7,474 research outputs found
Multiorbital tunneling ionization of the CO molecule
We coincidently measure the molecular frame photoelectron angular
distribution and the ion sum-momentum distribution of single and double
ionization of CO molecules by using circularly and elliptically polarized
femtosecond laser pulses, respectively. The orientation dependent ionization
rates for various kinetic energy releases allow us to individually identify the
ionizations of multiple orbitals, ranging from the highest occupied to the next
two lower-lying molecular orbitals for various channels observed in our
experiments. Not only the emission of a single electron, but also the
sequential tunneling dynamics of two electrons from multiple orbitals are
traced step by step. Our results confirm that the shape of the ionizing
orbitals determine the strong laser field tunneling ionization in the CO
molecule, whereas the linear Stark effect plays a minor role.Comment: This paper has been accepted for publication by Physical Review
Letter
Emitter-site selective photoelectron circular dichroism of trifluoromethyloxirane
The angle-resolved inner-shell photoionization of R-trifluoromethyloxirane,
C3H3F3O, is studied experimentally and theoretically. Thereby, we investigate
the photoelectron circular dichroism (PECD) for nearly-symmetric O 1s and F 1s
electronic orbitals, which are localized on different molecular sites. The
respective dichroic and angular distribution parameters
are measured at the photoelectron kinetic energies from 1 to 16 eV by using
variably polarized synchrotron radiation and velocity map imaging spectroscopy.
The present experimental results are in good agreement with the outcome of ab
initio electronic structure calculations. We report a sizable chiral asymmetry
of up to about 9% for the K-shell photoionization of oxygen atom.
For the individual fluorine atoms, the present calculations predict asymmetries
of similar size. However, being averaged over all fluorine atoms, it drops down
to about 2%, as also observed in the present experiment. Our study demonstrates
a strong emitter- and site-sensitivity of PECD in the one-photon inner-shell
ionization of this chiral molecule
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