential. In this visionary paper, we describe a framework for semantic enrichment that relies on the creation of thematic knowledge bases, i.e., about a given topic. These knowledge bases aggregate information by exploiting structured resources (e.g., Linked Open Data cloud) and by extracting new relationships from streams (e.g., Twitter) and textual documents (e.g., web pages). Our focused application in this paper is how this approach can be utilized when transforming library records into semantic web data based on the FRBR model in the process that commonly is called FRBRization

    A Survey of FRBRization Techniques

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    International audienceThe Functional Requirements for Bibliographic Records (FRBR), an emerging model in the bibliographic domain, provide interesting possibilities in terms of cataloguing, representation and semantic enrichment of bibliographic data. However, the automated transformation of existing catalogs to fit this model is a requirement towards a wide adoption of FRBR in libraries. The cultural heritage community proposed a notable amount of FRBRization tools and projects, thus making it difficult for practitioners to compare and evaluate them. In this paper, we propose a synthetic and relevant classification of the FRBRization techniques according to specific criteria of comparison such as model expressiveness or specific enhancements
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