Use of Sentinel-2 Satellite for Spatially Variable Rate Fertiliser Management in a Sicilian Vineyard

Satellites can be used for producing maps of within-field crop and soil parameters and, consequentially, spatially variable rate crop input application maps. The plant vegetative vigour index (i.e., Normalised Difference Vegetation Index—NDVI) and the leaf water content index (i.e., Normalised Difference Water Index—NDWI) maps were used to study—through both time and space—the phenological phases of two plots, with Syrah and Nero d’Avola grapevine varieties, in a Sicilian vineyard farm, located in Naro (Agrigento, Sicily, Italy). The aim of this work is to produce spatially variable rate nitrogen fertiliser maps to be applied in the two vineyard plots under study as well as to understand when they should be fertilised or not according to their target crop yields. The average plant vegetative vigour and leaf water content of both the plots showed a high temporal and spatial variability during all phenological phases and, according to these results, the optimal fertilisation time should have been 12 April 2021. In fact, this crop operation is aimed at supporting the vegetative activity but must be performed when the soil water and, therefore, the plant leaf water content are high. Therefore, spatially variable rate fertilisation should have been performed around 12 April 2021 in both plots, using previous NDVI maps and taking into consideration two management zones. This work demonstrates the usefulness of remote sensing data as Decision Support Systems (DSS) for nitrogen fertilisation in order to reduce the production cost, environmental impact and climate footprints per kg of produced grapes, according to the European Green Deal challenges

Spin Orbit Effects in the Electronic Transport Properties of Adsorbed Graphene Nanoribbons

Graphene has received great attention due to its exceptional properties, which include corners with zero effective mass, extremely large mobilities, this could render it the new template for the next generation of electronic devices. Furthermore it has weak spin orbit interaction because of the low atomic number of carbon atom in turn results in long spin coherence lengths. Therefore, graphene is also a promising material for future applications in spintronic devices - the use of electronic spin degrees of freedom instead of the electron charge. Graphene can be engineered to form a number of different structures. In particular, by appropriately cutting it one can obtain 1-D system -with only a few nanometers in width - known as graphene nanoribbon, which strongly owe their properties to the width of the ribbons and to the atomic structure along the edges. Those GNR-based systems have been shown to have great potential applications specially as connectors for integrated circuits. Impurities and defects might play an important role to the coherence of these systems. In particular, the presence of transition metal atoms can lead to significant spin-flip processes of conduction electrons. Understanding this effect is of utmost importance for spintronics applied design. In this work, we focus on electronic transport properties of armchair graphene nanoribbons with adsorbed transition metal atoms as impurities and taking into account the spin-orbit effect. Our calculations were performed using a combination of density functional theory and non-equilibrium Greens functions. Also, employing a recursive method we consider a large number of impurities randomly distributed along the nanoribbon in order to infer, for different concentrations of defects, the spin-coherence length

Smart Cities: A Systematic Mapping on an Academic Basis

Smart Cities belong to a multidisciplinary research area, which does not yet have a formal definition and may have different meanings depending on the context. In view of this, the objective of this work is to map the term "Smart City" in the scientific field. For such, the scientific publications present in Scopus\u27 data base, accessed by the Periodicals portal of the Coordination for the Improvement of Higher Level Personnel (CAPES), were researched. As results, 61,435 publications were found, which after the inclusion criteria, 632 publications remained to be analyzed. China was the country that presented the largest number of publications with a total of 94 documents. The analysis of annual publications showed that there was an increase in the number of publications over the years, especially between 2018 and 2019. The main contributions of this work were the provision of a knowledge base that can be used by both scientists and researchers and developers of the organizations, identifying gaps and opportunities to be explored

Study of the Influence of Localized Vibrational Modes in Charge Transport Properties at Nanoscale Systems.

In molecular and atomic devices the interaction between electrons and ionic vibrations has an important role in electronic transport. The electron-phonon coupling can cause the loss of the electron's phase coherence, the opening of new conductance channels and the suppression of purely elastic ones. From the technological viewpoint phonons might restrict the efficiency of electronic devices by energy dissipation, causing heating, power loss and instability. The state of the art in electron transport calculations consists in combining ab initio calculations via Density Functional Theory (DFT) with Non-Equilibrium Green's Function formalism (NEGF). In order to include electron-phonon interactions, one needs in principle to include a self-energy scattering term in the open system Hamiltonian which takes into account the effect of the phonons over the electrons and vice versa. Nevertheless this term could be obtained approximately by perturbative methods. In the First Born Approximation one considers only the first order terms of the electronic Green's function expansion. In the Self-Consistent Born Approximation, the interaction self-energy is calculated with the perturbed electronic Green's function in a self-consistent way. In this work we describe how to incorporate the electron-phonon interaction to the SMEAGOL program (Spin and Molecular Electronics in Atomically Generated Orbital Landscapes), an ab initio code for electronic transport based on the combination of DFT + NEGF. This provides a tool for calculating the transport properties of materials' specific system, particularly in molecular electronics. Preliminary results will be presented, showing the effects produced by considering the electron-phonon interaction in nanoscale devices

Stretching of BDT-gold molecular junctions: thiol or thiolate termination?

It is often assumed that the hydrogen atoms in the thiol groups of a benzene-1,4-dithiol dissociate when Au-benzene-1,4-dithiol-Au junctions are formed. We demonstrate, by stability and transport properties calculations, that this assumption can not be made. We show that the dissociative adsorption of methanethiol and benzene-1,4-dithiol molecules on a flat Au(111) surface is energetically unfavorable and that the activation barrier for this reaction is as high as 1 eV. For the molecule in the junction, our results show, for all electrode geometries studied, that the thiol junctions are energetically more stable than their thiolate counterparts. Due to the fact that density functional theory (DFT) within the local density approximation (LDA) underestimates the energy difference between the lowest unoccupied molecular orbital and the highest occupied molecular orbital by several electron-volts, and that it does not capture the renormalization of the energy levels due to the image charge effect, the conductance of the Au-benzene-1,4-dithiol-Au junctions is overestimated. After taking into account corrections due to image charge effects by means of constrained-DFT calculations and electrostatic classical models, we apply a scissor operator to correct the DFT energy levels positions, and calculate the transport properties of the thiol and thiolate molecular junctions as a function of the electrodes separation.Comment: 14 pages, 13 figures, to appear in Nanoscal

Experimental and Numerical Investigation of Post-Flutter Limit Cycle Oscillations on a Cantilevered Flat Plate

Futuristic aircraft designs and novel aircraft such as High Altitude Long Endurance (HALE) involve a higher level of structural flexibility than in conventional aircraft. Even at present, the trends in the aviation industry are to increase wing length (to reduce induced drag) and maxi- mize use of composites, which lead to increased structural flexibility. This necessitates a rethink of conventional (linear) aeroelastic analysis, since the increased flexibility results in coupling between the flight dynamic and aeroelastic dynamics, and consequently, limit-cycle oscillations of the structure. In this paper, a new three-dimensional low-order model for unsteady aerody- namics that accounts for large oscillation amplitudes and nonplanar wakes is developed. An experiment with a cantilevered flat plate at low Reynolds number is set up and used to validate the low-order model, as well as to study post-flutter limit-cycle oscillations. Results from the low-order model are promising, but show that aerodynamic nonlinearities such as flow sepa- ration and leading-edge vortex shedding must also be modeled in order to predict all possible limit-cycle oscillations of the aeroelastic system