23 research outputs found
The facilitated diffusion of oxygen by hemoglobin and myoglobin
We have clarified the use of Wyman's differential equation for the facilitated oxygen flux through a slab of solution of myoglobin or hemoglobin by showing that there is a unique choice of boundary condition on the carrier concentration to be employed in conjunction with it. The singular perturbation solution of Wyman's equation, due to Murrayand Mitchell and Murray, has been extended. By means of it, the paradox of Wittenberg, that the facilitated oxygen flux per mole of heme is apparently independent of the protein carrier, has been resolved
Semi-classical Green kernel asymptotics for the Dirac operator
We consider a semi-classical Dirac operator in arbitrary spatial dimensions
with a smooth potential whose partial derivatives of any order are bounded by
suitable constants. We prove that the distribution kernel of the inverse
operator evaluated at two distinct points fulfilling a certain hypothesis can
be represented as the product of an exponentially decaying factor involving an
associated Agmon distance and some amplitude admitting a complete asymptotic
expansion in powers of the semi-classical parameter. Moreover, we find an
explicit formula for the leading term in that expansion.Comment: 46 page