Effect of long range forces on the interfacial profiles in thin binary polymer films

We study the effect of surface fields on the interfacial properties of a binary polymer melt confined between two parallel walls. Each wall attracts a different component of the blend by a non-retarded van der Waals potential. An interface which runs parallel to the surfaces is stabilized in the center of the film. Using extensive Monte Carlo simulations we study the interfacial properties as a function of the film thickness, the strength of the surface forces and the lateral size over which the profiles across the film are averaged. We find evidence for capillary wave broadening of the apparent interfacial profiles. However, the apparent interfacial width cannot be described quantitatively by a simple logarithmic dependence on the film thickness. The Monte Carlo simulations reveal that the surface fields give rise to an additional reduction of the intrinsic interfacial width and an increase of the effective interfacial tension upon decreasing the film thickness. These modifications of the intrinsic interfacial properties are confirmed by self-consistent field calculations. Taking account of the thickness dependence of the intrinsic interfacial properties and the capillary wave broadening, we can describe our simulation results quantitatively.Comment: to appear in J.Chem.Phy

Diblock copolymers at a homopolymer-homopolymer-interface: a Monte Carlo simulation

The properties of diluted symmetric A-B diblock copolymers at the interface between A and B homopolymer phases are studied by means of Monte Carlo (MC) simulations of the bond fluctuation model. We calculate segment density profiles as well as orientational properties of segments, of A and B blocks, and of the whole chain. Our data support the picture of oriented ``dumbbells'', which consist of mildly perturbed A and B Gaussian coils. The results are compared to a self consistent field theory (SCFT) for single copolymer chains at a homopolymer interface. We also discuss the number of interaction contacts between monomers, which provide a measure for the ``active surface'' of copolymers or homopolymers close to the interface

New HST Observations of the Halo Gas of NGC 3067: Limits on the Extragalactic Ionizing Background at Low Redshift and the Lyman Continuum Escape Fraction

We present UV spectroscopy from HST/GHRS and reanalyze existing H_alpha images of the quasar/galaxy pair 3C 232/NGC 3067 and of the halo gas associated with NGC 3067. The spectra permit measurement of, or limits on, the column densities of Fe I, Fe II, Mg I, and Mg II in the absorbing cloud. Two distinct models of the extragalactic radiation field are considered: (1) the ionizing spectrum is dominated by a power-law extragalactic continuum, and (2) the power-law spectrum contains a Lyman break, implying enhanced flux longward of 912 A relative to the hydrogen-ionizing flux. The H_alpha images constrain the escape fraction of Lyman continuum photons from the galaxy to f_esc <= 0.02. With the assumption that the cloud is shielded from all galactic contributions, we can constrain the intensity and shape of the extragalactic continuum. For an AGN-dominated power-law extragalactic spectrum, we derive a limit on the extragalactic ionizing flux Phi_ion >= 2600 photons cm^-2 s^-1, or I_0 >= 10^-23 erg cm^-2 s^-1 Hz^-1 sr^-1 for an ionizing spectrum with power-law index of 1.8 and a cloud of constant density. When combined with previous upper limits from the absence of H_alpha recombination emission from intergalactic clouds, our observations require 2600 <= Phi_ion <= 10000 photons cm^-2 s^-1. We show that if galactic contributions to the incident radiation are important, it is difficult to constrain Phi_ion. These results demonstrate that galactic halo opacities and their wavelength dependence are crucial to understanding the abundance of low-ionization metals in the IGM.Comment: 25 Pages LaTex, 8 PostScript Figures, accepted for publication in AJ, Nov. 99 issu

The Escape of Ionizing Photons from OB Associations in Disk Galaxies: Radiation Transfer Through Superbubbles

By solving the time-dependent radiation transfer problem of stellar radiation through evolving superbubbles within a smoothly varying HI distribution, we estimate the fraction of ionizing photons emitted by OB associations that escapes the HI disk of our Galaxy into the halo and intergalactic medium (IGM). We consider both coeval star-formation and a Gaussian star-formation history with a time spread sigma_t = 2 Myr. We consider both a uniform H I distribution and a two-phase (cloud/intercloud) model, with a negligible filling factor of hot gas. We find that the shells of the expanding superbubbles quickly trap or attenuate the ionizing flux, so that most of the escaping radiation escapes shortly after the formation of the superbubble. For the coeval star-formation history, the total fraction of Lyman Continuum photons that escape both sides of the disk in the solar vicinity is f_esc approx 0.15 +/- 0.05. For the Gaussian star formation history, f_esc approx 0.06 +/- 0.03, a value roughly a factor of two lower than the results of Dove & Shull (1994), where superbubbles were not considered. For a local production rate of ionizing photons Psi_LyC = 4.95 X 10^7 cm^{-2} s^{-1}, the flux escaping the disk is Phi_LyC approx (1.5-3.0) X 10^6 cm^{-2} s^{-1} for coeval and Gaussian star formation, comparable to the flux required to sustain the Reynolds layer.Comment: Revised version (expanded), accepted for publication by ApJ, 38 pages, 8 figures, aasms4.sty and aabib.sty files include

Levitation of superconducting composites

The inverse levitation of a high temperature superconductor polymer composite consisting of powdered quench melt growth Ba2YCu3O(7-delta) and cyanoacrylate is reported. Magnetic hysteresis loop measurements for the composite are compared to those measured for the bulk material prior to powdering. Differences in the flux pining capability between the two material forms are small but significant

FUSE Observations of Intrinsic Absorption in the Seyfert 1 Galaxy Mrk 509

We present far-ultraviolet spectra of the Seyfert 1 galaxy Mrk 509 obtained in 1999 November with the Far Ultraviolet Spectroscopic Explorer (FUSE). Our data span the observed wavelength range 915-1185 A at a resolution of ~20 km/s. The spectrum shows a blue continuum, broad OVI 1032,1038 emission, and a broad CIII 977 emission line. Superposed on these emission components, we resolve associated absorption lines of OVI 1032,1038, CIII 977, and Lyman lines through Lzeta. Seven distinct kinematic components are present, spanning a velocity range of -440 to +170 km/s relative to the systemic velocity. The absorption is clustered in two groups, one centered at -370m km/s and another at the systemic velocity. The blue-shifted cluster may be associated with the extended line emission visible in deep images of Mrk 509 obtained by Phillips et al. Although several components appear to be saturated, they are not black at their centers. Partial covering or scattering permits ~7% of the broad-line or continuum flux to be unaffected by absorption. Of the multiple components, only one has the same ionization state and column density as highly ionized gas that produces the OVII and OVIII ionization edges in X-ray spectra of Mrk 509. This paper will appear in a special issue of Astrophysical Journal Letters devoted to the first scientific results from the FUSE mission.Comment: To appear in the Astrophysical Journal (Letters). 4 pages, 3 color PostScript figures. Figures are best viewed and printed in color. Added acknowledgment that this is one of many papers to be published in a special issue of ApJL devoted to the first scientific results from the FUSE missio