Compression Characteristics of Selected Ground Agricultural Biomass

Agricultural biomass such as barley, canola, oat and wheat straw has the potential to be used as feedstock for bioenergy. However, the low bulk density straw must be processed and densified in order to facilitate handling, storage and transportation. It is important to understand the fundamental mechanism of the biomass compression process, which is required in the design of energy efficient compaction equipment to mitigate the cost of pre-processing and transportation of the product. Therefore, a comprehensive review of various compression models was performed and the compression behavior of selected ground agricultural biomass was studied. Five compression models were considered to determine the pressure-volume and pressure-density relationship to analyze the compression characteristics of biomass samples, namely: Jones (1960), Heckle (1961), Cooper-Eaton (1962), Kawakita-Ludde (1971) and Panelli-Filho (2001) models. Densification studies were conducted on four selected biomass samples at 10 % moisture content (w.b.) and 1.98 mm grind size using four pressure levels of 31.6, 63.2, 94.7 and 138.9 MPa. The mean densities of barley, canola, oat and wheat straw increased from 907 to 977 kg/m3, 823 to 1003 kg/m3, 849 to 1011 kg/m3 and 813 to 924 kg/m3, respectively. The Kawakita-Ludde model provided an excellent fit having R2 values of 0.99 for selected agricultural straw samples. It was also concluded that the ground oat and canola straw had the highest level of porosity and failure stress, respectively. The parameters of Cooper-Eaton model indicated that the ground straw samples were densified easily by the particles rearrangement method and Jones model indicated that canola and oat straw were more compressible as compared to barley and wheat straw

Potential Applications of Infrared and Raman Spectromicroscopy for Agricultural Biomass

The low bulk density agricultural biomass should be processed and densified making it suitable for biorefineries. However, many agricultural biomass (lignocellulosic) especially those from straw and stover results in poorly formed pellets or compacts that are more often dusty, difficult to handle and costly to manufacture. The binding characteristics of biomass can be enhanced by modifying the structure of lignocellulose matrix (cellulose-hemicellulose-lignin) by different pre-processing and pre-treatment methods. However, it is not well understood as to how various pre-processing and pre-treatment methods affect the lignocellulosic matrix at the molecular level. Therefore, it is essential to determine chemical composition of agricultural biomass and the distribution of lignin relative to cellulose and hemicellulose before and after application of various treatment methods and after densification process. In this paper, the structural characteristics of lignocellulosic plant biomass and applications of Infrared (IR) and Raman spectromicroscopy methods are reviewed. The IR and Raman methods have good potential to determine the structural characteristics and distribution of chemical components in lignocellulosic biomass. Both methods have their own advantages and drawbacks, and should be used as complementary techniques