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Overcoming restrictive technologies in police call centres: A human agency perspective
Call centres in the police force are restrictive information systems which tend to present call
operators with constraints that they need to overcome using their experience in order to offer
better services to the public. This paper is looking at how elements of human agency come in
to play and help users’ enactment against restrictive technologies. Information systems
research on human agency has been mainly focused on the examination of whether agency
lies within human or machines or both while in this paper we take a different approach and
we clearly describe how human agency is enacted in practice. We use empirical data from
contact centres and operational rooms of five UK police forces. After extensive observations
we present how police call handlers manipulate digital information efficiently through human
agency. The theoretical framework is based on the three elements of agency theory (iteration,
projectivity and practical evaluation) The research findings assert that call handlers
overcome the restrictions of the system by forming human-digital networks and using mental
structures from their past experience in order to cope with the task at hand. The paper
concludes by drawing implications for theory and practice and suggests future research
directions
Exploring the phase diagram of the two-impurity Kondo problem
A system of two exchange-coupled Kondo impurities in a magnetic field gives
rise to a rich phase space hosting a multitude of correlated phenomena.
Magnetic atoms on surfaces probed through scanning tunnelling microscopy
provide an excellent platform to investigate coupled impurities, but typical
high Kondo temperatures prevent field-dependent studies from being performed,
rendering large parts of the phase space inaccessible. We present an integral
study of pairs of Co atoms on insulating Cu2N/Cu(100), which each have a Kondo
temperature of only 2.6 K. In order to cover the different regions of the phase
space, the pairs are designed to have interaction strengths similar to the
Kondo temperature. By applying a sufficiently strong magnetic field, we are
able to access a new phase in which the two coupled impurities are
simultaneously screened. Comparison of differential conductance spectra taken
on the atoms to simulated curves, calculated using a third order transport
model, allows us to independently determine the degree of Kondo screening in
each phase.Comment: paper: 14 pages, 4 figures; supplementary: 3 pages, 1 figure, 1 tabl
Agnostic cosmology in the CAMEL framework
Cosmological parameter estimation is traditionally performed in the Bayesian
context. By adopting an "agnostic" statistical point of view, we show the
interest of confronting the Bayesian results to a frequentist approach based on
profile-likelihoods. To this purpose, we have developed the Cosmological
Analysis with a Minuit Exploration of the Likelihood ("CAMEL") software.
Written from scratch in pure C++, emphasis was put in building a clean and
carefully-designed project where new data and/or cosmological computations can
be easily included.
CAMEL incorporates the latest cosmological likelihoods and gives access from
the very same input file to several estimation methods: (i) A high quality
Maximum Likelihood Estimate (a.k.a "best fit") using MINUIT ; (ii) profile
likelihoods, (iii) a new implementation of an Adaptive Metropolis MCMC
algorithm that relieves the burden of reconstructing the proposal distribution.
We present here those various statistical techniques and roll out a full
use-case that can then used as a tutorial. We revisit the CDM
parameters determination with the latest Planck data and give results with both
methodologies. Furthermore, by comparing the Bayesian and frequentist
approaches, we discuss a "likelihood volume effect" that affects the optical
reionization depth when analyzing the high multipoles part of the Planck data.
The software, used in several Planck data analyzes, is available from
http://camel.in2p3.fr. Using it does not require advanced C++ skills.Comment: Typeset in Authorea. Online version available at:
https://www.authorea.com/users/90225/articles/104431/_show_articl
Relieving tensions related to the lensing of CMB temperature power spectra
The angular power spectra of the cosmic microwave background (CMB)
temperature anisotropies reconstructed from Planck data seem to present too
much gravitational lensing distortion. This is quantified by the control
parameter that should be compatible with unity for a standard cosmology.
With the Class Boltzmann solver and the profile-likelihood method, for this
parameter we measure a 2.6 shift from 1 using the Planck public
likelihoods. We show that, owing to strong correlations with the reionization
optical depth and the primordial perturbation amplitude , a
tension on also appears between the results obtained with
the low () and high () multipoles
likelihoods. With Hillipop, another high- likelihood built from Planck
data, this difference is lowered to . In this case, the value
is still in disagreement with unity by , suggesting a non-trivial
effect of the correlations between cosmological and nuisance parameters. To
better constrain the nuisance foregrounds parameters, we include the very high
measurements of the Atacama Cosmology Telescope (ACT) and South Pole
Telescope (SPT) experiments and obtain . The
Hillipop+ACT+SPT likelihood estimate of the optical depth is
which is now fully compatible with the low
likelihood determination. After showing the robustness of our results with
various combinations, we investigate the reasons for this improvement that
results from a better determination of the whole set of foregrounds parameters.
We finally provide estimates of the CDM parameters with our combined
CMB data likelihood.Comment: accepted by A&
Controlled complete suppression of single-atom inelastic spin and orbital cotunnelling
The inelastic portion of the tunnel current through an individual magnetic
atom grants unique access to read out and change the atom's spin state, but it
also provides a path for spontaneous relaxation and decoherence. Controlled
closure of the inelastic channel would allow for the latter to be switched off
at will, paving the way to coherent spin manipulation in single atoms. Here we
demonstrate complete closure of the inelastic channels for both spin and
orbital transitions due to a controlled geometric modification of the atom's
environment, using scanning tunnelling microscopy (STM). The observed
suppression of the excitation signal, which occurs for Co atoms assembled into
chain on a CuN substrate, indicates a structural transition affecting the
d orbital, effectively cutting off the STM tip from the spin-flip
cotunnelling path.Comment: 4 figures plus 4 supplementary figure
Nanotechnological approaches to address photosensitizers' limitations: towards improved clinical applicability of photodynamic therapy
Photodynamic therapy (PDT) uses a combination of molecular oxygen, light and a photosensitizer (PS) to generate singlet oxygen or reactive oxygen species (ROS), which can eradicate tumoral cells. All currently approved PSs for cancer treatment are molecular PSs. To date, no nanoparticlebased PSs are used clinically although it has widely been shown that nanotechnology may help to improve the properties of molecular PSs; for instance, molecular PSs suffer from some intrinsic limitations that undermine their therapeutic efficacy. In the present minireview, the most critical weaknesses exhibited by molecular PSs are described, and the potential use of nanoparticles (NPs) to address them and to reach the clinics is discussed
Optimization of graphene-based materials outperforming host epoxy matrices
The degree of graphite exfoliation and edge-carboxylated layers can be controlled and balanced to design lightweight materials characterized by both low electrical percolation thresholds (EPT) and improved mechanical properties. So far, this challenging task has been undoubtedly very hard to achieve. The results presented in this paper highlight the effect of exfoliation degree and the role of edge-carboxylated graphite layers to give self-assembled structures embedded in the polymeric matrix. Graphene layers inside the matrix may serve as building blocks of complex systems that could outperform the host matrix. Improvements in electrical percolation and mechanical performance have been obtained by a synergic effect due to finely balancing the degree of exfoliation and the chemistry of graphene edges which favors the interfacial interaction between polymer and carbon layers. In particular, for epoxy-based resins including two partially exfoliated graphite samples, differing essentially in the content of carboxylated groups, the percolation threshold reduces from 3 wt% down to 0.3 wt%, as the carboxylated group content increases up to 10 wt%. Edge-carboxylated nanosheets also increase the nanofiller/epoxy matrix interaction, determining a relevant reinforcement in the elastic modulus
Semiconductor resonator solitons above band gap
We show experimentally the existence of bright and dark spatial solitons in
semiconductor resonators for excitation above the band gap energy. These
solitons can be switched on, both spontaneously and with address pulses,
without the thermal delay found for solitons below the band gap which is
unfavorable for applications. The differences between soliton properties above
and below gap energy are discussed.Comment: 4 pages, 7 figure
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