Generation and origin of natural gas in Lower Palaeozoic shales from southern Sweden

The Lower Palaeozoic succession in Scandinavia includes several excellent marine source rocks notably the Alum Shale, the Dicellograptus shale and the Rastrites Shale that have been targets for shale gas exploration since 2008. We here report on samples of these source rocks from cored shallow scientific wells in southern Sweden. The samples contain both free and sorbed hydrocarbon gases with concentrations significantly above the background gas level. The gases consist of a mixture of thermogenic and bacterially derived gas. The latter likely derives from both carbonate reduction and methyl fermentation processes. The presence of both thermogenic and biogenic gas in the Lower Palaeozoic shales is in agreement with results from past and present exploration activities; thermogenic gas is a target in deeply buried, gas-mature shales in southernmost Sweden, Denmark and northern Poland, whereas biogenic gas is a target in shallow, immature-marginally mature shales in south central Sweden. We here document that biogenic gas signatures are present also in gas-mature shallow buried shales in Skåne in southernmost Sweden

The Lower Palaeozoic now fully cored and logged on Bornholm, Denmark

A 558 m long, complete section of the Lower Palaeozoic succession preserved onshore southern Bornholm has been compiled from five fully cored scientific wells, carried out between 2005 and 2012. The scientific programme included coring and geophysical logging of the five scientific wells that yielded a total of c. 750 m of partially overlapping cores as well as re-logging of water wells and acquisition of shallow seismic data. The last well drilled, the Sommerodde-1, cored the youngest preserved Silurian strata on Bornholm including strata not exposed in outcrops. The well penetrated 168.1 m of Silurian shales, 42.7 m of Upper Ordovician shales and 27.9 m of Alum Shale before it terminated at a depth of 250.3 m in the Lower Cambrian Norretorp Member of the Læså Formation. Th e Sommerodde-1 well documents that the Lower Silurian Cyrtograptus shale is at least 91.7 m thick and that the Rastrites shale is 76.4 m thick. The complete Lower Cambrian succession has previously been covered by the 316.0 m deep Borggård-1 well that terminated in basement rocks (Nielsen et al. 2006)

Middle-Upper Ordovician and Silurian stratigraphy and basin development in southernmost Scandinavia

A complete log-stratigraphical breakdown of the Middle Ordovician to lower Silurian shale-dominated succession is presented for the Bornholm–Skåne–Kattegat area in southernmost Scandinavia. A wireline log zonation developed for the onshore Bornholm Palaeozoic shales is extended to include the offshore Palaeozoic shales in the adjacent Rønne Graben. A complete log zonation scheme for the Cyrtograptus shale (late Llandovery–Wenlock) and the lower part of the Colonus shale (Ludlow) is presented including correlation within the Bornholm–Skåne–Kattegat area. The Cyrtograptus shale in the Bornholm area is estimated to be 400 m thick and marks the shift to a rapidly subsiding foreland basin, heralding the Caledonian Orogeny

Shallow core drilling of the Upper Cretaceous Chalk at Stevns Klint, Denmark

The Upper Cretaceous – Danian succession in Denmark and most of NW Europe is composed mainly of chalk and associated shallower water carbonates deposited in a wide epeiric sea during an overall global sea-level highstand (e.g. Surlyk 1997). The Maastrichtian–Danian chalk has been intensely studied over the last 20 years, since it forms the most important reservoir rock for hydrocarbons in the North Sea Central Graben (e.g. Surlyk et al. 2003; Klinkby et al. 2005). In Denmark, thousands of water wells have been drilled through the succession as about 35% of the water consumption is from Maastrichtian chalk and Danian bryozoan limestone. During 2005 the new Cretaceous Research Centre (CRC) was established jointly at Geocenter Copenhagen by the Geological Institute, University of Copenhagen and the Geological Survey of Denmark and Greenland (GEUS) with financial support from the Danish Natural Science Research Council (FNU). CRC aims at studying the Earth System in a Greenhouse World, with special emphasis on the Upper Cretaceous – Danian chalk of NW Europe. The stable, long lasting marine macro-environment represented by the chalk sea provides a unique opportunity to analyse and link the depositional, geochemical and biological responses to external forcing at time scales ranging from the sub-Milankovitch to the million year range. The studies will be based on a wide range of methods, including seismic stratigraphy, palaeoecology, sequence-, cyclo- and biostratigraphy, isotope geochemistry, sedimentology and time series analysis. This paper presents the first preliminary results of a CRC drilling campaign at Stevns Klint, eastern Denmark (Fig. 1), where two shallow boreholes were drilled and logged from near the base of the Danian bryozoan limestone and down through the upper 350–450 m of the very thick Upper Cretaceous chalk section (Vejbæk et al. 2003). The cores represent the first complete sections through the Maastrichtian chalk of eastern Denmark

Late Cretaceous (late Campanian-Maastrichtian) sea-surface temperature record of the Boreal Chalk Sea

The last 8 Myr of the Cretaceous greenhouse interval were characterized by a progressive global cooling with superimposed cool/warm fluctuations. The mechanisms responsible for these climatic fluctuations remain a source of debate that can only be resolved through multi-disciplinary studies and better time constraints. For the first time, we present a record of very high-resolution (ca. 4.5 kyr) sea-surface temperature (SST) changes from the Boreal epicontinental Chalk Sea (Stevns-1 core, Denmark), tied to an astronomical timescale of the late Campanian–Maastrichtian (74 to 66 Ma). Well-preserved bulk stable isotope trends and calcareous nannofossil palaeoecological patterns from the fully cored Stevns-1 borehole show marked changes in SSTs. These variations correlate with deep-water records of climate change from the tropical South Atlantic and Pacific oceans but differ greatly from the climate variations of the North Atlantic. We demonstrate that the onset and end of the early Maastrichtian cooling and of the large negative Campanian–Maastrichtian boundary carbon isotope excursion are coincident in the Chalk Sea. The direct link between SSTs and δ13C variations in the Chalk Sea reassesses long-term glacio-eustasy as the potential driver of carbon isotope and climatic variations in the Maastrichtian

Shale gas investigations in Denmark:Lower Palaeozoic shales on Bornholm

The Cambrian to Lower Silurian succession in Denmark is mostly composed of organic-rich black shales that were deposited in an epicontinental sea during a period of high global sea level (Haq & Schutter 2008). The mid-Cambrian to early Ordovician Alum Shale was intensively studied in the 1980s for its source-rock properties (e.g. Buchardt et al. 1986). Recent attention has focused on its potential as an unconventional shale gas source (Energistyrelsen 2010). On southern Bornholm, many wells have been drilled through the Lower Palaeozoic succession because of its importance for groundwater exploitation. In western Denmark, only the deep exploration wells Slagelse-1 and Terne-1 have penetrated the Alum Shale, and knowledge of the unit west of Bornholm is thus very limited (Fig. 1)

Early Silurian δ¹³Corg excursions in the foreland basin of Baltica, both familiar and surprising

The Sommerodde-1 core from Bornholm, Denmark, provides a nearly continuous sedimentary archive from the Upper Ordovician through to the Wenlock Series (lower Silurian), as constrained by graptolite biostratigraphy. The cored mudstones represent a deep marine depositional setting in the foreland basin fringing Baltica and we present high-resolution data on the isotopic composition of the section's organic carbon (δ 13 C org ). This chemostratigraphical record is correlated with previously recognized δ 13 C excursions in the Upper Ordovician–lower Silurian, including the Hirnantian positive isotope carbon excursion (HICE), the early Aeronian positive carbon isotope excursion (EACIE), and the early Sheinwoodian positive carbon isotope excursion (ESCIE). A new positive excursion of high magnitude (~4‰)is discovered in the Telychian Oktavites spiralis Biozone (lower Silurian)and we name it the Sommerodde Carbon Isotope Excursion (SOCIE). The SOCIE appears discernible in δ 13 C carb data from Latvian and Estonian cores but it is not yet widely recognized. However, the magnitude of the excursion within the deep, marine, depositional setting, represented by the Sommerodde-1 core, suggests that the SOCIE reflects a significant event. In addition, the chemostratigraphical record of the Sommerodde-1 core reveals the negative excursion at the transition from the Aeronian to Telychian stages (the ‘Rumba low’), and suggests that the commencement of the EACIE at the base of the Demirastrites triangulatus Biozone potentially is a useful chemostratigraphical marker for the base of the Aeronian Stage