Catalytic Reductive Degradation of Methyl Orange Using Air Resilient Copper Nanostructures

The study describes the application of oxidation resistant copper nanostructures as an efficient heterogeneous catalyst for the treatment of organic dye containing waste waters. Copper nanostructures were synthesized in an aqueous environment using modified surfactant assisted chemical reduction route. The synthesized nanostructures have been characterized by UV-Vis, Fourier transform infrared spectroscopy FTIR spectroscopy, Atomic force microscopy (AFM), Scanning Electron Microscopy (SEM), and X-ray diffractometry (XRD). These surfactant capped Cu nanostructures have been used as a heterogeneous catalyst for the comparative reductive degradation of methyl orange (MO) in the presence of sodium borohydride (NaBH4) used as a potential reductant. Copper nanoparticles (Cu NPs) were found to be more efficient compared to copper nanorods (Cu NRds) with the degradation reaction obeying pseudofirst order reaction kinetics. Shape dependent catalytic efficiency was further evaluated from activation energy (EA) of reductive degradation reaction. The more efficient Cu NPs were further employed for reductive degradation of real waste water samples containing dyes collected from the drain of different local textile industries situated in Hyderabad region, Pakistan

Optimization of Processing Parameters to Achieve Superior Quality and Maximum Recovery of Canola Oil

Aim of the present study was to improve the efficiency of processing to achieve a superior quality of canola oil with better recovery. Three sets of canola oil containing crude, neutralized, bleached, deodorized oils and deodorizer distillates (DD) were collected from edible oil processing industries. Important physicochemical properties of the oil were evaluated in all three sets including unsaponifiable matter, phosphorus content and soap content. The industrial processing of set I and II was found to be satisfactory as compared to set III. Therefore, set III was selected for the optimization of different processing parameters during each stage of processing. For neutralization, bleaching and deodorization different parameters were optimized to achieve a better quality of the finished product, good recovery and control of the processing cost. After optimization, physicochemical characteristics of neutralized, bleached, deodorized oil and its DD were evaluated. Also, the loss and recovery of neutral oil were calculated in each processing stage. The results of the present study showed that a slight variation of processing parameters leads to a great impact on the quality and recovery of the canola oil. High contents of free fatty acids (FFA) in DD indicated that it could be used as a potential source of biodiesel production

A chemometric approach to assess the frying stability of cottonseed oil blends during deep-frying process: fatty acid composition and tocopherol analyses

WOS:000359160500015The aim of the present study was to determine impacts of different additives on fatty acid composition and total tocopherol content of cottonseed oil during deep-frying process using a chemometric approach. A quarter-fractional factorial design with two levels and five factors was used for preparing the frying cottonseed oil blends. In the experimental design, additives were such as ascorbic palmitate, mixed tocopherols, dimethylpolysiloxane, lecithin, and sesame oil were used as factors. The effect of additives on fatty acid composition and tocopherol content were evaluated with normal distribution (ND) graphs during ten hours frying at 170 +/- 5 degrees C. The data were statistically assessed by one-way analysis of variance at a significance level of p < 0.05. The analysis of variance test results were in good agreement with ND graphs and data indicated that the interaction between ascorbic palmitate and dimethylpolysiloxane (A x C factor) showed a significant and protective effect on fatty acids. Meanwhile, the sesame oil (E factor) and A x C factor were showed a significant effect on level of tocopherols. The results of study indicated that present approach could be used to assess and improve the frying stability of any oil with respect to fatty acid composition and tocopherols.Republic of Turkey Industry and Trade Ministry of Research and Development CentreMinistry of Science, Industry & Technology - Turkey; San-Tez ProjectsMinistry of Science, Industry & Technology - Turkey [150.STZ.2007-2]; Selcuk University Coordinators of Scientific ResearchSelcuk University [SU-08201044, SU-08401007]The present study is a part of master thesis entitled Increasing Usage Efficiencies of Cottonseed Oils Produced in Our Country by Improving Their Refinery Process was supported by Republic of Turkey Industry and Trade Ministry of Research and Development Centre with San-Tez Projects-150.STZ.2007-2 project number and Selcuk University Coordinators of Scientific Research with SU-08201044 and SU-08401007 project numbers

Synthesis and evaluation of oxidation stability of biodiesel prepared from spent bleaching clay residual oil

© 2020, Japan Oil Chemists Society. All rights reserved.Energy plays a key role in each sector of life ranging from basic needs to better standards of life. The world is concerned about 3 ps (population, poverty, and pollution). The increase of these three factors has led the search of the best alternative sources of energies to fulfill all needs of a modern way of life. Biodiesel is a sustainable energy source that has proved to be the best alternate of mineral diesel that possesses similar properties as found in mineral diesel. The recent trend in biodiesel research is towards the use of very cheap feedstock to make this substitute more economical. Following this similar trend, the attempt is made to produce biodiesel from less expensive feedstock namely; residual oil of spent bleaching clay (SBC). In the first step, the quantity of the residual oil that can be recovered followed by assessing its quality was investigated. Afterward, a two-step method of the transesterification process was employed to enhance the yield of methyl ester. The highest yield of 85% was obtained. Key fuel properties were measured and found in good agreement with ASTMD 6751 standards limits. The study also concerned with the practical availability of biodiesel in terms of its stability. For this purpose, produced biodiesel was evaluated for its oxidation stability during 90 days of storage by FT-IR and rancimat methods

A review: Health benefits and physicochemical characteristics of blended vegetable oils

Abstract:: Oil blending is the method of choice used worldwide to improve oxidative stability and nutritional value. There is no such edible oil/fat that meets all the recommendations from the health point of view. The fatty acid composition of vegetable oils decides the fate of the oil. Pure single oil is unable to provide a balanced amount of fatty acids (FAs) required/recommended on a daily intake basis. Blending oils/fats is an appropriate procedure of physically mixing multiple oils in suitable proportions which may provide functional lipids with improved antioxidant potential and desirable physical and chemical properties. This review piled up the accessible data on the blending of diverse oils/fats in the combination of binary, ternary, quaternary, or other types of oils into a single blended oil. Blending can be found very convincing towards appropriate FA profile, enhancement in physicochemical characteristics, and augmented stability for the period of storage or when used as cooking/frying processes which could ultimately serve as an effectual dietary intervention towards the health protectiveness

Synthesis of biodiesel via pre-blending of feedstocks: an optimization by the polynomial curve fitting method

Use of abundant indigenous energy crops for biofuel production contributes to enhance the economy and reduce the dependence on fossil fuels. This article aims to shed light on two energy crops available in Pakistan; castor (Ricinus communis L.) and cottonseed (Gossypium hirsutum L.). Although castor has excellent oil content (54%), its high viscosity is not acceptable. Therefore, pre-blending with cottonseed oil was proposed. Physical and chemical properties of crude oils, pure biodiesels and binary blends besides fatty acid composition and degree of unsaturation were analyzed. Biodiesels were checked for quality parameters within limits of American Society for Testing Materials (ASTM) and European Standards. Improvement in kinematic viscosity and density of castor biodiesel were noticed following this concept. Moreover, the developed empirical formula indicated that an optimized blending ratio of 93.86% cottonseed oil and 6.14% castor oil accomplished biodiesel yield of 91.12%, kinematic viscosity of 6 mm(2)/s and cetane number of 48.79, respectively, which all satisfy ASTM D6751. This technique also indicated that pre-blending can raise the ester content of castor biodiesel. In conclusion, it is recommended to adopt the concept of pre-blending to improve the quality of biodiesel and thus the engine and emission performance in compression ignition engines