578 research outputs found

    A High-Resolution Compton Scattering Study of the Electron Momentum Density in Al

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    We report high-resolution Compton profiles (CP's) of Al along the three principal symmetry directions at a photon energy of 59.38 keV, together with corresponding highly accurate theoretical profiles obtained within the local-density approximation (LDA) based band-theory framework. A good accord between theory and experiment is found with respect to the overall shapes of the CP's, their first and second derivatives, as well as the anisotropies in the CP's defined as differences between pairs of various CP's. There are however discrepancies in that, in comparison to the LDA predictions, the measured profiles are lower at low momenta, show a Fermi cutoff which is broader, and display a tail which is higher at momenta above the Fermi momentum. A number of simple model calculations are carried out in order to gain insight into the nature of the underlying 3D momentum density in Al, and the role of the Fermi surface in inducing fine structure in the CP's. The present results when compared with those on Li show clearly that the size of discrepancies between theoretical and experimental CP's is markedly smaller in Al than in Li. This indicates that, with increasing electron density, the conventional picture of the electron gas becomes more representative of the momentum density and that shortcomings of the LDA framework in describing the electron correlation effects become less important.Comment: 7 pages, 6 figures, regular articl

    Monitoring bridge degradation using dynamic strain, acoustic emission and environmental data

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    This paper studies the long term structural behaviour of a Victorian railway viaduct under train loading and temperature variation. A multi-sensing, self-sustaining and remotely controlled data acquisition system combines fibre Bragg grating strain sensors with acoustic emission sensors for the study of both global dynamic deformation and local masonry deterioration. A statistical analysis of fibre Bragg grating signals reveals regions with permanent change in the dynamic deformation of the bridge over the last two years, whereas in other locations the deformation follows a seasonal cyclic pattern. In order to decouple changes in structural behaviour due to real mechanical damage from normal seasonal effect, the paper studies the ambient temperature effect on the dynamic deformation of the bridge, showing a clear linear dependence. In particular, when temperature increases, the dynamic strain due to train loading decreases uniformly in the longitudinal direction. In the transverse direction, where the thermal expansion is not constrained, the decrease is smaller. Decoupling damage from normal seasonal effect is of critical importance for the development of reliable early warning structural alert systems for infrastructure networks. The paper further studies local masonry deterioration at four critical location by combining data from the two sensing technologies: fibre optic and acoustic emission sensors.This work is being funded by the Lloyd’s Register Foundation, EPSRC and Innovate UK through the Data-Centric Engineering programme of the Alan Turing Institute and through the Cambridge Centre for Smart Infrastructure and Construction. Funding for the monitoring installation was provided by EPSRC under the Ref. EP/N021614/1 grant and by Innovate UK under the Ref. 920035 grant

    A new double-layered kagome antiferromagnet ScFe6_6Ge4_4

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    ScFe6_6Ge4_4 with the LiFe6_6Ge4_4-type structure (space group R3ˉmR{\bar{3}}m), which has a double-layered kagome lattice (18hh site) of Fe crystallographically equivalent to that of a well-known topological ferromagnet Fe3_3Sn2_2, is newly found to be antiferromagnetic (AFM) with a high N\'eel temperature of TN≈650T_{\rm{N}} \approx 650 K, in contrast to the ferromagnetic (FM) ground state previously proposed in a literature. 45^{45}Sc nuclear magnetic resonance experiment revealed the absence of a hyperfine field at the Sc site, providing microscopic evidence for the AFM state and indicating AFM coupling between the bilayer kagome blocks. The stability of the AFM structure under the assumption of FM intra-bilayer coupling is verified by DFT calculations.Comment: 13 pages, 1 tables, 4 figure

    In situ observations of "cold trap" dehydration in the western tropical Pacific

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    International audienceWater vapor sonde observations were conducted at Bandung, Indonesia (6.90 S, 107.60 E) and Tarawa, Kiribati (1.35 N, 172.91 E) in December 2003 to examine the efficiency of the "cold trap'' dehydration in the tropical tropopause layer (TTL). Trajectory analysis based on bundles of trajectories suggest that the modification of air parcels' identity due to irreversible mixing by the branching-out and merging-in of nearby trajectories is found to be an important factor, in addition to the routes air parcels are supposed to follow, for interpreting the water vapor concentrations observed by radiosondes in the TTL. Clear correspondence between the observed water vapor concentration and the estimated temperature history of air parcels is found showing that dry air parcels are exposed to low temperatures while humid air parcels do not experience cold conditions during advection, in support of the "cold trap'' hypothesis. It is suggested that the observed air parcel retained the water vapor by roughly twice as much as the minimum saturation mixing ratio after its passage through the "cold trap,'' although appreciable uncertainties remain

    Measurement of stratospheric and mesospheric winds with a submillimeter wave limb sounder: results from JEM/SMILES and simulation study for SMILES-2

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    Satellite missions for measuring winds in the troposphere and thermosphere will be launched in a near future. There is no plan to observe winds in the altitude range between 30-90 km, though middle atmospheric winds are recognized as an essential parameter in various atmospheric research areas. Sub-millimetre limb sounders have the capability to fill this altitude gap. In this paper, we summarize the wind retrievals obtained from the Japanese Superconducting Submillimeter Wave Limb Emission Sounder (SMILES) which operated from the International Space Station between September 2009 and April 2010. The results illustrate the potential of such instruments to measure winds. They also show the need of improving the wind representation in the models in the Tropics, and globally in the mesosphere. A wind measurement sensitivity study has been conducted for its successor, SMILES-2, which is being studied in Japan. If it is realized, sub-millimeter and terahertz molecular lines suitable to determine line-of-sight winds will be measured. It is shown that with the current instrument definition, line-of-sight winds can be observed from 20 km up to more than 160 km. Winds can be retrieved with a precision better than 5 m s(-1) and a vertical resolution of 2-3 km between 35-90 km. Above 90 km, the precision is better than 10 m s(-1) with a vertical resolution of 3-5 km. Measurements can be performed day and night with a similar sensitivity. Requirements on observation parameters such as the antenna size, the satellite altitude are discussed. An alternative setting for the spectral bands is examined. The new setting is compatible with the general scientific objectives of the mission and the instrument design. It allows to improve the wind measurement sensitivity between 35 to 90 km by a factor 2. It is also shown that retrievals can be performed with a vertical resolution of 1 km and a precision of 5-10 m s(-1) between 50 and 90 km. RAGAM A, 1953, PHYSICAL REVIEW, V92, P144

    Cyclooxygenase 2 and Prostaglandin E2 are not Involved in N-Nitrosodiethylamine-Initiated Early Rat Hepatocarcinogenesis

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    The present study was undertaken to investigate the effect of dietary supplementation with nimesulide or eugenol on N-nitrosodiethylamine (DEN)-initiated early hepatocarcinogenesis in F344 male rats. Both compounds did not alter the expression of cytochrome P450 (CYP) 2E1, the enzyme that plays a major role in the activation of DEN to genotoxic products; however, nimesulide induced the expression of CYP1A1. Western blot analysis revealed that COX-1 and COX-2 protein expressions were not modulated by DEN compared with normal controls. Furthermore, post-initiation feeding with nimesulide or eugenol did not modulate COX-2 protein expression in normal or DEN-treated rats, whereas eugenol significantly increased the liver prostaglandin E2 (PGE2) levels of DEN-injected animals compared with the DEN controls. Ultimately, nimesulide or eugenol did not modify DEN-induced hepatocarcinogenesis as evidenced by insignificant changes in the number and size of preneoplastic placental glutathione S-transferase (GST-P) positive liver foci compared with the DEN controls. These results suggest that COX-2, as well as prostaglandin E2, may play no role in the post-initiation development of DEN-induced rat hepatocarcinogenesis at an early stage

    HCI and CIO Profiles Inside the Antarctic Vortex as Observed by Smiles in November 2009: Comparisons with MLS and ACE-FTS Instruments

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    We present vertical profiles of hydrogen chloride (HCl) and chlorine monoxide (ClO) as observed by the Superconducting Submillimeter-Wave Limb-Emission Sounder (SMILES) on the International Space Station (ISS) inside the Antarctic vortex on 19-24 November 2009. The SMILES HCl value reveals 2.8-3.1 ppbv between 450K and 500K levels in potential temperature (PT). The high value of HCl is highlighted since it is suggested that HCl is a main component of the total inorganic chlorine Cly, defined as Cly similar or equal to HCl + ClO + chlorine nitrate ClONO2, inside the Antarctic vortex in spring, owing to low ozone values. To confirm the quality of two SMILES level 2 (L2) data products provided by the Japan Aerospace Exploration Agency (JAXA) and Japan\u27s National Institute of Information and Communications Technology (NICT), vis-a-vis the partitioning of Cly, comparisons are made using other satellite data from the Aura Microwave Limb Sounder (MLS) and Atmospheric Chemistry Experiment Fourier Transform Spectrometer (ACE-FTS). HCl values from the SMILES NICT L2 product agree to within 10% (0.3 ppbv) with the MLS HCl data between 450 and 575K levels in PT and with the ACE-FTS HCl data between 425 and 575 K. The SMILES JAXA L2 product is 10 to 20% (0.2-0.5 ppbv) lower than that from MLS between 400 and 700K and from ACE-FTS between 500 and 700 K. For ClO in daytime, the difference between SMILES (JAXA and NICT) and MLS is less than ±0.05 ppbv (100 %) between 500K and 650K with the ClO values less than 0.2 ppbv. ClONO2 values as measured by ACE-FTS also reveal 0.2 ppbv at 475-500K level, resulting in the HCl/Cly ratios of 0.91-0.95. The HCl/Cly ratios derived from each retrieval agree to within -5 to 8% with regard to their averages. The high HCl values and HCl/Cly ratios observed by the three instruments in the lower stratospheric Antarctic vortex are consistent with previous observations in late Austral spring

    A Novel 2D Folding Technique for Enhancing Fermi Surface Signatures in the Momentum Density: Application to Compton Scattering Data from an Al-3at%Li Disordered Alloy

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    We present a novel technique for enhancing Fermi surface (FS) signatures in the 2D distribution obtained after the 3D momentum density in a crystal is projected along a specific direction in momentum space. These results are useful for investigating fermiology via high resolution Compton scattering and positron annihilation spectroscopies. We focus on the particular case of the (110) projection in an fcc crystal where the standard approach based on the use of the Lock-Crisp-West (LCW) folding theorem fails to give a clear FS image due to the strong overlap with FS images obtained through projection from higher Brillouin zones. We show how these superposed FS images can be disentangled by using a selected set of reciprocal lattice vectors in the folding process. The applicability of our partial folding scheme is illustrated by considering Compton spectra from an Al-3at%Li disordered alloy single crystal. For this purpose, high resolution Compton profiles along nine directions in the (110) plane were measured. Corresponding highly accurate theoretical profiles in Al-3at%Li were computed within the local density approximation (LDA)-based Korringa-Kohn-Rostoker coherent potential approximation (KKR-CPA) first-principles framework. A good level of overall accord between theory and experiment is obtained, some expected discrepancies reflecting electron correlation effects notwithstanding, and the partial folding scheme is shown to yield a clear FS image in the (110) plane in Al-3%Li.Comment: 24 pages, 8 figures, to appear in Phys. Rev.
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