Long range polarization attraction between two different likely charged macroions

It is known that in a water solution with multivalent counterions (Z-ions), two likely charged macroions can attract each other due to correlations of Z-ions adsorbed on their surfaces. This "correlation" attraction is short-ranged and decays exponentially with increasing distance between macroions at characteristic distance A/2\pi, where A is the average distance between Z-ions on the surfaces of macroions. In this work, we show that an additional long range "polarization" attraction exists when the bare surface charge densities of the two macroions have the same sign, but are different in absolute values. The key idea is that with adsorbed Z-ions, two insulating macroions can be considered as conductors with fixed but different electric potentials. Each potential is determined by the difference between the entropic bulk chemical potential of a Z-ion and its correlation chemical potential at the surface of the macroion determined by its bare surface charge density. When the two macroions are close enough, they get polarized in such a way that their adjacent spots form a charged capacitor, which leads to attraction. In a salt free solution this polarization attractive force is long ranged: it decays as a power of the distance between the surfaces of two macroions, d. The polarization force decays slower than the van der Waals attraction and therefore is much larger than it in a large range of distances. In the presence of large amount of monovalent salt, when A/2\pi<< d<< r_s (r_s is the Debye-H\"{u}ckel screening radius), this force is still much stronger than the van der Waals attraction and the correlation attraction mentioned above.Comment: 12 pages, 7 figures. Small change in the text, no change in result

Tabulation, bibliography, and structure of binary intermetallic compounds. I. Compounds of lithium, sodium, potassiu, and rubidium.

The compilation of the material in this report was undertaken to provide a convenient reference source for intermetallic compounds. An adequate bibliography is required for most efficient use. It is in this sense and because of the addition of more compounds that the compilation is considered an extension of the compilation in Smithell\u27s Metals Reference Book

Electronic states and optical properties of PbSe nanorods and nanowires

A theory of the electronic structure and excitonic absorption spectra of PbS and PbSe nanowires and nanorods in the framework of a four-band effective mass model is presented. Calculations conducted for PbSe show that dielectric contrast dramatically strengthens the exciton binding in narrow nanowires and nanorods. However, the self-interaction energies of the electron and hole nearly cancel the Coulomb binding, and as a result the optical absorption spectra are practically unaffected by the strong dielectric contrast between PbSe and the surrounding medium. Measurements of the size-dependent absorption spectra of colloidal PbSe nanorods are also presented. Using room-temperature energy-band parameters extracted from the optical spectra of spherical PbSe nanocrystals, the theory provides good quantitative agreement with the measured spectra.Comment: 35 pages, 12 figure

Transition from small to large world in growing networks

We examine the global organization of growing networks in which a new vertex is attached to already existing ones with a probability depending on their age. We find that the network is infinite- or finite-dimensional depending on whether the attachment probability decays slower or faster than $(age)^{-1}$. The network becomes one-dimensional when the attachment probability decays faster than $(age)^{-2}$. We describe structural characteristics of these phases and transitions between them.Comment: 5 page

Control of the Casimir force by the modification of dielectric properties with light

The experimental demonstration of the modification of the Casimir force between a gold coated sphere and a single-crystal Si membrane by light pulses is performed. The specially designed and fabricated Si membrane was irradiated with 514 nm laser pulses of 5 ms width in high vacuum leading to a change of the charge-carrier density. The difference in the Casimir force in the presence and in the absence of laser radiation was measured by means of an atomic force microscope as a function of separation at different powers of the absorbed light. The total experimental error of the measured force differences at a separation of 100 nm varies from 10 to 20% in different measurements. The experimental results are compared with theoretical computations using the Lifshitz theory at both zero and laboratory temperatures. The total theoretical error determined mostly by the uncertainty in the concentration of charge carriers when the light is incident is found to be about 14% at separations less than 140 nm. The experimental data are consistent with the Lifshitz theory at laboratory temperature, if the static dielectric permittivity of high-resistivity Si in the absence of light is assumed to be finite. If the dc conductivity of high-resistivity Si in the absence of light is included into the model of dielectric response, the Lifshitz theory at nonzero temperature is shown to be experimentally inconsistent at 95% confidence. The demonstrated phenomenon of the modification of the Casimir force through a change of the charge-carrier density is topical for applications of the Lifshitz theory to real materials in fields ranging from nanotechnology and condensed matter physics to the theory of fundamental interactions.Comment: 30 pages, 10 figures, 2 table

Addition-Deletion Networks

We study structural properties of growing networks where both addition and deletion of nodes are possible. Our model network evolves via two independent processes. With rate r, a node is added to the system and this node links to a randomly selected existing node. With rate 1, a randomly selected node is deleted, and its parent node inherits the links of its immediate descendants. We show that the in-component size distribution decays algebraically, c_k ~ k^{-beta}, as k-->infty. The exponent beta=2+1/(r-1) varies continuously with the addition rate r. Structural properties of the network including the height distribution, the diameter of the network, the average distance between two nodes, and the fraction of dangling nodes are also obtained analytically. Interestingly, the deletion process leads to a giant hub, a single node with a macroscopic degree whereas all other nodes have a microscopic degree.Comment: 8 pages, 5 figure

Electrostatics of Edge States of Quantum Hall Systems with Constrictions: Metal--Insulator Transition Tuned by External Gates

The nature of a metal--insulator transition tuned by external gates in quantum Hall (QH) systems with point constrictions at integer bulk filling, as reported in recent experiments of Roddaro et al. [1], is addressed. We are particularly concerned here with the insulating behavior--the phenomena of backscattering enhancement induced at high gate voltages. Electrostatics calculations for QH systems with split gates performed here show that observations are not a consequence of interedge interactions near the point contact. We attribute the phenomena of backscattering enhancement to a splitting of the integer edge into conducting and insulating stripes, which enable the occurrence of the more relevant backscattering processes of fractionally charged quasiparticles at the point contact. For the values of the parameters used in the experiments we find that the conducting channels are widely separated by the insulating stripes and that their presence alters significantly the low-energy dynamics of the edges. Interchannel impurity scattering does not influence strongly the tunneling exponents as they are found to be irrelevant processes at low energies. Exponents of backscattering at the point contact are unaffected by interchannel Coulomb interactions since all channels have same chirality of propagation.Comment: 19 pages; To appear in Phys. Rev.

Plasmonic atoms and plasmonic molecules

The proposed paradigm of plasmonic atoms and plasmonic molecules allows one to describe and predict the strongly localized plasmonic oscillations in the clusters of nanoparticles and some other nanostructures in uniform way. Strongly localized plasmonic molecules near the contacting surfaces might become the fundamental elements (by analogy with Lego bricks) for a construction of fully integrated opto-electronic nanodevices of any complexity and scale of integration.Comment: 30 pages, 16 figure

On the accuracy of the PFA: analogies between Casimir and electrostatic forces

We present an overview of the validity of the Proximity Force Approximation (PFA) in the calculation of Casimir forces between perfect conductors for different geometries, with particular emphasis for the configuration of a cylinder in front of a plane. In all cases we compare the exact numerical results with those of PFA, and with asymptotic expansions that include the next to leading order corrections. We also discuss the similarities and differences between the results for Casimir and electrostatic forces.Comment: 17 pages, 5 figures, Proceedings of the meeting "60 years of Casimir effect", Brasilia, 200