Retrieval analysis of different orthodontic brackets: the applicability of electron microprobe techniques for determining material heterogeneities and corrosive potential

OBJECTIVE: The objective of this study was to investigate the applicability of micro-analytical methods with high spatial resolution to the characterization of the composition and corrosion behavior of two bracket systems. MATERIAL AND METHODS: The surfaces of six nickel-free brackets and six nickel-containing brackets were examined for signs of corrosion and qualitative surface analysis using an electron probe microanalyzer (EPMA), prior to bonding to patient's tooth surfaces and four months after clinical use. The surfaces were characterized qualitatively by secondary electron (SE) images and back scattered electron (BSE) images in both compositional and topographical mode. Qualitative and quantitative wavelength-dispersive analyses were performed for different elements, and by utilizing qualitative analysis the relative concentration of selected elements was mapped two-dimensionally. The absolute concentration of the elements was determined in specially prepared brackets by quantitative analysis using pure element standards for calibration and calculating correction-factors (ZAF). RESULTS: Clear differences were observed between the different bracket types. The nickel-containing stainless steel brackets consist of two separate pieces joined by a brazing alloy. Compositional analysis revealed two different alloy compositions, and reaction zones on both sides of the brazing alloy. The nickel-free bracket was a single piece with only slight variation in element concentration, but had a significantly rougher surface. After clinical use, no corrosive phenomena were detectable with the methods applied. Traces of intraoral wear at the contact areas between the bracket slot and the arch wire were verified. CONCLUSION: Electron probe microanalysis is a valuable tool for the characterization of element distribution and quantitative analysis for corrosion studies

Corrosion in Haas expanders with and without use of an antimicrobial agent: an in situ study

OBJECTIVES: The purpose of this study was to evaluate in situ the occurrence of corrosion in the soldering point areas between the wire, silver brazing and band in Haas expanders. MATERIAL AND METHODS: Thirty-four 7-12-year-old patients who needed maxillary expansion with a Haas expander were randomly assigned to two groups of 17 individuals each, according to the oral hygiene protocol adopted during the orthodontic treatment: Group I (control), toothbrushing with a fluoride dentifrice and Group II (experimental), toothbrushing with the same dentifrice plus 0.12% chlorhexidine gluconate (Periogard(®)) mouthrinses twice a week. The appliances were removed after approximately 4 months. Fragments of the appliances containing a metallic band with a soldered wire were sectioned at random for examination by stereomicroscopy, scanning electron microscopy (SEM) and energy dispersive x-ray spectroscopy (EDS). Data were analyzed statistically by Fisher's test at 5% significance level. RESULTS: The analysis by optical microscopy revealed areas with color change suggestive of corrosion in the soldering point areas joining the band and the wire in all specimens of both groups, with no statistically significant difference between the groups (p=1). The peaks of chemical elements (Ni, Fe, Cr, O, C and P) revealed by EDS were also similar in both groups. CONCLUSION: Color changes and peaks of chemical elements suggestive of corrosion were observed in the soldering point areas between the wire, silver brazing and band in both control and experimental groups, which indicate that the 0.12% chlorhexidine gluconate mouthrinses did not influence the occurrence of corrosion in situ

Galvanic corrosion of metal injection molded (MIM) and conventional brackets with nickel-titanium and copper-nickel-titanium archwires

Objective: To compare the galvanic coupling of conventional and metal injection molded (MIM) brackets with commonly used orthodontic archwires. Materials and Methods: Six of each type of bracket were suspended in lactic acid along with a sample of orthodontic wire (three nickel-titanium and three copper-nickel-titanium) for 28 days at 37°C. The potential differences between the wires and brackets were recorded per second throughout the duration of the experiment. Results: The MIM brackets exhibited potential differences similar to those seen for the conventional brackets. The greatest potential difference was found for MIM brackets with nickel-titanium wires (512 mV), whereas MIM brackets with copper-nickel-titanium wires had the smallest difference (115 mV). Scanning electron microscope (SEM)-energy-dispersive spectroscopic analysis of the tie-wing area of each bracket type indicated similar elemental composition in both brackets, but in slightly different percentages by weight. The MIM bracket exhibited extensive internal porosity, whereas the conventional bracket was more solid internally. Conclusion: The composition and manufacturing processes involved in fabricating MIM brackets impart corrosive properties similar to those seen in the bracket-wing area of conventional brackets and may provide a measurable benefit when taking into account the increased corrosion between the bracket and brazing alloy of conventional brackets. © 2006 by The EH Angle Education and Research Foundation, Inc