303 research outputs found
A Novel Route for Preparation of Hollow Carbon Nanospheres Without Introducing Template
A newly developed route for the synthesis of hollow carbon nanospheres without introducing template under hydrothermal conditions was reported. Hollow carbon nanospheres with the diameter of about 100 nm were synthesized using alginate as reagent only. Many instruments were applied to characterize the morphologies and structures of carbon hollow nanospheres, such as XRD, TEM, and Raman spectroscopy. The possible formation and growth mechanism of carbon hollow spheres were discussed on the basis of the investigation of reaction influence factors, such as temperature, time, and content. The findings would be useful for the synthesis of more materials with hollow structure and for the potential use in many aspects. The loading of SnO2on the surface of carbon hollow spheres was processed, and its PL property was also characterized
Alteration of cystic airway mesenchyme in congenital pulmonary airway malformation.
Congenital pulmonary airway malformation (CPAM) is the most common congenital lesion detected in the neonatal lung, which may lead to respiratory distress, infection, and pneumothorax. CPAM is thought to result from abnormal branching morphogenesis during fetal lung development, arising from different locations within the developing respiratory tract. However, the pathogenic mechanisms are unknown, and previous studies have focused on abnormalities in airway epithelial cells. We have analyzed 13 excised lung specimens from infants (age < 1 year) with a confirmed diagnosis of type 2 CPAM, which is supposed to be derived from abnormal growth of intrapulmonary distal airways. By examining the mesenchymal components including smooth muscle cells, laminin, and elastin in airway and cystic walls using immunofluorescence staining, we found that the thickness and area of the smooth muscle layer underlining the airway cysts in these CPAM tissue sections were significantly decreased compared with those in bronchiolar walls of normal controls. Extracellular elastin fibers were also visually reduced or absent in airway cystic walls. In particular, a layer of elastin fibers seen in normal lung between airway epithelia and underlying smooth muscle cells was missing in type 2 CPAM samples. Thus, our data demonstrate for the first time that airway cystic lesions in type 2 CPAM occur not only in airway epithelial cells, but also in adjacent mesenchymal tissues, including airway smooth muscle cells and their extracellular protein products. This provides a new direction to study the molecular and cellular mechanisms of CPAM pathogenesis in human
Hollow mesoporous zeolite microspheres: hierarchical macro-/meso-/ microporous structure and exceptionally enhanced adsorption properties
Assessing contributions of agricultural and nonagricultural emissions to atmospheric ammonia in a Chinese megacity
Ammonia (NH3) is the predominant alkaline gas in the atmosphere contributing to formation of fine particles—a leading environmental cause of increased morbidity and mortality worldwide. Prior findings suggest that NH3 in the urban atmosphere derives from a complex mixture of agricultural (mainly livestock production and fertilizer application) and nonagricultural (e.g., urban waste, fossil fuel-related emissions) sources; however, a citywide holistic assessment is hitherto lacking. Here we show that NH3 from nonagricultural sources rivals agricultural NH3 source contributions in the Shanghai urban atmosphere. We base our conclusion on four independent approaches: (i) a full-year operation of a passive NH3 monitoring network at 14 locations covering urban, suburban, and rural landscapes; (ii) model-measurement comparison of hourly NH3 concentrations at a pair of urban and rural supersites; (iii) source-specific NH3 measurements from emission sources; and (iv) localized isotopic signatures of NH3 sources integrated in a Bayesian isotope mixing model to make isotope-based source apportionment estimates of ambient NH3. Results indicate that nonagricultural sources and agricultural sources are both important contributors to NH3 in the urban atmosphere. These findings highlight opportunities to limit NH3 emissions from nonagricultural sources to help curb PM2.5 pollution in urban China
Anomalous thermal Hall effect and anomalous Nernst effect of CsVSb
Motived by time-reversal symmetry breaking and giant anomalous Hall effect in
kagome superconductor \textit{A}VSb (\textit{A} = Cs, K, Rb), we
carried out the thermal transport measurements on CsVSb. In addition to
the anomalous Hall effect, the anomalous Nernst effect and the anomalous
thermal Hall effect emerge. Interestingly, the longitudinal thermal
conductivity largely deviates from the electronic contribution
obtained from the longitudinal conductivity by the
Wiedemann-Franz law. In contrast, the thermal Hall conductivity
is roughly consistent with the Wiedemann-Franz law from electronic
contribution. All these results indicate the large phonon contribution in the
longitudinal thermal conductivity. Moreover, the thermal Hall conductivity is
also slightly greater than the theoretical electronic contribution, indicating
other charge neutral contributions. More than that, the Nernst coefficient and
Hall resistivity show the multi-band behavior with possible additional
contribution from Berry curvature at the low fields
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