Synthesis of fused cyanopyrroles and spirocyclopropanes via addition of N-ylides to chalconimines

Addition of N-ylides derived from DABCO to chalconimines takes place through a Michael addition-cyclization pathway to afford fused cyanopyrroles and/or spirocyclopropanes. The product profile depends heavily on the nature of chalconimines. While 6-membered cyclic chalconimines provide a mixture of pyrrole and spirocyclopropane, 5-membered chalconimines furnish exclusively spirocyclopropane. Cyclopropane was the only product in the case of a representative open chain chalconimine as well. On the other hand, chalcones provide only spirocyclopropanes which is in contrast to the previously reported reactivity of enones. The complementary nature of the reactivity of the tetralone derived chalcone and its corresponding imine in providing spirocyclopropane and pyrrole, respectively, has also been demonstrated

Global (50°S-50°N) distribution of water vapor observed by COSMIC GPS RO: Comparison with GPS radiosonde, NCEP, ERA-Interim, and JRA-25 reanalysis data sets

In this study, global (50°S-50°N) distribution of water vapor is investigated using COSMIC GPS RO measurements. Detailed comparisons have been made between COSMIC and high resolution GPS radiosonde measurements across 13 tropical stations and model outputs (ERA-Interim, NCEP, and JRA-25 reanalyses data sets). In comparison with independent techniques like radiosonde (Väisälä), it is found that COSMIC GPS RO wet profiles are accurate up to 7-8. km (assuming radiosonde as standard technique). In general, comparisons with corresponding seasonal means of model outputs are qualitatively in good agreement, although they differ quantitatively especially over convective regions of South America, Africa, and Indonesia. In tropical latitudes, the COSMIC specific humidity values are higher than the model outputs. Among various model outputs, ERA-Interim data set show near realistic features to that observed by COSMIC GPS RO measurements. Large asymmetry in the specific humidity distribution is observed between northern and southern hemispheres. © 2011 Elsevier Ltd

Global (50°S-50°N) distribution of water vapor observed by COSMIC GPS RO: Comparison with GPS radiosonde, NCEP, ERA-Interim, and JRA-25 reanalysis data sets

In this study, global (50°S-50°N) distribution of water vapor is investigated using COSMIC GPS RO measurements. Detailed comparisons have been made between COSMIC and high resolution GPS radiosonde measurements across 13 tropical stations and model outputs (ERA-Interim, NCEP, and JRA-25 reanalyses data sets). In comparison with independent techniques like radiosonde (Väisälä), it is found that COSMIC GPS RO wet profiles are accurate up to 7-8. km (assuming radiosonde as standard technique). In general, comparisons with corresponding seasonal means of model outputs are qualitatively in good agreement, although they differ quantitatively especially over convective regions of South America, Africa, and Indonesia. In tropical latitudes, the COSMIC specific humidity values are higher than the model outputs. Among various model outputs, ERA-Interim data set show near realistic features to that observed by COSMIC GPS RO measurements. Large asymmetry in the specific humidity distribution is observed between northern and southern hemispheres. © 2011 Elsevier Ltd