Tethered balloon measurements of biogenic volatile organic compounds at a Boreal forest site

Measurements of biogenic volatile organic compounds (VOCs) were performed at Hyytiälä, a Boreal forest site in Southern Finland as part of the OSOA (origin and formation of secondary organic aerosol) project in August 2001. At this site, frequent formation of new particles has been observed and the role of biogenic VOCs in this process is still unclear. Tethered balloons served as platforms to collect VOC samples within the planetary boundary layer at heights up to 1.2 km above ground during daytime. Mean mixed layer concentrations of total monoterpenes varied between 10 and 170 pptv, with <font face='Symbol'>a</font>-pinene, limonene and <font face='Symbol'>D</font>³-carene as major compounds, isoprene was detected at levels of 2-35 pptv. A mixed layer gradient technique and a budget approach are applied to derive surface fluxes representative for areas of tens to hundreds of square kilometres. Effects of spatial heterogeneity in surface emissions are examined with a footprint analysis. Depending on the source area considered, mean afternoon emissions of the sum of terpenes range between 180 and 300 <font face='Symbol'>m</font>g m^-2 h^-1 for the period of 2-12 August 2001. Surface fluxes close to Hyytiälä were higher than the regional average, and agree well with mean emissions predicted by a biogenic VOC emission model. Total rates of monoterpene oxidation were calculated with a photochemical model. The rates did not correlate with the occurrence of new particle formation, but the ozone pathway was of more importance on days with particle formation. Condensable vapour production from the oxidation of monoterpenes throughout the mixed layer can only account for a fraction of the increase in aerosol mass observed at the surface

Engineered hexavalent Fc proteins with enhanced Fc-gamma receptor avidity provide insights into immune-complex interactions

Tania Rowley et al. present multivalent Fc molecules with enhanced avidity for Fc gamma receptors in order to improve the treatment of autoantibody-mediated human diseases. They found several key amino acids involved in Fc receptor binding interactions

Observations of Diurnal to Weekly Variations of Monoterpene-Dominated Fluxes of Volatile Organic Compounds from Mediterranean Forests: Implications for Regional Modeling

The Estate of Castelporziano (Rome, Italy) hosts many ecosystems representative of Mediterranean vegetation, especially holm oak and pine forests and dune vegetation. In this work, basal emission factors (BEFs) of biogenic volatile organic compounds (BVOCs) obtained by Eddy Covariance in a field campaign using a proton transfer reaction-time-of-flight-mass spectrometer (PTR-TOF-MS) were compared to BEFs reported in previous studies that could not measure fluxes in real-time. Globally, broadleaf forests are dominated by isoprene emissions, but these Mediterranean ecosystems are dominated by strong monoterpene emitters, as shown by the new BEFs. The original and new BEFs were used to parametrize the model of emissions of gases and aerosols from nature (MEGAN v2.1), and model outputs were compared with measured fluxes. Results showed good agreement between modeled and measured fluxes when a model was used to predict radiative transfer and energy balance across the canopy. We then evaluated whether changes in BVOC emissions can affect the chemistry of the atmosphere and climate at a regional level. MEGAN was run together with the land surface model (community land model, CLM v4.0) of the community earth system model (CESM v1.0). Results highlighted that tropospheric ozone concentration and air temperature predicted from the model are sensitive to the magnitude of BVOC emissions, thus demonstrating the importance of adopting the proper BEF values for model parametrization

The Namib Turbulence Experiment: Investigating surface-atmosphere heat transfer in three dimensions

The Namib Turbulence EXperiment (NamTEX) was a multi-national micrometeorological campaign conducted in the Central Namib Desert to investigate three-dimensional surface layer turbulence and the spatio-temporal patterns of heat transfer between the sub-surface, surface, and atmosphere. The Namib provides an ideal location for fundamental research that revisits some key assumptions in micrometeorology that are implicitly included in the parameterizations describing energy exchange in weather forecasting and climate models: Homogenous flat surfaces, no vegetation, little moisture, and cloud-free skies create a strong and consistent diurnal forcing, resulting in a wide range of atmospheric stabilities. A novel combination of instruments was used to simultaneously measure variables and processes relevant to heat transfer: A three km fibre-optic distributed temperature sensor (DTS) was suspended in a pseudo-three-dimensional array within a 300 m x 300 m domain to provide vertical cross-sections of air temperature fluctuations. Aerial and ground-based thermal imagers recorded high resolution surface temperature fluctuations within the domain and revealed the spatial thermal imprint of atmospheric structures responsible for heat exchange. High-resolution soil temperature and moisture profiles together with heat flux plates provided information on near-surface soil dynamics. Turbulent heat exchange was measured with a vertical array of five eddy-covariance point measurements on a 21-m mast, as well as by co-located small- and large-aperture scintillometers. This contribution first details the scientific goals and experimental set-up of the NamTEX campaign. Then using a typical day, we demonstrate i) the coupling of surface layer, surface, and soil temperatures using high-frequency temperature measurements, ii) differences in spatial and temporal standard deviations of the horizontal temperature field using spatially distributed measurements, and iii) horizontal anisotropy of the turbulent temperature field