Photovoltage Bleaching in Bulk Heterojunction Solar Cells through Occupation of the Charge Transfer State

We observe a strong peak in the capacitive photocurrent of a MDMO-PPV / PCBM bulk heterojunction solar cell for excitation below the absorbance threshold energy. Illumination at the peak energy blocks charge capture at other wavelengths, and causes the photovoltage to drop dramatically. These results suggest that the new peak is due to a charge transfer state, which provides a pathway for charge separation and photocurrent generation in the solar cell.Comment: submitted to Physical Review Letter

Learning to Hash-tag Videos with Tag2Vec

User-given tags or labels are valuable resources for semantic understanding of visual media such as images and videos. Recently, a new type of labeling mechanism known as hash-tags have become increasingly popular on social media sites. In this paper, we study the problem of generating relevant and useful hash-tags for short video clips. Traditional data-driven approaches for tag enrichment and recommendation use direct visual similarity for label transfer and propagation. We attempt to learn a direct low-cost mapping from video to hash-tags using a two step training process. We first employ a natural language processing (NLP) technique, skip-gram models with neural network training to learn a low-dimensional vector representation of hash-tags (Tag2Vec) using a corpus of 10 million hash-tags. We then train an embedding function to map video features to the low-dimensional Tag2vec space. We learn this embedding for 29 categories of short video clips with hash-tags. A query video without any tag-information can then be directly mapped to the vector space of tags using the learned embedding and relevant tags can be found by performing a simple nearest-neighbor retrieval in the Tag2Vec space. We validate the relevance of the tags suggested by our system qualitatively and quantitatively with a user study

Combining mathematical programming and SysML for component sizing as applied to hydraulic systems

In this research, the focus is on improving a designer's capability to determine near-optimal sizes of components for a given system architecture. Component sizing is a hard problem to solve because of the presence of competing objectives, requirements from multiple disciplines, and the need for finding a solution quickly for the architecture being considered. In current approaches, designers rely on heuristics and iterate over the multiple objectives and requirements until a satisfactory solution is found. To improve on this state of practice, this research introduces advances in the following two areas: a.) Formulating a component sizing problem in a manner that is convenient to designers and b.) Solving the component sizing problem in an efficient manner so that all of the imposed requirements are satisfied simultaneously and the solution obtained is mathematically optimal. In particular, an acausal, algebraic, equation-based, declarative modeling approach is taken to solve component sizing problems efficiently. This is because global optimization algorithms exist for algebraic models and the computation time is considerably less as compared to the optimization of dynamic simulations. In this thesis, the mathematical programming language known as GAMS (General Algebraic Modeling System) and its associated global optimization solvers are used to solve component sizing problems efficiently. Mathematical programming languages such as GAMS are not convenient for formulating component sizing problems and therefore the Systems Modeling Language developed by the Object Management Group (OMG SysML ) is used to formally capture and organize models related to component sizing into libraries that can be reused to compose new models quickly by connecting them together. Model-transformations are then used to generate low-level mathematical programming models in GAMS that can be solved using commercial off-the-shelf solvers such as BARON (Branch and Reduce Optimization Navigator) to determine the component sizes that satisfy the requirements and objectives imposed on the system. This framework is illustrated by applying it to an example application for sizing a hydraulic log splitter.M.S.Committee Co-Chair: Paredis, Chris ; Committee Co-Chair: Schaefer, Dirk; Committee Member: Goel, Asho

Detection of salient video segments and associated comments via reinforcement learning

The application of computer vision and techniques that rely on machine intelligence has improved automated determination of notable segments within video content. However, further refinement in these techniques can improve the quality and accuracy of the marked segments. Also, it can be difficult for automated techniques to surface the most notable text comments associated with video content. This disclosure describes techniques that combines initial independent automated determination of notable video segments and text comments to refine and improve each aspect based on the other. The techniques leverage audience engagement with live and pre-recorded video content as captured via user comments entered while the video is being viewed. Machine learning models that identify salient video segments can be trained using the output of models that identify notable comments and vice versa, using reinforcement learning

Explaining Snapshots of Network Diffusions: Structural and Hardness Results

Much research has been done on studying the diffusion of ideas or technologies on social networks including the \textit{Influence Maximization} problem and many of its variations. Here, we investigate a type of inverse problem. Given a snapshot of the diffusion process, we seek to understand if the snapshot is feasible for a given dynamic, i.e., whether there is a limited number of nodes whose initial adoption can result in the snapshot in finite time. While similar questions have been considered for epidemic dynamics, here, we consider this problem for variations of the deterministic Linear Threshold Model, which is more appropriate for modeling strategic agents. Specifically, we consider both sequential and simultaneous dynamics when deactivations are allowed and when they are not. Even though we show hardness results for all variations we consider, we show that the case of sequential dynamics with deactivations allowed is significantly harder than all others. In contrast, sequential dynamics make the problem trivial on cliques even though it's complexity for simultaneous dynamics is unknown. We complement our hardness results with structural insights that can help better understand diffusions of social networks under various dynamics.Comment: 14 pages, 3 figure

Retrieval-based Text Selection for Addressing Class-Imbalanced Data in Classification

This paper addresses the problem of selecting of a set of texts for annotation in text classification using retrieval methods when there are limits on the number of annotations due to constraints on human resources. An additional challenge addressed is dealing with binary categories that have a small number of positive instances, reflecting severe class imbalance. In our situation, where annotation occurs over a long time period, the selection of texts to be annotated can be made in batches, with previous annotations guiding the choice of the next set. To address these challenges, the paper proposes leveraging SHAP to construct a quality set of queries for Elasticsearch and semantic search, to try to identify optimal sets of texts for annotation that will help with class imbalance. The approach is tested on sets of cue texts describing possible future events, constructed by participants involved in studies aimed to help with the management of obesity and diabetes. We introduce an effective method for selecting a small set of texts for annotation and building high-quality classifiers. We integrate vector search, semantic search, and machine learning classifiers to yield a good solution. Our experiments demonstrate improved F1 scores for the minority classes in binary classification

Enhanced Breast Cancer Tumor Classification using MobileNetV2: A Detailed Exploration on Image Intensity, Error Mitigation, and Streamlit-driven Real-time Deployment

This research introduces a sophisticated transfer learning model based on Google's MobileNetV2 for breast cancer tumor classification into normal, benign, and malignant categories, utilizing a dataset of 1576 ultrasound images (265 normal, 891 benign, 420 malignant). The model achieves an accuracy of 0.82, precision of 0.83, recall of 0.81, ROC-AUC of 0.94, PR-AUC of 0.88, and MCC of 0.74. It examines image intensity distributions and misclassification errors, offering improvements for future applications. Addressing dataset imbalances, the study ensures a generalizable model. This work, using a dataset from Baheya Hospital, Cairo, Egypt, compiled by Walid Al-Dhabyani et al., emphasizes MobileNetV2's potential in medical imaging, aiming to improve diagnostic precision in oncology. Additionally, the paper explores Streamlit-based deployment for real-time tumor classification, demonstrating MobileNetV2's applicability in medical imaging and setting a benchmark for future research in oncology diagnostics