369 research outputs found
Further evidence on the extent and time course of repeat missing incidents involving children: A research note
This study examines the extent and time course of repeat missing incidents involving children. Using data from one UK police force (n = 2,251), we find (1) that the majority (65%) of missing incidents are repeats, (2) that a small group of repeatedly missing children (n = 43; 6%) account for a sizable proportion of all missing incidents (n=739, 33%) and (3) that the likelihood of a child going missing repeatedly is elevated in the weeks immediately following a previous missing incident. The implications of our findings for future research and for the prevention of missing incidents are discussed
Fundamental questions relating to ion conduction in disordered solids
A number of basic scientific questions relating to ion conduction in
homogeneously disordered solids are discussed. The questions deal with how to
define the mobile ion density, what can be learned from electrode effects, what
is the ion transport mechanism, the role of dimensionality, and what are the
origins of the mixed-alkali effect, of time-temperature superposition, and of
the nearly-constant loss. Answers are suggested to some of these questions, but
the main purpose of the paper is to draw attention to the fact that this field
of research still presents several fundamental challenges.Comment: Reports on Progress in Physics, to appea
Anomalous Drude Model
A generalization of the Drude model is studied. On the one hand, the free
motion of the particles is allowed to be sub- or superdiffusive; on the other
hand, the distribution of the time delay between collisions is allowed to have
a long tail and even a non-vanishing first moment. The collision averaged
motion is either regular diffusive or L\'evy-flight like. The anomalous
diffusion coefficients show complex scaling laws. The conductivity can be
calculated in the diffusive regime. The model is of interest for the
phenomenological study of electronic transport in quasicrystals.Comment: 4 pages, latex, 2 figures, to be published in Physical Review Letter
Problem-oriented policing in England and Wales: barriers and facilitators
Evidence shows that the application of problem-oriented policing can be effective in reducing a wide range of crime and public safety issues, but that the approach is challenging to implement and sustain. This article examines police perceptions and experiences regarding organisational barriers to and facilitators of the implementation and delivery of problem-oriented policing. Drawing on surveys of (n = 4141) and interviews with (n = 86) police personnel from 19 police forces in England and Wales, we identify five key barriers and facilitators to problem-oriented policing: leadership and governance, capacity, organisational structures and infrastructure, partnership working and organisational culture. These factors provide important indicators for what police organisations need to do, or need to avoid, if they are to successfully embed and deliver problem-oriented policing. The article generates critical information about the processes that drive change in police organisations and offers recommendations for police managers who may wish to implement or develop problem-oriented policing. The paper also proposes a research agenda aimed at addressing evidence gaps in our understanding of the implementation and sustenance of problem-oriented policing
Matrix controlled channel diffusion of sodium in amorphous silica
To find the origin of the diffusion channels observed in sodium-silicate
glasses, we have performed classical molecular dynamics simulations of
NaO--4SiO during which the mass of the Si and O atoms has been
multiplied by a tuning coefficient. We observe that the channels disappear and
that the diffusive motion of the sodium atoms vanishes if this coefficient is
larger than a threshold value. Above this threshold the vibrational states of
the matrix are not compatible with those of the sodium ions. We interpret hence
the decrease of the diffusion by the absence of resonance conditions.Comment: 5 pages, 4 figure
Metastable Dynamics above the Glass Transition
The element of metastability is incorporated in the fluctuating nonlinear
hydrodynamic description of the mode coupling theory (MCT) of the liquid-glass
transition. This is achieved through the introduction of the defect density
variable into the set of slow variables with the mass density and
the momentum density . As a first approximation, we consider the case
where motions associated with are much slower than those associated with
. Self-consistently, assuming one is near a critical surface in the MCT
sense, we find that the observed slowing down of the dynamics corresponds to a
certain limit of a very shallow metastable well and a weak coupling between
and . The metastability parameters as well as the exponents
describing the observed sequence of time relaxations are given as smooth
functions of the temperature without any evidence for a special temperature. We
then investigate the case where the defect dynamics is included. We find that
the slowing down of the dynamics corresponds to the system arranging itself
such that the kinetic coefficient governing the diffusion of the
defects approaches from above a small temperature-dependent value .Comment: 38 pages, 14 figures (6 figs. are included as a uuencoded tar-
compressed file. The rest is available upon request.), RevTEX3.0+eps
Does sequence similarity of human choline esterase, Torpedo acetylcholine esterase and Geotrichum candidum lipase reveal the active site serine residue?
Origin of non-exponential relaxation in a crystalline ionic conductor: a multi-dimensional 109Ag NMR study
The origin of the non-exponential relaxation of silver ions in the
crystalline ion conductor Ag7P3S11 is analyzed by comparing appropriate
two-time and three-time 109Ag NMR correlation functions. The non-exponentiality
is due to a rate distribution, i.e., dynamic heterogeneities, rather than to an
intrinsic non-exponentiality. Thus, the data give no evidence for the relevance
of correlated back-and-forth jumps on the timescale of the silver relaxation.Comment: 4 pages, 3 figure
Conformational and Structural Relaxations of Poly(ethylene oxide) and Poly(propylene oxide) Melts: Molecular Dynamics Study of Spatial Heterogeneity, Cooperativity, and Correlated Forward-Backward Motion
Performing molecular dynamics simulations for all-atom models, we
characterize the conformational and structural relaxations of poly(ethylene
oxide) and poly(propylene oxide) melts. The temperature dependence of these
relaxation processes deviates from an Arrhenius law for both polymers. We
demonstrate that mode-coupling theory captures some aspects of the glassy
slowdown, but it does not enable a complete explanation of the dynamical
behavior. When the temperature is decreased, spatially heterogeneous and
cooperative translational dynamics are found to become more important for the
structural relaxation. Moreover, the transitions between the conformational
states cease to obey Poisson statistics. In particular, we show that, at
sufficiently low temperatures, correlated forward-backward motion is an
important aspect of the conformational relaxation, leading to strongly
nonexponential distributions for the waiting times of the dihedrals in the
various conformational statesComment: 13 pages, 13 figure
Beta relaxation in the shear mechanics of equilibrium viscous liquids: Phenomenology and network modeling of the alpha-beta merging region
The phenomenology of the beta relaxation process in the shear-mechanical
response of glass-forming liquids is summarized and compared to that of the
dielectric beta process. Furthermore, we discuss how to model the observations
by means of standard viscoelastic modeling elements. Necessary physical
requirements to such a model are outlined, and it is argued that physically
relevant models must be additive in the shear compliance of the alpha and beta
parts. A model based on these considerations is proposed and fitted to data for
Polyisobutylene 680.Comment: 8 pages, 6 figures, Minor correction
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